查询词典 reaction

The effects of various reaction conditions were studied by GC analysis. Reaction time has slight effect on the conversion of acenaphthene. The selectivity of N-phenyl aminoacenaphthene increases with reaction time. Biacenaphthenyls or N-phenyl aminoacenaphthene is in the majority, 77.6% or 90.2% when the molar ratio of AlCl3 to acenaphthene is 1.2 and 2.4 respectively.

GC考察了不同反应条件对苊转化率和产物选择性的影响，时间对苊转化率影响不大，N-苯基氨基苊的选择性随着时间增加而增大；随着AlCl3用量的增加，苊转化率和N-苯基氨基苊的选择性随之增加；AlCl3与苊的摩尔比为1.2和2.4时，产物中联苊和N-苯基氨基苊的选择性分别达到77.6%和90.2%。

The impact of reaction conditions, such as acid/oil ratio, reaction temperature and reaction time on the product yield was studied.

在磺化反应过程中主要考察了反应温度、反应时间和酸油体积比对石油磺酸收率的影响。

The effect of reaction temperature,reaction time,materials ratio on the synthesis of piperidine alcohol benzoate ,hindered amine light stabilizer,from piperidine alcohol and benzoyl chloride by direct condensation were studied,and the proper technological conditions were given as follows:the reaction temperature is 95℃;reaction time is 4 h; the mole ratio of reactants,n∶n is 1∶1.4,the amounts of solvent is 40 mL(based 0.1mol piperidine alcohol),the arerage yield ...

王树清，高崇，苯甲酸哌啶醇酯HALS的合成工艺研究研究了以苯甲酰氯和哌啶醇为原料直接缩合合成苯甲酸哌啶醇酯受阻胺光稳定剂时反应温度、反应时间、原料配比等条件对合成反应的影响，确定了最佳工艺条件。最适宜的工艺条件是：反应温度95℃、反应时间6h、原料摩尔比n∶n为1∶1.4，溶剂用量为70mL(相对于0.1mol哌啶醇)，苯甲酸哌啶醇酯的收率为91.05%，产品纯度98.5%。

There are three different nucleophilic reagent respectively reaction with m-dinitrobenzene ramification at distint alkaline term:With the nitrobenzene 、 m-nirtobenzenesulfone sodium salt 、 2.4-dinitro chlorobenzene 、 m-dinitrobenzene for bottom thing, benzyl cyanide、 benzyl chloride、 benzyl chloropyridine、is a nucleophilic reagent reaction for under the different term proceeds a series reaction. At the same time ,discuss about the impact factor to nucleophilicity such as the number of attract electron group、 ability of attract electron and the nucleophilic substitution reaction part.

设计了三类不同的亲核试剂分别与活化芳环在不同的碱性条件下发生反应：以苄基氰、苄基氯化吡啶为亲核试剂，以硝基苯、间二硝基苯、间硝基苯磺酸钠、2，4-二硝基苄基氯为底物进行亲核取代反应；并且对亲核试剂的体积效应、溶剂效应对亲核性影响，底物上吸电子基团的数目、吸电子能力对亲电性的影响，以及亲核取代反应的发生部位受哪些因素影响进行探讨。

The experiments for determining the reaction kinetics of Daqing atmospheric residue were performed in a continuous flow, expanded bed rector. Four-lumped reaction kinetic model was developed to account for various feed and product fractions of Daqing atmospheric residue (gases, gas oil, residue and coke). The amounts of olefins and alkyls in the gas products were further analyzed to determine reaction kinetics of gas product distributions. Hence, a combined five-lumped reaction kinetic model was obtained for catalytic pyrolysis of Daqing atmospheric residue. The kinetic constants both in four-lump model and five-lump model were evaluated. A simulator for catalytic pyrolysis process was developed by incorporating the five-lumped kinetic model into the hydrodynamic flow model.

其次利用改进的固定流化床装置考察大庆常压渣油催化裂解反应规律，筛选反应工艺参数；分析了催化裂解工艺存在的主要化学反应类型，提出了渣油一次反应和二次反应网络图；将反应原料油作为单独集总组分，而将产品中的轻质油、气体、焦炭分别作为集总，从而建立了四集总动力学模型；在此基础上，把气体产物中的目的产物低碳烯烃独立划分，得到五集总动力学模型；采用最小二乘法分析实验数据，分别得到四集总动力学模型和五集总动力学模型中各集总间相互反应转化的反应速率常数。

The traditional technology of iron carbide production exists the problem that the reaction time is too long. The research of adding the additive into the ore of the fluid-bed was carried out in order to find the catalyst of this reaction. It was found out that K2CO3 and CaCl2 can be the catalysts of this reaction. The reacting time and equilibrium data in addition of K2CO3 and CaCl2 were examined and were campared with the contrastive experimental results respectively. The theoretical dynamics analysis also reveals that both K2CO3 and CaCl2 can accelerate the iron carbide forming reaction.

摘 要：传统的碳化铁生产工艺存在反应时间较长的难题，为此通过在流化床入炉矿石中配加部分添加剂的还原实验研究，以寻求该反应可能的催化剂，缩短反应时间，提高碳化铁生产效率和经济效益采用CaCl2和K2CO3作为反应的催化剂，利用反应所测数据，与对比实验相比较，并结合动力学分析，得出CaCl2和K2CO3可以加速碳化铁还原反应进行的结论。

The result shows that the elimination reaction and ring closing reaction are synergistic, and the hydrogen in the elimination reaction derives from hydroxyl. In addition, the activation energy of the reaction is 139.2kJ/mol.

计算结果表明，该反应中的消除反应和成环反应是协同进行的，溴化氢消除反应中的氢来自与O(22)相连的羟基氢，反应的活化势垒为139.2kJ/mol，反应放热25.1kJ/mol。

The non-isothermal decomposition kinetics of nylon 1010 and nylon 1010/POSS composites in nitrogen were investigated. POSS significantly increased the activation energy but had little effect on the reaction order.(5) Exploring research was carried out on the reaction between EVM and nylon 1010. The reaction between EVM and TsOH during melt mixing was also invesigated, and related reaction mechanisms were studied in terms of NMR, TGA-FTIR and etc.

五初步研究了乙烯-醋酸乙烯酯橡胶和尼龙1010在高温下的反应性，报道了EVM和TsOH在高温条件下的反应性，通过核磁共振、热重-红外联用等分析表征方法探索了相关的反应机理，EVM和TsOH反应后，EVM的耐溶剂性、玻璃化转变温度和力学性能均有所提高，而体积电阻率则显著下降。

The results show that the reactive characters of macro-kinetics are different from that of intrinsic kinetics under the same experimental conditions. The isobutene dimeric reaction follows 1.5 order reaction because of the effect of inner diffusion, and isooctane dimeric reaction follows zero order reaction.

结果表明，在相同的实验条件下，反应的宏观动力学行为与本征动力学行为有较大的不同，异丁烯的反应级数受内扩散影响由2级变为1.5级，异辛烯的反应级数则为0级。

The reaction kinetics was studied by selecting control-step method as well as modified Debye-Hückel activity coefficient model and Bromley osmotic coefficient model. The results show that the reaction order is 2 and apparent reaction activation energy 85.8 kJ/mol, and the reaction is mainly controlled by precipitation of KB5O8?4H2O.

采用选取控制步骤法并引入修正的Debye-Hückel活度系数模型和Bromley渗透系数模型研究了该反应的动力学的影响规律，得出反应级数为2，表观反应活化能为85.8 kJ/mol，反应主要受四水五硼酸钾晶体析出的控制。

Chrysanthemum of 10 thousand birthday is lax to edaphic requirement, with the arenaceous qualitative loam with fecund, good drainage had better.

万寿菊对土壤要求不严，以肥沃。排水良好的砂质壤土为好。

He unstepped the mast and furled the sail and tied it.

他拔下桅杆，把帆卷起，系住。