查询词典 oxidation

The Schiff base transitional metal complexes of various structures and their metallomicelles as peroxidase models for the phenol and phenolic derivant oxidation have been investigated. Some results are obtained from the studies:(1) the Schiff base transitional metal complexes have high catalytic activity for the phenol and phenolic derivant oxidation, and the structure of the complexes has a great effect on its catalytic activity;(2)a novel kinetic mathematical model for the complexes and their metallomicelles catalyzing the phenolic derivant oxidation has been established;(3) the feasibility and mechanism for the phenolic derivant oxidation catalyzed by the metallomicelle(as the mimetic model of peroxidase)have been discussed.

研究了冠醚Schiff碱金属配合物作为过氧化物酶的模拟模型对酚类物质氧化反应的催化作用，取得如下结果：(1)几种冠醚Schiff碱金属配合物对催化酚类物质氧化具有良好的催化活性，其中配体结构对其催化活性有较大的影响；(2)建立了金属配合物与表面活性剂形成的金属胶束催化酚类物质氧化反应的动力学数学模型；(3)探讨了金属胶束模拟过氧化物酶催化酚类氧化反应的可行性及其机理。

The results of the ability of anti-oxidation scavenging DPPH free radical shows that polyhydroxy substituted N-benzoylserotonin derivatives (compound 1-10) have the generally better ability of anti-oxidation than control group, in which the IC50 of compound 1-10 ranges 8.75 to 18.02 μg/ml and the IC50 of trolox is 13.04 μg/ml. The abilities of anti-oxidation of compound 1, 4, 5, 7, and 10 are all better than the control group, trolox. Among all, compound 10 has the best ability of anti-oxidation (IC50 is 8.75 μg/ml). This study also discovers that the ability of scavenging DPPH free radical is strongly related to the number and the position of hydroxyl.

在清除DPPH自由基的抗氧化能力结果显示，相较於对照组水溶性维生素E之IC50值13.04 μg/ml，多羟基取代之N-色洛冬宁苯甲醯胺衍生物（化合物 1 ~ 10），皆具有相当不错的抗氧化能力，十种醯胺化合物的 IC50值介於8.75 ~ 18.02 μg/ml之间，化合物1、4、5、7、10的抗氧化能力效果皆优於对照组水溶性维生素E的IC50值，其中又以化合物10的效果最佳(IC50值8.75 μg/ml)，而清除DPPH自由基的能力发现与羟基的数量及其位置有关。

Firstly the oxidation loss was controlled by the reaction between the coated C/C composites and oxygen. Secondly the oxidation loss was controlled by the producing and vaporing rate of the glass. The oxidation loss was lined with the oxidation time. Thirdly there were cracks in the coating and the deep of the coating was oxidated. The weight loss rate increased linearly and the matrix had been oxidated partly in the end.

氧化初期，涂层的表面开始氧化，氧化失重是一个受氧气和涂层的化学反应控制，表现为氧化增重；氧化中期，氧化失重受玻璃质的形成速度和蒸发速度控制，表现为缓慢的氧化失重，氧化失重与时间的关系为直线型；随后，涂层上出现裂纹的形成和愈合过程，涂层深层被氧化，表现为较快的氧化失重；最后，涂层被局部破坏，基体被部分氧化，氧化失重直线上升。

Advances on the development of new oxidation reagents and methodologies and their applications in both target-and diversity-oriented synthesis have been regularly surveyed and constituted one of the most extensively and actively investigated areas of current organic synthesis.1 In this context,a plethora of oxidants,including those small organic molecule-based reagents (such as Dess-Martin periodinane,Swern oxidation,Moffatt oxida- tion,Corey-Kim oxidation,and 三氧化硫/pyridine)and metal-based systems(such as Jones reagent,Collins reagent,pyridinium chlorochromate,pyridinium dichromate,barium permanganate, manganese dioxide,ruthenium tetroxide,silver carbonate,and Oppenauer oxidation),have been identified to be powerful tools promoting conversion of various alcohols into their corresponding aldehyde or ketone products and thus evolved as a most important class of tools in synthetic chemists'arsenal.

关于新的氧化试剂和方法，在两个目标和多样性为导向的发展及其应用合成的进步定期调查，构成一个最广泛，积极探讨在这方面，过多的地区目前有机合成。1氧化剂，包括有机小分子为基础的试剂（如Dess - Martin氧化剂，斯文氧化反应，氧化法特，科里，金氧化，三氧化硫/吡啶）和金属为基础的系统（如琼斯试剂，柯林斯试剂，吡啶氯铬，吡啶铬，钡锰，二氧化锰，四氧化钌，银碳酸盐和开瓶器氧化），已被证实为推动中相应的醛或酮醇转化的各种产品，功能强大的工具，因而作为一个最重要的阶级演变在阿森纳的工具合成化学家。

The zinc oxidation leaching ratio can reach 86.73% in 96h. The oxidation mechanisms of zinc sulphide concentrate in different suspension electrolysis solution are almost same. However, the exchange current density in the process of oxidation is low and it will quicken electrochemical oxidation with the increasement of temperature.

通过实验分析得出：硫化锌矿在不同悬浮电解溶液中都能够被氧化，但有较大的差别，在硫酸锌、硫酸铵和硫酸的悬浮电解液中，矿物明显被氧化而溶解进入悬浮液中，氧化速度比较快，锌的氧化溶出率在96h的时间内达到86.73％。

Meanwhile, the concentration of Pb,Zn and other heavy metals is rather high in the oxidation zone and decreasesdownward to levels that are unbelievably low for Pb-Zn mine tailings. Theseobservations suggest that heavy metals should be re-immobilized by secondaryminerals, rather than primary minerals, in the oxidation zone, and could be leachedout from suboxic environment due to low rate oxidative dissolution which preventsthe precipitation of secondary minerals in significant amount. Thus, cover scenarioswhich establish a suboxic environment beneath the cover layer might not always beeffective in preventing heavy metal release from mine tailings.Sequential extraction studies indicate that, in addition to heavy metal leaching,oxidation of the mine tailings increased the mobility of residual Zn, and Cu, while Pb remains immobile due to the formation of anglesite (PbSO4). Using the seven-step extraction technique developed by Dold (J. Geochem. Explor., 2003, 80: 55-68), galena dissolves in significant amount at step 2 most probably due to the strong complexing of Pb2+ by acetate, while other metal sulfides dissolve at step 6, which suggest that this extraction technique could not be used to evaluate the mobility of lead in natural environment

重金属含量均低于新鲜尾矿，但以硬化层中的含量最高(Pb、Zn含量分别为0.47%和0.93%)，往下大幅度降低，表明尾矿风化过程中形成的次生矿物对Pb、Zn等重金属元素有较强的固定作用，而次氧化带的淋溶作用造成了金属元素的大量流失；(4)与新鲜尾矿相比，硬化层中铅的可迁移性大大降低，硬化层之下尾矿样品中铅的可迁移性也不同程度降低，这是由于硫化物氧化产生的硫酸根与尾矿中的铅反应形成铅矾(PbSO_4)的缘故；(5)氧化作用使尾矿中的zn、Cu等重金属的可迁移性不同程度地增大，其中对锌的可迁移性影响最大，铜的可迁移性与铁比较相似，铅则容易与硫化物氧化形成的SO_4~(2-)反应形成铅矾(PbSO_4)；(6)为了减少尾矿污染和修复矿山环境，人们提出了各种不同的尾矿覆盖方案，本文的研究结果表明，这些方法不一定能够有效地阻滞污染元素的迁移。

To study the performance of inorganic composite catalyst for the SPC oxidation of p-methyl anisole, Cu2-Co2-KBr is used as catalyst of sodium percarbonate oxidation for p-methyl anisole synthesized by paracresol methylating. Effect of reaction conditions, such as the factors of catalyst composition, catalyst quantity, solvent, reaction temperature and time on oxidation of p-methyl anisole, is investigated.

研究了无机复合催化剂催化SPC氧化对甲基苯甲醚的反应性能：以Cu2-Co2-KBr为催化剂，利用过碳酸钠氧化对甲酚甲基化产物对甲基苯甲醚，系统研究了催化剂组成比例、催化剂用量、溶剂、反应温度、反应时间等因素对反应的影响。

Results: Oxidation resistance effect of 0.10% loquat leaf flavanone was close to that of 0.05% tertiary butylhydroquinone, indicating the loquat 1eaf flavanone had obviously oxidation resistance effect to the fat with quantitative relationship. Antiscorbutic acid and the loquat leaf flavanone has the coordination oxidation resistance effect.

结果：0.10%枇杷叶黄酮的抗氧化效果和0.05%叔丁基对苯二酚相近，表明枇杷叶黄酮对油脂的抗氧化效果明显，且作用呈一定的量效关系，抗坏血酸与枇杷叶黄酮有协同抗氧化效应。

Of the first oxidation stage of biliverdin for the first time, and found that the intermediate reactions existed during the further oxidation process of the oxidized product of biliverdin, and proposed a ECECE mechanism for the whole oxidation reactions.

发现了胆绿素氧化反应产物再氧化的中间过程及胆黄素的氧化反应，均为首次报道。并提出了胆绿素氧化的ECECE反应机理。

It is very difficult to eliminate these influence factors completely by conventional treatment. Surface properties and surface treatment of ultrafine red phosphorus and MMT and their interface properties with polymer matrices were studied in this thesis. The results were characterized by GC, FTIR, XRD, DTA, TG, XPS, UV, SEM, TEM and other physical and chemical methods. The main contents are as following: 1. The study of factors influencing ultrafine red phosphorus's invariability and phosphine liberation indicated red phosphorus undergone oxidation and dismutation reaction in air, and trace ion of iron, copper and nickel fastened water absorption and oxidation, in which the effect of copper ion was the most, while aluminium and zinc ion could slow down red phosphorus'oxidation, and silver ion had the best effect on red phosphorus moisture absorption. Inhibitors such as aluminium hydroxide, magnesium hydroxide, organic phenol and ferrous potassuim cyanide had a good effect on reducing red phosphorus moisture absorption and restraining phosphine liberation.

本文围绕纳微米材料的表面处理及其在高聚物基体中的应用这一主题，系统地研究了超细红磷和蒙脱土两种常见材料的表面特性、表面处理方法及其与高聚物基体的界面特性，通过气相色谱、红外光谱、X射线衍射、差热、热重、X射线光电子能谱仪、紫外光谱、扫描电镜、透射电镜等现代分析仪器以及其它物理、化学方法对实验结果进行了表征和分析，全文主要内容如下： 1、对影响超细红磷安定性的因素以及磷化氢的缓释研究表明：红磷在空气中发生缓慢氧化、歧化反应，微量的铜、铁、镍等金属离子增加了它的吸水和氧化速度，其中铜离子的作用最为明显，而铝、锌等离子减慢了红磷的氧化速度，银离子对减少红磷的吸湿性效果最好。

There had been a moment during the breakfast meeting, though, after the backslapping and the small talk and when all of us were seated, with Vice President Cheney eating his eggs Benedict impassively and Karl Rove at the far end of the table discreetly checking his BlackBerry, that I witnessed a different side of the man.

那次早餐会期间，在表示过关心和寒暄以后，我们所有人坐了下来，我注意观察了一下，副总统切尼面无表情地吃着班尼迪克蛋（Eggs benedict，源自美国，以英式松饼、火腿、水煮蛋以及荷兰酱组合而成），卡尔。罗夫在餐桌的远端谨慎地经常查看他的黑莓手机，我目睹了他所不为人知的一面。

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