查询词典 chitosan

objective:with the local lobster shell as the raw material,we inquire into the abstraction and preparation of chitin and chitosan to develop a new raw material resources for chitosan.methods:use methods such as take off protein,calcium,colour,deacetylate and purification to prepare chitosan to study deacetylate degree,molecular weight and other characters of chitosan,then compare with infrared spectrum of bio-chemical chitosan on market.results:the chitin and chitosan obtained from lobster shell are 14.8% and 8.9%, respectively.

目的：以地产龙虾壳为原料，探讨其甲壳素的提取和壳聚糖的制备方法，以开发壳聚糖制备的新原料资源。方法：用脱蛋白、除钙、脱色、脱乙酰基、纯化等方法制备壳聚糖，研究其壳聚糖的脱乙酰度、分子量等性质，并与市售生化级壳聚糖的红外光谱进行比较。

CA-CTSs including N,O-carboxymethyl chitosan,N,O-1-carboxyethyl chitosan (N,O-1-CEC),N,O-2-carboxyethyl chltosan(N,O-2-CEC),N-carboxymethyl chitosan and N-1-carboxyethyl chitosan(N-1-CEC) are quaternized using active quaternary salts prepared in laboratory.5 series including 25 kinds amphoteric chitosans characterized with polymeric ampholyte,in which 24 kinds are synthesized firstly,are obtained, 2-Hydroxypropyl dimethylbenzyl ammonium N,O-(1-carboxyethyl) chitosan chloride (GDMBA-N,O-1-CEC) is hydrolyzed into serial low molecular weight GDMBA-N, O-1-CEC with acid as catalyst and microwave as assistant instrumentality innovately.

以合成的活性季铵盐改性了N，O-羧甲基壳聚糖、N，O-1-羧乙基壳聚糖(N，O-1-CEC)、N，O-2-羧乙基壳聚糖(N，O-2-CEC)、N-羧甲基壳聚糖和N-1-羧乙基壳聚糖(N-1-CEC)等羧烷基壳聚糖，得到5个系列25种具有两性高分子电解质特征的新季铵化羧烷基壳聚糖，其中24种为首次合成；创新提出以微波辅助酸催化的方法催化2-羟丙基二甲基苄基-N，O-(1-羧乙基)壳聚糖氯化铵(GDMBA-N，O-1-CEC)水解，得到了低分子量的GDMBA-N，O-1-CEC。

The results show that a little amount of heteropolymolybdovanadophosphate can remarkably speed the degradation, the best conditions of the oxidative degradation of chitosan with hydrogen peroxide catalized by heteropolymolybdovanadophosphate in homogeneous condition are as follows: the ratio of catalyst and chitosan is 1 to 10, concentration of hydrogen peroxide is 0.15%, the temperature is 80℃, reaction time is 2h. 0.2g chitosan was degraded under the best condition and the molecular weight by viscometry was degraded from 1460000 to 7812. then water-soluble chitosan was obtained by this method; The heterogeneous method is a high efficient way, the best condition of this method are as follows: the ratio of catalyst and chitosan is 2 to 100, the volume of 30% hydrogen peroxide is about 3mL, the temperature is 90℃, reaction time is 5min～30min.

研究结果表明，适量磷钼钒的存在可显著加速壳聚糖的降解，磷钼钒催化过氧化氢均相氧化降解壳聚糖的适宜反应条件是：催化剂与壳聚糖的质量比为1∶10、过氧化氢百分浓度为0.15％、反应温度为80℃、反应时间为2h，在此条件下对0.2g溶解在100 mL 0.5％稀醋酸中的壳聚糖进行降解，可使壳聚糖的粘均分子量由原来的146万下降到七千多(7812)，成为水溶性低分子量壳聚糖，从而达到应用的要求；在异相条件下以磷钼钒为催化剂催化过氧化氢氧化降解壳聚糖是一种高效快速的方法，此法降解壳聚糖的最佳反应条件是：催化剂与壳聚糖的质量比为2∶100；30％过氧化氢的用量为3mL左右；反应温度为90℃、反应时间为5min～30min。

Chitosan had been modified by polyacrylate sodium, glularaldehyde, and NaBH4, respectively, which afforded three kinds modified chitosan: polyacrylate sodium modified chitosan (CIS- PA4) chitosan bead and pentamethylene diamido crosslinked chitosan bead (CTSB- G- Hy). The adsorption properties of CTS-CTSB and CTSB-G-Hy were studied by L25(56) orthogonal experimental design. They show high adsorption activities for Pb2+ in solution. The highest removal efficiency of Pb2+ for CTS-PA4, CTSB and CTSB-G-Hy is 94%, 96% and 93%, respectively. The results showed the adsorption property of CTSB is the highest. The CTSB- G- Hy has good mechanical property, acid-resistance and alkali-resistance.

第二部分壳聚糖的改性及其对水溶液中铅离子的吸附性能研究以壳聚糖为原料制备了三种改性吸附剂——聚丙烯酸钠改性壳聚糖(CTS——PA_4)、珠状壳聚糖凝胶树脂和戊二氨交联珠状壳聚糖凝胶树脂，着重考察了CTSB—G—Hy的制备条件，并考察了三种吸附剂吸附6.3mg/L铅离子水溶液中铅的最佳使用条件，结果表明对CTS—PA_4而言当pb~(2+)溶液的pH在4～6.5之间，吸附剂用量为5g/L，吸附时间为1h时pb~(2+)去除率高于94％，CTS—PA_4可在酸性条件下使用，在碱性条件下依然有效但处理效果较差；CTSB对pb~(2+)具有很好的吸附能力吸附剂用量为5g/L，吸附时间为1h时处理效果极佳，pb~(2+)去除率高于96％；CTSB—G—Hy对pb~(2+)具有一定的吸附能力，吸附剂用量为3g/L，吸附时间为1.5h时处理效果最佳，Pb~(2+)去除率高于93％，而且CTSB—G—Hy的机械强度高，耐酸碱性强，可在较宽的pH范围内使用。

Two kinds of water-soluble biomimetic chitosan derivatives with a phosphoramide linkage between glucosamine and choline were prepared through Atherton-Todd reaction under the mild conditions, including zwitterionic phosphorylcholine bound chitosan and acetyl-phosphorylcholine bound chitosan with positive charge. The interaction between chitosan derivatives and calf thymus DNA were inversigated by UV alsorption spectra and circular dichroism spectra.

采用Antherton-Todd反应制备了两种水溶性的磷酰化壳聚糖仿生衍生物：两性的N-磷酸胆碱磷酰化壳聚糖和带正电荷的N-乙基磷酸胆碱磷酰化壳聚糖，并用紫外吸收光谱和圆二色光谱研究了两种胆碱磷酰化壳聚糖衍生物与小牛胸腺DNA的相互作用。

Congregation obtained after chitosan k and a treatments showed more tightness than sediments obtained without chitosan treatment, sediments after chitosan b and c treatments were network in structure. Mixed systems of pectin, protein and polyphenol were applied for studying a simulated system of kiwifruit juice. It was shown that the aggregates of pectin molecules in pectin solution were dispersing tubular globules. Particles in mixed solution of pectin and bovine serum albumin had two states: one was circular in photo, the other contained single particle or aggregates of several particles. Pectin decreased the interaction between protein and polyphenol and strengthened the stability of mixed solution of pectin, protein and polyphenol. Chitosan flocculated mixed solution of pectin, protein and polyphenol, and the floccule was white, having a network structure.

用果胶-蛋白质-丹宁酸混合体系作为猕猴桃原果汁的模拟体系研究结果表明：1、果胶溶液中果胶分子聚集物呈中空球形均匀分散；2、果胶／牛血清白蛋白混合溶液中的球形粒子有两种：粒子中央光线可透过，照片上呈环形；粒子的中央包含有单个或多个球形粒子的聚集体，认为粒子的中央是蛋白质，外层是果胶；3、果胶的存在抑制或减弱了蛋白质-丹宁酸之间的相互作用，果胶起到防止蛋白质-多酚产生沉淀的作用，增强了溶液的稳定性；4、壳聚糖加入果胶-蛋白质-丹宁酸混合溶液中时，可以絮凝果胶-蛋白质-丹宁酸混合溶液，溶液中出现白色的网状絮凝物。

Themain contents of this dissertation are as follows:(1) The quality analytiedal results of chitosan are as follows: water for 15.205%;degree of deacetylation 92.671%; the weight average relative molecular weight ofchitosan 195900; the viscosity average relative molecular weight of chitosan 194100;and the decomposing temperature 298℃. The infrared ray IR spectra of chitosanshows that the feature-absorbing band of chitosan amido was 1601cm~(-1), that ofβ-indican bond was 986cm~(-1). The results of the X-ray diffraction of chitosan indicatesthat its degree of deacetylation and degree of crystal are both big.

本文的主要内容如下：(1)对壳聚糖的质量进行分析，其水份为15.205％，脱乙酰度为92.671％，重均分子量为195900，黏均分子量为194100，分解温度为298℃，壳聚糖的红外光谱表明，壳聚糖—NH_2的特征吸收峰为1601cm~(-1)，β-糖苷键的特征吸收峰为986cm~(-1)，壳聚糖的X-衍射图表明壳聚糖原料的脱乙酰度和结晶度均较大。

The specific properties of materials, such as the palate adhesion, dynamic cruor, anti-bacterial and the degradability of lysozyme, were studied, which provide valuable data for further application. The main creative ideas are listed as follows:(1) The water-retention chitosan/poly vinyl alcohol blend fiber was obtained by coagulating in 10％ NaOH/ethanol solution, and the blend and crosslink due to GA can enhance the mechanical properties of fiber;(2) The controlled degradable chitosan/gelatin blend fiber was obtained by solution filature, and the mechanical properties were improved;(3) The N-acylchitosan with the different degree of substitution were successfully prepared, and the relationship between structure and properties was estabilished;(4) By a new solvent system of 6％ NaOH/4％ urea for cellulose, the blood anti-coagulant function films were prepared by blending cellulose with chitin;(5) In the same solvent system above mentioned, the anti-bacterial blend films based on cellulose and carboxymethyl-chitosan were prepared, and the relationship of DS and the anti-bacterial property was concluded;(6) The controlled degradable chitosan films was obtained by the chemical crosslink.

本论文的主要创新点：（1）以NaOH水溶液／无水乙醇为凝固液，采用溶液纺丝法制备出保水性壳聚糖／聚乙烯醇纤维，共混和戊二醛交联极大提高了壳聚糖纤维力学性能；（2）用壳聚糖和明胶共混，以溶液纺丝法制备出可控降解的壳聚糖／明胶纤维，并大幅度提高了壳聚糖共混纤维的干、湿态抗张强度；（3）确立了不同取代度N-酰基壳聚糖的合成方法及其膜的结构与性能的关系；（4）利用纤维素新溶剂6％NaOH／4％尿素制备出抗凝血性纤维素／甲壳素共混膜；（5）利用上述纤维素新溶剂制备出抗菌性纤维素／羧甲基壳聚糖共混膜，揭示了羧甲基壳聚糖取代度与抗菌性能的关系；（6）制备出可控降解壳聚糖交联膜。

The result shows that the chitosan can increase the the amount of effective tiller, then the yield of both of cultivars of Zizania caduciflora is enhanced markedly, and the concentration of 45mg/L of the chitosan has the best effect. The activity of POD in leaves and the content of sucrose in product can be increased after using the chitosan, and the change of the chlorophyl content could be abated and the effect has a long duration, and the furthersome effect of chitosan on the activities of the CAT and the APX lasts in the prophase and the midphase of growth.

结果显示壳聚糖的使用对单季茭和双季茭的有效分蘖数都有增加作用，从而明显提高茭白产量，并且均以45mg/L的浓度效果最好，其使用能显著提高两种类型茭白生长期叶片中POD酶的活性以及茭体中的蔗糖含量；壳聚糖对茭白叶绿素有缓和变化波动的作用且持效久，对茭白CAT、APX酶活性的促进作用只在处理前中期有效；而对株高和A.A。

And the PLA/Chitosan/ACP barriers with additional 2 wt% chitosan still maintain 56.58 % antibacterial ability after eightieth day. The different composition of PLA/Chitosan/ACP composites was prepared by water washing solidification from NMP/water/lactic acid consolvent. After storing at room temperature for 48 hours and taking it out to obtain a shapable composites. To investigate the influence of ratio of composition with the shapable property of composites, it was analyzed by Rheometer, TGA, AFM, XRD. The result of the different APC content had different effect both water content and yield stress of composite materials. The yield stress decreased with ACP content while increases. It was derived that ions, released from ACP interact with amide groups of chitosan to form water-absorbing ionic clusters through chelating or electrostatic attraction.

另外，以聚乳酸/几丁聚醣作为基材并添加不同比例的非晶型磷酸钙，经过水洗固化后可得白色片状沉淀物，於室温下静置48小时后，复合材之体积呈现膨胀且具有可塑形之特性，以热重分析仪与流变仪分析样品之含水率与屈伏应力，结果显示不同ACP含量对复合材含水率与屈伏应力具有消长变化，而PLA/Chitosan/ACP之可塑程度与其所吸收之水份多寡有关，推测可能机制为ACP磷酸钙盐解离后之金属离子与几丁聚醣之胺基透过螯合作用或静电吸引之交互作用，形成具吸水性之离子团簇分散於疏水性之聚乳酸基材中。

Mr. Putin said there were signs of genocide against the Ossetian people.

普京说，有迹象表明对南奥塞梯人进行了种族清洗。

What I'm trying to say, Tristan is...

特瑞斯坦。我想说的是。