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Dealcoholization temperature markedly influences the surface area and porosity of the resultant MAO-supports. When the support was pretreated at lower or higher temperature, the corresponding MAO-support shows very low surface area;2.XRD and IR analyses indicate that MAO has reacted with the residual ethanol in the supports, which is an important manner to get MAO fixed on the carrier. Morever, XPS analyse indicates that MAO can also be coordinated with MgCl_2, which is another way to get MAO fixed on the support;3.ICP and EDX analyses indicate that dealcoholization temperature not only determined the element content on the solid catalyst, but also influences the element distribution on the carrier;4.The activities of the supported phenoxy-imine catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature. The support (MSP-5) obtained by treating MgCl_2·2.56C_2H_5OH at 160℃for 4 h, then modified by MAO is very effective for immobilizing complex 3, the resultant solid catalyst (MSPC-5) shows very high activity in ethylene polymerization, and its kinetics of polymerization is stable during the reaction process. Finally, PEs with spherical morphology and high bulk density (over 0.35g/ml) were obtained, without reactor fouling;5.In this work, polymerization conditions such as alkylaluminums, Al/Zr ratio, temperature and H_2 had a pronounced effect on the activity of MSPC-5 and properties of PE;(3). New MgCl_2-Supported Single-Site Catalysts for Ethylene PolymerizationIn this work, a kind of new MgCl_2 support was obtained by anhydrous MgCl_2 co-milled with solid MAO, and it is a creative contribution. Then some single-site catalysts were supported on the new MgCl_2 support, and the resulted solid catalysts were tested in ethylene polymerization, the results indicated that:1.XRD and IR analyses indicate that MAO does be coordinated with MgCl_2, which is in good agreement with the results obtained by XPS;2.co-mlling time had no obvious effect on the texture of support after 12 hours;3.In this work, MgCl_2 was co-milled with solid MAO for different hours, and then complex 3 was supported on these co-milled supports. It was found that co-milling time markedly influences the activity of solid catalysts, but it had negligible effect on the kinetic profile and the properties of resultant PE.

XPS研究结果表明,MAO不仅仅只和乙醇作用,MAO还与MgCl_2本身有一定的作用,这是一个极为重要的发现;3、通过ICP和EDX表征,发现载体的脱醇温度直接影响着元素在固体催化剂中的含量及分布;4、脱醇温度极大地影响着负载苯氧基亚胺类催化剂的活性和聚合物的性能,特别是原始载体经160℃活化4小时制备得到的固体催化剂MSPC-5的活性明显高于其他脱醇温度条件下制得的固体催化,并且催化剂寿命长,表现出稳定的动力学行为,最终获得了高堆密度(大于0.35g/ml)的球形聚乙烯颗粒;5、本文选择MSPC-5为研究对象,考察了聚合反应参数对催化剂的活性及其聚合物的影响,研究发现:不同的烷基铝对催化剂具有非常重要的影响,特别足TIBA对MSPC-5的助催化活性最高,烷基铝的加入量有一个较佳值,聚合温度为80度时活性最高,H_2的加入使催化剂的活性明显降低且聚合物的分子量也减小;、新型氯化镁载体负载单活性中心催化剂催化乙烯聚合本文创造性采用固体MAO与无水氯化镁直接进行共研磨,制备出了一种的新型的氯化镁载体,并将该载体用于多种单活性中心催化剂的负载化研究,研究表明:1、通过BET、XRD的表征,再次证实了MAO与MgCl_2之间具有直接作用,与XPS的研究结果相一致;2、当研磨时间高于12小时时,延长研磨时间对载体的结构没有显著的影响;3、将配合物3负载于共研磨时间不同的一系列载体上,乙烯聚合结果表明,尽管共研磨时间对负载催化剂的活性具有明显的影响,但是它对聚合物的性能以及催化剂的影响不明显。

Dealcoholization temperature markedly influences the surface area and porosity of the resultant MAO-supports. When the support was pretreated at lower or higher temperature, the corresponding MAO-support shows very low surface area; 2.XRD and IR analyses indicate that MAO has reacted with the residual ethanol in the supports, which is an important manner to get MAO fixed on the carrier. Morever, XPS analyse indicates that MAO can also be coordinated with MgCl_2, which is another way to get MAO fixed on the support; 3.ICP and EDX analyses indicate that dealcoholization temperature not only determined the element content on the solid catalyst, but also influences the element distribution on the carrier; 4.The activities of the supported phenoxy-imine catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature. The support (MSP-5) obtained by treating MgCl_2·2.56C_2H_5OH at 160℃for 4 h, then modified by MAO is very effective for immobilizing complex 3, the resultant solid catalyst (MSPC-5) shows very high activity in ethylene polymerization, and its kinetics of polymerization is stable during the reaction process. Finally, PEs with spherical morphology and high bulk density (over 0.35g/ml) were obtained, without reactor fouling; 5.In this work, polymerization conditions such as alkylaluminums, Al/Zr ratio, temperature and H_2 had a pronounced effect on the activity of MSPC-5 and properties of PE;(3). New MgCl_2-Supported Single-Site Catalysts for Ethylene Polymerization In this work, a kind of new MgCl_2 support was obtained by anhydrous MgCl_2 co-milled with solid MAO, and it is a creative contribution. Then some single-site catalysts were supported on the new MgCl_2 support, and the resulted solid catalysts were tested in ethylene polymerization, the results indicated that: 1.XRD and IR analyses indicate that MAO does be coordinated with MgCl_2, which is in good agreement with the results obtained by XPS; 2.co-mlling time had no obvious effect on the texture of support after 12 hours; 3.In this work, MgCl_2 was co-milled with solid MAO for different hours, and then complex 3 was supported on these co-milled supports. It was found that co-milling time markedly influences the activity of solid catalysts, but it had negligible effect on the kinetic profile and the properties of resultant PE.

XPS研究结果表明,MAO不仅仅只和乙醇作用,MAO还与MgCl_2本身有一定的作用,这是一个极为重要的发现; 3、通过ICP和EDX表征,发现载体的脱醇温度直接影响着元素在固体催化剂中的含量及分布; 4、脱醇温度极大地影响着负载苯氧基亚胺类催化剂的活性和聚合物的性能,特别是原始载体经160℃活化4小时制备得到的固体催化剂MSPC-5的活性明显高于其他脱醇温度条件下制得的固体催化,并且催化剂寿命长,表现出稳定的动力学行为,最终获得了高堆密度(大于0.35g/ml)的球形聚乙烯颗粒; 5、本文选择MSPC-5为研究对象,考察了聚合反应参数对催化剂的活性及其聚合物的影响,研究发现:不同的烷基铝对催化剂具有非常重要的影响,特别足TIBA对MSPC-5的助催化活性最高,烷基铝的加入量有一个较佳值,聚合温度为80度时活性最高,H_2的加入使催化剂的活性明显降低且聚合物的分子量也减小;、新型氯化镁载体负载单活性中心催化剂催化乙烯聚合本文创造性采用固体MAO与无水氯化镁直接进行共研磨,制备出了一种的新型的氯化镁载体,并将该载体用于多种单活性中心催化剂的负载化研究,研究表明: 1、通过BET、XRD的表征,再次证实了MAO与MgCl_2之间具有直接作用,与XPS的研究结果相一致; 2、当研磨时间高于12小时时,延长研磨时间对载体的结构没有显著的影响; 3、将配合物3负载于共研磨时间不同的一系列载体上,乙烯聚合结果表明,尽管共研磨时间对负载催化剂的活性具有明显的影响,但是它对聚合物的性能以及催化剂的影响不明显。

Provides attributes for elements which may be independently associated with a particular declarable element within the header, thus overriding the inherited default for that element.

提供元素属性,这些元素可单独与标头中一特定可宣告元素相关连,因此超越该特定元素本身的预设值。

To achieve the program of finite element, which apply to the two-dimensional temperature distribution of high power laserAccording to the diathermanous principles and the thoughts of finite element, the temperature distribution of the chip and the submount of high-power laser were simulated in the work.

2实现了适用于大功率半导体激光器二维温度场的有限元程序根据传热学的基本原理和有限单元的思想对大功率半导体激光器的芯片和载体的温度场进行计算机模拟了,最终求解出了总体温度刚度矩阵K_总和总体边界条件矩阵P_总,进而求解出各个节点的温度值T。

It is seen that oxygen group function of additives is very remarkably in tribological characteristics, that is EP property of dihydroxy docosanoic acid without active element is very near to that of SO with active element sulfur.

双羟基廿二酸的极压性与不含氧基团的硫化烯烃十分接近,以液体石蜡为基础油,最大无卡咬负荷P〓值,前者为539N,后者为588N,再者相差49N,可以看出,氧基团的作用是十分显著的,即无活性元素的双羟基廿二酸的极压性可以十分接近于含活性元素的抗磨极压剂硫化烯烃。

The element is based on the Reissner-Mindlin plate bending theory and is eccentrically stiffened with beam element.

采用非等参插值的方法避免了Mindlin板/壳单元用于分析薄板/壳结构时固有的剪切锁死问题,数值算例结果表明,该单元对与薄板和厚板均给出了精确的解。

This element of surprise or mystery — the detective element as it is sometimes rather emptily called is of great importance in a plot .

译文这种惊奇和神秘的成分—有时人们干脆空洞地叫它&侦探成分&—对情节应是十分重要的。它打断故事发展的思路。

Seriously escapes themedicine which sends to have the Arab League mildew element, the tableArab League mildew element, the ghost 臼 ethylidene glucoside (vp16)and so on.

较严重脱发的药有阿霉素、表阿霉素、鬼臼乙叉甙(vp16)等。

In this paper, the research object is the XM18 spherical generator, in order to improve the dynamic behavior of the machine tool, the following aspects have been studied in this thesis: Firstly, based on the elasticity theory and finite element analysis theory, the finite element models of the lathe bed, dovetail, dovetail shelf, headstock, fanlike plank and millhead shelf, which were the main parts of the spherical generator, were built up using ANSYS9.0. And based on the modal analysis theory and FEM technology, the free modal and the constrained modal analysis of the main parts were studied. Accordance to the analytical results, put forword methods to optimize the key parts.

本课题以XM18球面铣磨机为研究对象,为了提高其动态特性,本文主要从以下几个方面进行研究:首先,根据弹性力学理论和有限元分析的基本理论,利用ANSYS9.0软件建立了铣磨机的主要零部件床身、燕尾、燕尾座、主轴箱、扇形板和磨头座的有限元模型,利用有限元法对主要零部件进行了自由模态和约束模态分析,并根据分析结果对关键部件提出了改进方案。

The core of this model is using solid element to simulate elastoplasticity deformation of faultage and using contact element to simulate the interface of faultage and rock, and so, realizing the problems coupling of elastoplasticity and contact.

模型的核心是以三维实体单元模拟断层或软弱夹层材料弹塑性变形特性,以接触面单元模拟断层或软弱夹层与完整岩石之间交界面的力学特性,即剪切效应和法向提离效应,从而实现了弹塑性问题和接触问题的耦合。

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牢固树立多元文化的理念和正确把握先进文化的发展方向,有助于在世界范围内自觉地抵制恐怖主义,民族分裂主义和宗教极端主义。不仅具有重大的学术理论意义,而且也具有重大的现实意义和深远的历史意义。

But if anyone walks in the night, he stumbles, because the light is not in him.

11:10 若在黑夜行走,就必碰跌,因为那光不在他里面。

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你的要求太过分了。