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New ruthenium benzylidene complexes benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] [k~2-diphenylphosphinoacetato] monochlororuthenium (46), benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene][k~2-3-propionato]monochlororuthenium (47), benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] [k~2-2-benzonato]monochlororuthenium (48) featured five-membered, flexible six-membered and rigidsix-membered chelating rings respectively are prepared by reactions of complex 41 withcorresponding sodium phosphino-carboxylates. It is confirmed by X-ray crystallographicanalysis that the coordination geometries of complexes 46 and 47 are distorted squarepyramids with phosphino-carboxylate ligands chelating to ruthenium, and the coordinationbetween ruthenium and benzylidene ligands are strengthened.

用二苯基瞵乙酸盐、二苯基膦丙酸盐、二苯基膦苯甲酸盐与钌卡宾配合物41反应合成了三个新的钌卡宾配合物：含五元膦-氧螯合环的1，3-二-(2，6-二甲苯基)-4，5-二氢咪唑基1-苯亚甲基--一氯合钌(46)、含六元柔性膦-氧螯合环的[1，3-二-(2，6-二甲苯基)-4，5-二氢咪唑基1-苯亚甲基--一氯合钌(47)及含六元刚性膦-氧螯合环的[1，3-二-(2，6-二甲苯基)-4，5-二氢咪唑基]-苯亚甲基--一氯合钌(48)。X射线单晶衍射分析证明，配合物46、47都为变形的四方锥构型，膦-氧与钌形成螯合配位，其中苯亚甲基与钌的配位得以加强。

The tin atoms are five-coordinated with geometry of distorted trigonal bipyramid.

两个锡原子为五配位的三角双锥构型。

The exo-cyclic tin atoms are five-coordinate and have coordination geometry of monocapped trigonal bipyramid with very similarly distorted mode.

有关该类化合物的晶体结构研究表明，中心锡原子的配位形式决定于直接与锡原子相连的烃基的结构和羧酸基配体的类型[8～ 10 ] 。

The structure is a distorted triangular bipyramid with five coordinated central tin atom.

配合物中锡原子呈五配位畸变三角双锥构型。

In the complex, the tin atom is hepta-coordinated in a distorted pentagonal bipyramid including a bridging pyridyl N atom, by which the one-dimensional infinite chain is formed.

结果表明，该化合物中锡原子配位数为7，处在畸变五角双锥配位场中，化合物通过吡啶基氮原子的桥连作用形成了一维无限链状结构。

In the 2A1 distorted trigonal bipyramid structure ,the single non equivalent Ga atom has the population of 4s 4p ,while the two equivalent Ga atoms have the population of 4s 4p .this compares with a Ga population of 4s 4p in the undistorted D3h structure ,hence the jahn-teller distortion causes depletion of the charge density on the 4s orbital of the non-equivalent Ga atom, and enhancement of charge density on the 4s orbital for the two equivalent atoms .an opposite trend is observed for the 4p orbitals of these Ga atoms .the P population for the two equivalent atoms is 3s 3p .the populations of the other 2B1 state with the edge-capped tetrahedral structure are similar with the exception that all three Ga atoms have similar but not identical populations .

在2A1被变形的三角bipyramid结构，唯一非等效Ga原子有4s 4p的人口，而二个等效Ga原子在未变形的D3h结构有4s 4p 。this的人口和4s相比4p的Ga人口，因此jahn出纳畸变在non-equivalent Ga原子的4s轨道导致电荷密度的取尽，并且电荷密度的改进在4s轨道为二个等效原子。an在趋向对面对这些Ga原子4p轨道被观察。the人口为二个等效原子是另一个2B1状态3s 3p 。the人口与边缘加盖的四面体结构是相似的P 除之外全部三个Ga原子有相似，但不相同人口。

Bipyridyl and 1,10-phenanthroline (L3), Cl3SnCH2CH2COORo L (L= L1, a; L2, b; L3, c), formed by low-heating solid-state reaction. The crystal structures of 1 and 2 show that the tin atom adopts a distorted trigonal bipyramid geometry via intramolecular carbonyl oxygen to tin coordination [the distances of Sn-0 bond are 0.2351(6) ran for 1 and 0.2362(3) nm for 2]. Compound 1 belongs to monoclinic with space group P2/c, a = 0.9842(2) nm, b =1. 0923(8) nm, c = 1.23948(11) nm,/?= 93.894(15)°, V= 1.3294(4) ran3, Mr = 366.23, 7 = 4. Compound2 belongs to monoclinic with space group P2{/c, a = 1.04443(9) nm, b = 1.04823(7) nm, c = 1.28113(9) nm,/= 90. 953(8)°, V= 1.40239(19) nm3, Mr = 380.25, Z = 4

利用元素分析、红外光谱、核磁共振对其结构进行了表征，并通过X射线单晶衍射测定了1和2的晶体结构，二者均为具有分子内羰基氧原子配位的畸变三角双锥结构。1属于单斜品系，空间群P21/c， a=0.9842(2)nm，b=1.0923(8)nm，c=1.23948(11)nm，β=93.894(15)°，V=1.3294(4) nm^3，Mr=366.23，Z=4.2属于单斜晶系，空间群P21/c，a=1.04443(9)nm，b=1.04823 (7)nm，c=1.28113(9)nm，β=90.953(8)°，V=1.40239(19)nm^3，Mr=380.25，Z=4。

Forming a distorted trigonal bipyramid.

形成畸变的三角双锥构型。

X-ray single crystal analysis of a new paramagnetic manganese complex with DTPA-BpABA (a DTPA- bisamide derivative), Mn·4H2O, shows that four oxygen atoms and three nitrogen atoms from the ligand coordinate to Mn cation, forming a seven-coordinate distorted pentagonal bipyramid polyhedron.

采用X-射线单晶衍射法对锰与DTPA-BpABA(DTPA-二酰胺衍生物)形成的一个新的顺磁性配合物Mn·4H2O进行了结构测定。

The Sn atoms are considered as five-coordinate and exist as distorted trigonal bipyramidal geometry in a one-dimensional chain.

合成化合物的中心Sn原子为五配位，构成以Sn为中心，扭曲的三角双锥构型，通过分子间氢键形成一维链状结构。

That snake Alaric named Archbishop...

庇护。。。那个毒如蛇蝎的Alaric被命名为大教主。。。

You have done lots of magical things to be amazed at.

你做了很多神奇的事物感到惊讶。