查询词典 crystal diffraction

Finally, the cytotoxic and antibacterial activities of the oxamido-bridged binuclear complexes were studied in vitro.. This dissertation consists of three sections as follows:1. The crystal structure of a oxamide dinitrate,(1) [H_4dmaeoxd](NO_3)_2 H_2dmaeoxd = N,N\'-bis[2-ethyloxamide, has been obtained. The diversity of complexes with different structures is carried out by successful synthetic strategy of controlling species of metal ions, counter anions, pH values and solvents in the course of synthesis. Four dinuclear complexes bridged by trans-dmaeoxd2-: [Cu_2_2](ClO_4)_2 (2), [Cu_2_2](ClO_4)_2 (3),、[Cu_2(Me_2phen)_2](ClO_4)_2 (4), [Cu_2_2(H_2O)_2] (5); Four dinuclear complexes bridged by cis-dmaeoxd2-: [NiNi_2](ClO_4)_2 (6), [CuNi_2](ClO_4)_2·2CH_3OH (7), [CuZn_2]-(ClO_4)_2·2H_2O (8), [Cu(H_2O)Ni_2](ClO_4)_2.0.5CH_3OH (9); three 1-D polynuclear complexes: [Cu_2]_n·nH_2O (10), [Cu_2(H_2O)_2-]_n·4nH_2O (11), [Cu_2(H_2O)]_n(NO_3)_n·2nH_2O (12); one 2-D polynuclear complex,[Cu_6_3(μ_3-OH)_2(H_2O)_2]_n(ClO_4)_(4n).2nH_2O (13); the others: [VO(H_2O)]·2H_2O (14), [Zn_2_4](ClO_4)_2·H_2O (15), [Cu_2]·2DCM (16) have been synthesized and characterized by X-ray single crystal diffraction, elemental analysis, IR spectra.

本论文主要包括以下三部分：一、合成得到了一个草酰胺配体硝酸盐的单晶结构，[H_4dmaeoxd](NO_3)_2 (1)；通过调控金属离子的种类、端基配体、抗衡阴离子、溶剂、pH值等条件定向合成了四个反式草酰胺桥联双核铜配合物：[Cu_2_2](ClO_4)_2 (2)、[Cu_2_2](ClO_4)_2 (3)、、[Cu_2(Me_2phen)_2](ClO_4)_2 (4)、[Cu_2_2(H_2O)_2] (5)；四个顺式草酰胺桥联同/异双核配合物：[NiNi_2](ClO_4)_2 (6)、[CuNi_2](ClO_4)_2·2CH_3OH (7)、[CuZn_2]-(ClO_4)_2·2H_2O (8)、[Cu(H_2O)Ni_2](ClO_4)_2.0.5CH_3OH (9)；三个一维聚合物： [Cu_2]_n·nH_2O (10)、[Cu_2(H_2O)_2-]_n·4nH_2O (11)、[Cu_2(H_2O)]_n(NO_3)_n·2nH_2O (12)；一个二维聚合物： [Cu_6_3(μ_3-OH)_2(H_2O)_2]_n(ClO_4)_(4n)。2nH_2O (13)；单核钒配合物[VO(H_2O)]·2H_2O (14)、草酸根桥联双核锌配合物[Zn_2_4](ClO_4)_2·H_2O (15)、美洛西康铜配合物[Cu_2]·2DCM (16)，利用元素分析、摩尔电导、红外光谱、电子光谱和单晶X-射线衍射对上述所得化合物进行了结构表征，探讨了结构影响因素，并研究了其超分子结构。

Two new binuclear complexes, [TpCu(μ-1, 1-N3)2CuTp](1) and [Tp(superscript *)Co2CoTp(superscript *)](2) Tp=tri (pyrazolyl borate and Tp(superscript *)=3,5-dimethyltri borate, have been synthesized and characterized by IR, UV-vis, ESR, and CV. The crystal structures of both complexes have been determined by X-ray single crystal diffraction.

合成了两个新型的含三吡唑硼配体的双核铜配合物[TpCu(μ-1， 1-N3)2CuTp](1)和双核钴配合物[TpCo2CoTp](2)，并通过IR，UV-vis，EPR，CV，X-射线单晶衍射等手段进行表征。

The crystal was obtained from the interaction system, NH4VO3/H2O2/ 2-(2′-pyridyl)imidazole, in aqueous solution under the physiological conditions, and the complex was characterized by solution NMR, IR, X-ray crystal diffraction and elementary analysis.

经NMR、IR、X-ray衍射和元素分析等谱学方法或分析手段确定其组成[NH4{OV(O2)2{2-(2′-Py)-Imi}·4H2O}]和结构，其51V的化学位移在单核双过氧钒化合物中是最大的。

Both were measured using X-ray single crystal diffraction. For the crystal in MeOH, X-ray in compound. In an ansymmetry unit, there are two Cu atoms, two ligands and twosolvent methanol molecules. The tetranuclear complex contains two kinds of Cucenter.

本文在MeOH中得到了阶梯型四核铜骨架配合物；在THF中得到了扭曲的立方烷型四核铜骨架配合物，经晶体结构分析表明，阶梯型四核铜骨架配合物是由两个Cu2被μ~3-剪刀撑二个醇羟基O所连接形成中心对称的二铜二聚体结构。

One mixed-ligand complex ofnH2Otpa=terephthalate, tripy=4'-(4methyoxyphenyl-2,2':6',2-terpyridine was synthesized and characterized by IR, elemental analysis and thermo-gravimetric analysis. The crystal structure of the product was established by single-crystal X-ray diffraction.

采用水热法合成了新的维链状锌的配位聚合物nH2O（tpa=对苯二甲酸，tripy=4'-（4-甲氧基苯基）－2，2'：6'，2-三联吡啶），通过红外光谱和元素分析对该配位聚合物进行了结构表征，用X射线单晶衍射测定了晶体结构。

The compositions of complexes were determined as, by chemical and elemental analyses, Mn2CI2, Mn2Cl2, Cu2Cl2-2H2O, Cu(NO3)2-H2O, Cu(CH3COO)2, Zn2Cl2, Zn2(NO3)2-4H2O,ZnSO4 and Zn4(NO3)2, respectively. These complexes were characterized by IR,'H NMR and XPS. The crystal structures of these complexes were determined by single crystal X-ray diffraction techniques. The thermstability of the complexes was investigated by TG-DTG and the processes of their thermal decomposition were speculated. The constant-volume combustion energies of complexes, cU, were determined by a precision rotating bomb calorimeter at 298.15 K. Their standard enthalpies of formation, Hm, were calculated respectively. Finally, their biological activity was researched after the bactericidal activity was determined by selection of 1-2 bacteria.

通过化学分析、元素分析确定化合物分子组成分别为Mn_2Cl_2，Mn_2Cl_2，Cu_2Cl_2·2H_2O，Cu(NO_3)_2·H_2O，Cu(CH_3COO)_2，Zn_2Cl_2，Zn_2(NO_3)_2·4H_2O，ZnSO_4和Zn_4(NO_3)_2；借助IR、~1H NMR和XPS对化合物的键型特征进行了表征，运用X-射线单晶衍射分析法测定了个别化合物的晶体结构；以TG-DTG技术研究了化合物的热稳定性，阐明了它们的热分解机理；用精密转动弹热量计测定了化合物在298.15 K的恒容燃烧能，并计算了它们的标准燃烧焓和标准生成焓；选取1～2种病菌，初步测定了化合物的杀菌活性，进而研究了它们的生物活性。

A chiral phase transfer catalyst, N-benzyl quinine bromide, was synthesized from natural chiral compound. And 2,5-bimethyl-4-(3-nitrobenzene)-1,4-bihydrogenation pyridine-3--4-methyl formate (viz. nitrendipine) was synthesized by this chiral phase transfer catalysis, and characterized by elemental analysis, infrared spectrum,1H nuclear magnetic resornace, and X-ray single-crystal diffraction.Key words: ammonium; chiral phase transfer catalyser; crystal structure

通过对天然手性物质进行修饰合成手性相转移催化剂N-苄基溴化奎宁，并对目标分子2，5-二甲基-4-(3-硝基苯)-1，4-二氢吡啶-3-甲酸乙酯-5-甲酸甲酯进行不对称催化合成，并通过红外光谱和核磁共振氢谱对化合物进行了表征，用X射线单晶衍射法测定了该化合物的晶体结构。

This article mainly divides into three parts, The first part is the albite jade characteristic, uses traditional the gemology method conducts the research to the albite jade physical property as well as the structure, carries on the electron probe analysis to its chemical composition, and the discussion of its mineral component\'s chemical composition change carries on the SPSS statistical software; uses X powder crystal diffraction to determine its lattice parameter, mineral constituent\'s crystal structure conducts the research to the albite jade, carries on the analysis to the feldspar degree of order, and carries on the discussion to the albite jade\'s origin. The above method each other confirms mutually, confirms the data reliability.

本文主要分为三部分，第一部分为钠长石玉的性质，采用常规的宝石学方法对钠长石玉的物理性质以及结构构造进行研究，利用电子探针分析对其化学成分进行分析，并运用SPSS统计软件对其矿物成分的化学成分变化进行探讨；采用X粉晶衍射测定其晶胞参数，对钠长石玉中矿物组成的晶体结构进行研究，对长石的有序度进行分析，并对钠长石玉的成因进行探讨；上述方法彼此相互验证，以证实数据的可靠性。

(NH_4)_2GeF_6·H_2O is obtained as light-green single crystal from the low-temperature solvothermal reaction of GeO_2, NH_4VO_3 and HF in pyridine-water and characterized by the IR, elemental analysis, TG-DTA and single crystal X-ray diffraction.

化合物(NH_4)_2GeF_6·H_2O由GeO_2，NH_4VO_3和HF在吡啶-水体系中低温溶剂热条件下合成，并用IR、元素分析、TG-DTA和X射线单晶衍射进行了表征。

Solid complexes of rare earth picrates with the ligand 2,6-bis(benzimidazol-2-yl)pyridine have been synthesized and characterized by elemental analysis, IR and electronic spectra. The crystal and molecular structures of the complex [CeL22]·(CH3OH)3 have been determined by single crystal X-ray diffraction.

合成了稀土苦味酸盐与配体2，6-二(2-苯并咪唑基)吡啶的配合物，通过元素分析、红外光谱及电子光谱对配体及配合物进行了表征，并用X射线单晶衍射测定了配合物[CeL22]·(CH3OH)3的晶体结构。

That snake Alaric named Archbishop...

庇护。。。那个毒如蛇蝎的Alaric被命名为大教主。。。

You have done lots of magical things to be amazed at.

你做了很多神奇的事物感到惊讶。