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The property of the lowest excited triplet states of xanthone in acetonitrile has been investigated by using time-resolved laser flash photolysis at 355nm. The transient absorption spectra and the quenching rate constants of the excited xanthone with several amines have been obtained.

用时间分辨的激光闪光光解的方法在乙腈溶剂中研究了呫吨酮的激发三重态的性质，并得到了呫吨酮激发三重态和胺类、醇类以及酚类反应的瞬态吸收光谱和猝灭速率常数。

The use of an efficient adaptive absorbing boundary condition, which is concluded from Z transform absorbing boundary condition, further improved the accuracy of the calculated propagation constants.

基于大量精确的计算结果，本文总结出了一些实用的设计曲线和两个计算基片集成波导传播常数的经验公式。

When the reaction temperatures were 303.15, 308.15, 313.15, 318.15, 323.15 and 328.15 K, respectively, the apparent reaction rate constants of abietic acid were 0.0036, 0.0041, 0.0062, 0.0087, 0.011 and 0.0157 min^(-1), respectively. Its reaction activation energy was 50.29 kJ/mol.

枞酸的氧化反应温度为30，35，40，45，50和55℃时，表观速率常数分别为0.0036，0.0041，0.0062，0.0087，0.011和0.0157min^(-1)，表观反应活化能E为50.29kJ/mol。

When the reaction temperatures were 303.15, 308.15, 313.15, 318.15, 323.15 and 328.15 K, respectively, the apparent reaction rate constants of abietic acid were 0.0036, 0.0041, 0.0062, 0.0087, 0.011 and 0.0157 min-1, respectively.

松香的氧化反应温度为35， 40和45 ℃时，表观速率常数分别为0.0009， 0.0015和0.0025 min-1 ，表观反应活化能 E a为80.2 kJ/mol。

Using the one-atom theory, the electronic structures of Pt-electrocatalyst with fcc structure was determined as follows:(5dn)6.48 (5dc)2.02 (6sc)1.48(6sf)0.02. Compared to the result obtained by the first-principle method such as FP-LMTO, CASTEP, their results are in good agreement with each other. Comparing the calculations of physical properties such as lattice constants, cohesive energy and bulk modulus by OA method and first-principle method, the result obtained by OA method is in excellent agreement with experimental value, but the result obtained by first-principle method is not accordable. The relationship between the electronic structures and catalytic performance was explained qualitatively by OA method and first principle method according to its electronic structures. Because the d-orbital vacancies increases and static density is high around Fermi energy band, Pt has good catalytic performance.

摘 要：依据纯金属单原子理论确定面心立方结构电催化剂Pt的电子结构为(5dn)6.48(5dc)2.02-(6sc)1.48(6sf)0.02，与采用第一原理的FP-LMTO和CASTEP等方法所计算的电子结构相比较，其结果非常相近；由OA理论和第一原理方法计算的晶格常数、结合能、体弹性模量等物理参数进行比较，OA理论计算的结果与实验值较符合，而第一原理方法计算的结果与实验值相差较大；在此基础上用OA理论和第一原理方法研究了Pt的电子结构与催化性能的关系，由于d带空穴增多和费米能级附近态密度较高，导致金属Pt的催化性能很好。

Substituent Constants σp for Long Chain Alkyl and Alkoxyl Group s and their Correlation with Group Connectivity

磷化合物的长碳链烷基及烷氧基的σ~p常数与基团连通性

The catalytic reaction rate constant for amidopyrine in different conditions are also determined, and the rate constants agreed closely with the mechanism presented by us.

讨论了影响其催化反应速度的因素及条件；并对不同条件下氨基比林对亚铁氰化钾的催化反应速率常数进行了测定，所得结果很好的符合提出的反应机理。

The results show that the calculated values agree with the experimental data. The mean square amplitude of (110) plane surface exhibits anisotropic behavior. The calculated anharmonic constants indicate that the anharmonic effect of (111) plane is the smallest.

结果表明，计算值与已有的实验数据比较相符；(110)面的原子振动振幅表现出明显的各向异性；由声子频率随温度变化关系得到的非谐常数表明(111)面的非谐效应最弱。

To evaluate the antioxygenic property of the antioxidants, the oxidation reaction rate constants of sodium sulfite, sodium bisulfite and sodium pyrosulfite in aqueous solutions were determined.

为评价抗氧剂的抗氧化能力，测定了抗氧剂亚硫酸钠、亚硫酸氢钠及焦亚硫酸钠在水溶液中与氧反应的速率常数。

Methods: The above four methods have similar formula apar from the weighting constants.

上述四法之估计值公式颇为类似，其差异仅在加权常数的不同。

A historical region of southwest France between the Pyrenees and the Garonne River. The duchy of Aquitaine was joined with France after the marriage of Eleanor of Aquitaine to King Louis VII in1137, but its possession was disputed after her subsequent marriage to Henry II of England.

阿基坦法国西南部一个历史地区，位于比利牛斯山和加隆河之间，在1137年阿基坦的埃莉诺与国王路易斯七世结婚之后阿基坦公国加入法国，但当她再嫁英国亨利二世后，其归属权便受到争议

There are moments when I look at the smiling , happy faces of my expectant staff and wonder how they will cope when confronted by an outraged housemaster along with an unrepentant and recalcitrant bleached blond teenager in 18 years ' time .

有时候，我看着那些满怀期待的员工微笑，幸福的脸，想着当他们遇到一位愤怒的宿舍管理员和一位不知悔改，叛逆，而且将头发染成白色的18岁少年时，他们会如何处理。