查询词典 polymerization

Anionic polymerization ; Acylate ; Atom transfer radical polymerization ATRP ; Macroinitiator

阴离子聚合；酰化；原子转移自由基聚合；大分子引发剂

Poly was synthesized with calcium ammine as catalyst system and hexane as solvent,and the relationship among catalyst amounts,polymerization temperature,polymerization time and moisture of solvent with the yield of PEO and its relative molecular mass were investingated.

阐述了采用氨钙体系催化剂、以正己烷为溶剂的沉淀聚合制备聚氧化乙烯的方法。研究了催化剂用量、反应温度、反应时间及溶剂含水量与PEO收率及其相对分子质量的关系。

The electric conductivity of solid polyiodides increases largely as the aggrandizement of polyiodide anions"polymerization degree. The solid polyiodides have excellent sterilizing effects and the effect of tetra-n-butyl ammonium undecaiodide is the best of them, and the sterilizing effects increase as the aggrandizement of polyiodide anions" polymerization degree. The sterilizing effects of resinic polyiodides increase as the aggrandizement of polyiodide anions polymerization degree, the heptaiodide resinic polyiodide has better sterilizing effects than the triiodide and pentaiodide.

固体高聚碘系列化合物的电导率随着高聚碘阴离子聚合度的增加而增加，并且增幅较大；固体高聚碘对常见细菌均具有很好的杀灭作用，并且随着高聚碘阴离子聚合度的增加，杀菌能力也随着增强，其中正四丁基十一碘化铵杀菌剂的效果最佳；树脂高聚碘随着高聚碘阴离子聚合度的增加，杀菌能力增强，碘七树脂高聚碘的杀菌效果要明显好于碘三树脂和碘五树脂高聚碘。

Reversible Addition-Fragmentation Transfer polymerization; Living Free Radical Polymerization; Photoinitiate polymerization; Trithiocarbonate

工程科技I，化学，高分子化学可逆加成-断裂链转移自由基聚合；活性聚合；紫外光聚合；苯乙烯St

The relationship of the amounts of emulsifier, organosilicon monomer (D4) and initiator with the ratio of fluorescence intensity between first vibronic peak of pyrene (λ= 373 nm) and third vibronic peak of pyrene (λ=384nm)Ⅰ1/Ⅰ3 were discussed during the emulsion polymerization process, in which pyrene was used as fluorescence probe. The polymerization behavior of the organosilicon-acrylate latex with core-shell structure was investigated in line with the relationship of monomer conversion and development of morphology in latex particles with the value of Ⅰ1/Ⅰ3 for probe pyrene during the polymerization process.

以芘为荧光探针，探讨了有机硅-丙烯酸酯核壳乳液聚合过程中，芘的第一振动峰(373nm处)与第三振动峰(384nm处)荧光强度的比值Ⅰ1/Ⅰ3与乳化剂、有机硅单体（D4）和引发剂用量之间的关系，并结合聚合过程中探针芘的Ⅰ1/Ⅰ3 峰值与单体转化率及乳胶粒形态演变之间的关系，研究了核壳结构有机硅-丙烯酸酯乳液的聚合行为。

For the first time, the dynamics changing process of KGM chain in vacuum is proposed, We obtained the following results: polymerization degree influences the stability and shapes of the chain, the chain stability drops with the increasing of polymerization degree, for the high polymerization degree KGM, KGM chain takes on irregular curl state; acetyl group is not the main factor influencing chain conformation , during the course of dynamics movement KGM chain takes on irregular curl state before and after acetyl group was doffed, Extending and curling states change periodicity and has good flexibility.

首次提出了KGM链的动态模型，得到了以下结果：聚合度影响其链形态和稳定性，对于高聚合度的魔芋葡甘聚糖来说，其链呈现无规卷曲状态且稳定性下降，在整个动态运动过程中KGM链脱乙酰基前后都呈现无规卷曲状态，而且其伸展和卷曲的变化是周期性的，表现出了很好的柔性，说明乙酰基不是影响其链形态的主要因素，二面角能和静电作用是真空中影响单链构象的主要的键合作用力和非键合作用力，但是乙酰基对氢键作用的影响(来源：ABC6c论文网www.abclunwen.com)较大。

Emulsification is the mainly reason to influence on the reaction, the influences of emulsifiers such as the concentration of emulsifies, the ratio of anionic to nonionic emulsifier on the polymerization stability were researched;The influences of concentration and feeding method of initiators on the reaction stability and the mechanical properties of coating film of acrylate polymerization stability were researched;The influences of reaction temperature, stirring speed and pH buffer agent on the polymerization stability and pH regulator on the storage stability of Acrylate emulsions were also researched.

乳化剂是影响乳液稳定性的主要因素，因此对乳化剂进行了全面的探讨，包括乳化剂的种类和用量、阴离子型与非离子型乳化剂的比例对乳液稳定性的影响；文中还研究了引发剂的用量、加入方式对聚合稳定性的影响，以及引发剂用量对聚丙烯酸酯涂膜力学性能的影响；此外，讨论了反应温度、搅拌速率、pH值缓冲剂对乳液聚合过程稳定性的影响及pH调节剂对乳液贮存稳定性的影响。

There are the non-saturated and carbon -carbon double keys and carboxyl group and special functional group derived from carboxyl group, so it is used in the polymerization and co-polymerization widely, can react with many kinds of the compounds, and produce a series of acrylic acid co-polymerization compound .

丙烯酸及其酯的化学结构中均有不饱和碳碳双键和羧基或羧基衍生的特性功能团，因此可广泛用于均聚反应和共聚反应，能与多种化合物反应，合成一系列丙烯酸共聚物。

In the second part, quantum chemical AM1 methods were employedto theoretically investigate the electronic structures of maleic anhydride in ground- and excited-states. On basis of the frontier orbital theoryand three bonding principles, the possibility of reaction of active α-hydroxysuccinic anhydride carbanion and active α-hydroxy-succinic anhydride radical on polymerization process of MArespectively by alkali catalyst and by hydroxyl radical was discussed. Theanionic and radical polymerization of MA discussed also. Theoreticalstudies show that both polymerization products of MA are in the chainstructures, corresponding to the experimental findings.

第二部分用量子化学AM1方法，计算研究了马来酸酐的基态和激发态电子结构；应用前线轨道理论和成键三原则分别探讨了碱催化条件下和羟基自由基引发下马来酸酐均聚合过程中α-羟基丁二酸酐碳阴离子和α-羟基丁二酸酐碳自由基活性中间体参与反应的可能性及由它们引发的马来酸酐阴离子聚合反应机理和自由基引发聚合反应机理；理论研究表明马来酸酐的均聚合产物均为链式结构，与实验事实相相符。

Symmetric Lewis base has the following problem in the application that the relatively high content of regulator will reduce the rate of polymerization and impact further polymerization as well as the coupling process after the polymerization.

对称型路易斯碱在应用中存在问题：较高调节剂含量将会降低聚合速率、影响进一步聚合以及聚合以后的偶联过程。

Since historical times,England ,where the early inhabitants were Celts, has been conquered three times .

从有历史以来，英国，在此地早期居住的是凯尔特人，已经被征服了三次。

Bluetooth OBEX File Transfer Enables the sending and receiving of files on your phone via Bluetooth.

蓝牙OBEX文件移动允许经过蓝牙传送和接受文件。。。。