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In this paper, the inhibition of growth by organic compounds, limited use of organic compounds, central metabolic pathways, and transport mechanism of the extremely acidophilic obligately chemolithoautotrophic thiobacilli are reviewed, as well as the current research progress in their genetic modification to use organic compounds.

主要对极端嗜酸性专性化能自养硫细菌有机质代谢的研究进展进行了综述,其中包括有机化合物的抑制作用、有机化合物的有限利用、中心代谢途径及物质的转运等,还包括专性化能自养硫细菌有机质代谢遗传改造研究的最新进展。

The new structure compounds (4, 54, 56) possessing vasodilatation were found. These compounds may be as lead compounds of developing antihypertension drugs. The synthesis method of peptidemimetics containing β-tetrahydro -carbolic acid was established for the first time.

在对上述化合物NO清除能力评价实验中,发现了一类具有舒血管活性新化合物(化合物4,54,56),这一类具有舒血管活性化合物的发现可以为研制高血压治疗药物提供先导化合物。

The relative contents of thujopsene and cedrol were higher in P.orientalis extracted by SFE and MSD methods.No monoterpenes was found in the compounds extracted by SFE and SDE,and the wood resin acids were the major compounds in the compounds extracted by SE.

改装简易蒸馏样品和超临界CO_2萃取物以及并时蒸馏萃取物中含量最高的组分是罗汉柏烯和柏木脑,但是超临界CO_2萃取物中未检测出单萜;索氏提取法样品中含量最高的组分为非挥发性的树脂酸类物质。

The main differences in chemical compounds related to the taste and flavorbetween cultured and wild prawns may be summerized as follows: 1 The content of quaternary bases in the extractives of wild prawn is higher than that of cultured prawn; 2 The content of fatty acids, C18:2ω6 is higher in the cultured prawn; 3 Many thiazole compounds were found in the odor concentrate of cultured prawn, azulene was found in the odor compounds of wild prawn; 4 The textrue of cultrued prawn meat is relatively weak.

综上所述,养殖对虾与天然对虾的尝味比较中主要差别是提取物组分的有机碱;对虾肌肉脂质比较结果是养殖对虾肌肉脂质中C18:2ω6含量特别高;对虾挥发性成分结果是养殖对虾中有大量的噻唑化合物,天然对虾存在薁类化合物;两类对虾质地比较的结果是养殖对虾质地不及天然对虾。

They had suppressed the cathodic process of carbon steel electrode. Their inhibition performance was also related with their molecule stereo conformation and electron configuration. Four of bis-(1, 1'-benzotriazoly)-α,β-diamide compounds linked via-CO 〓CO-chain were synthesized and certified by IR and 〓H-NMR. The minimum energy conformations of these compounds were obtained by MM2 forcefield program. The two benzotriazole moiety in BBT1 was more planar than in other compounds. This was beneficial in increasing the inhibition effects of BBT1. In 0.5M H〓SO〓 solution, BBT1 suppressed anodic corrosion reaction. In 3%NaCl solution, BBT1 suppressed both cathodic and anodic corrosion reactions. 1- [ (1'-imidazolly)-methyl] benzotriazole was synthesized by Mannich reaction.

合成了四个通过-CO〓CO-连接的双(1,1'-苯并三唑)-α,ω-二酰胺化合物,采用MM2分子力学程序优化了它们的分子结构,双(1,1'-苯并三唑)-α,ω-二酰胺化合物的缓蚀作用与其分子内两个苯并三唑单元的空间取向有关系,良好的平面性有利于苯并三唑二聚体的吸附和缓蚀作用,苯并三唑二聚体BBT1分子内两个苯并三唑单元近似平行,所以显示出较好的缓蚀效果。0.5M硫酸中BBT1主要抑制铜的阳极溶解的电化学反应;3%NaCl溶液中,BBT1对铜的阳极溶解和氧的阴极还原过程均有抑制作用,相比较而言对阴极过程的抑制作用更大一些。

In our research on study chemical reaction of active methylene compounds and brom-acetophenone. Because of brom-acetophenone is compound that contain carbonyl and halogen ,which will take place electrophilic substitution and nucleophilic addition. When active methylene compounds are ethyl acetoacetate and β-diketone, controlling reaction condition, we have found that mono-substitution's production and di-substitution's. production is isolated; active methylene compounds are acetoacetanilide and acetoacetanilide derivate, pyrrolidin-2-one derivants were obtained by substitution and close-ring reaction .but there is no report about it.

本文是让活泼亚甲基类化合物与溴代苯乙酮发生化学反应,由于溴代苯乙酮是含有羰基的卤代烃结构,它可以发生亲电取代和亲核加成反应,当活泼亚甲基类化合物为乙酰乙酸乙酯和β-二酮时,控制反应条件可以发生单取代和双取代两种产物;当活泼亚甲基类化合物为乙酰乙酰芳胺类化合物来反应时,溴代苯乙酮中的羰基与氨基会发生分子内的关环反应生成吡咯烷-2-酮衍生物,这在以前的研究中是没有发现的。

In some cases, its epimer 4 was also obtained. 22 compounds were synthesized, among them 18 were new.3. Using the intramolecular Pictet-Spengler reaction to form the pentacyclic skeleton of Et-743, the byproducts 25 were obtained under various conditions. The structures of them were determined to be 1, 2-dihydro-isoquinoline compounds, and the mechanism of the reaction was proposed.B. The synthesis of the analogs of Et-743Because of the failure of removing the protective groups in compounds 14, the synthetic strategy was adjusted.

对于苄基保护的羟基化合物13a,顺利得到化合物30,然后与不同的羧酸反应得到18个酯化合物33-50;对于苄氧羰基保护的氨基化合物13b,由于脱除保护基的化合物31在空气中不稳定,所以我们采取不经分离纯化,直接与羧酸反应得到酰胺化合物53-62,然后再分别对其C-21位的羰基进行还原氰基化,得到10个酰胺目标化合物63-72,另外,我们还对羟基转化为氨基的反应进行了探索。3。

To discover new strobilurin analogues with high pesticidal activity, a series of new strobilurin derivatives containing substituted pyrazole and pyrimide ring, which included 124 novel compounds (73 compounds containing substituted pyrazole ring and 51 compounds containing substituted pyrimide ring) were designed and synthesized. In addition, 36 new intermediates were synthesized. Their structures were characterized by 1H NMR and elemental analysis, partial compounds were characterized by MS and IR once again.

为了发现具有更好生物活性的新型Strobilurin类化合物,本论文在详尽总结文献的基础上,设计并合成了含吡唑和嘧啶环的新型Strobilurin类化合物124个,其中含吡唑环的新加热管型Strobilurin类化合物73个,含嘧啶环的新型Strob 加热管 ilurin类化合物51个;未见文献报道的中间体36个,所合成的化合物经过1H NMR、IR、LC-MS或元素分析等确定了结构。

In order to reveal the nature of reducibility of organic compounds and find theoretical basis for the selection of organic reductants, the electronic structure of studied organic reductants and related organic compounds has been calculated by means of HMO method、CNDO/2 method in quantum chemistry. It was discovered that the energy of the highest occupied molecular orbital of organic compounds has best correlation with their reducibility, and theoretical criterion for reducibility of organic compounds was presented.

为了揭示有机化合物还原性的本质,为有机还原剂的寻找提供理论依据,应用量子化学HMO法、CNDO/2法计算分析了研究的有机还原剂及相关有机化合物的电子结构特性,发现有机化合物的最高占据分子轨道HOMO能量与其还原性之间具有最好的相关性,据此提出了有机化合物还原性的理论判据。

Generally the catalysts have high activity and good selectivity. At present the coupling reactions of organoborahes with terminal olefins s acid chlorides and aryl halides play an important synthetic approaches in organoborane chemical. The catalysts can be used by many kinds of organometal compounds such as: irons cobalt nickel ruthenium rhodium palladiums titaniums zirconiums tins indium and lithium organic compounds; The achievement has been amazed in preparing of unsaturated or saturated compounds and in synthesizing of natural products bioactive molecules and chiral compounds.

目前,卤代烃与不饱和烃的偶联反应和有机硼试剂与酰卤和卤代烃的偶联反应已成为有机合成的研究热点,此类反应可用铁、钴、镍、钌、铑、钛、锆、锡、铟、锂等多种有机金属化合物来催化,用于形成含饱和或不饱和C-C键的化合物,并已在天然产物、液晶、具有生理活性物质和手性化合物的合成中应用。

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In her eyes, because that is the doorway toher heart * the place where love resides.

女人的漂亮必須從她的眼睛中去看,因為那是她心靈的窗戶和愛居住的地方

I will send some postcards to you.

我会向你发送一些明信片。

Of aesthetics and the definiteness of its content and leads to its immaturity and decline .

它的不确定,直接影响美学学科定位乃至研究内容的确定,导致美学学科的不成熟和衰微。