查询词典 catalyst

It was found that the MCM-22 zeolite catalyst prepared by the VPT method not only showed good crystallinity and high BET surface area, but also better crystal growth orientation and denser structure.The catalyst showed high activity, selectivity and good stability for alkylation of benzene with propylene, especially better selectivity to the end product cumene.The shaped MCM-22 zeolite catalyst prepared by the VPT method has good prospect of industrial application in synthesis of cumene.

结果表明：汽相法制备的MCM-22分子筛催化剂不仅具有较好的结晶度和较高的微孔表面积，而且具有更好的晶体生长取向性和更加致密的结构；在烷基化反应中也具有很好的活性、选择性和稳定性，特别是对目的产物异丙苯的选择性明显高于水热法合成的催化剂，在异丙苯合成上具有很好的应用前景。

A process for preparing cycloolefin features that in the presence of catalyst slurry containing metal Ru catalyst, water and metallic sulfate, the mononuclear aromatics is partially hydrogenated by hydrogen, and includes a step to control the activity of catalyst.

一种生产环烯烃的方法，该方法是在含有金属钌催化剂、水和金属硫酸盐的催化剂浆液存在下用氢部分加氢单环芳烃进行该方法，其中包括控制催化剂活性的步骤。

Vapor makes the activity and selectivity of the catalyst decrease a great deal yet this disvalue is reversible; When the elemental sulfur and vapor exist simultaneity in the system, it might generate H〓S and S on 〓 catalyst since the anti-Claus reaction, but this phenomena is not observed on CoS〓-TiO〓 catalyst showing that sulfides could check the anti-Claus reaction.

对硫化物催化剂CoS〓-TiO〓来说，助剂La和Ce的引入对CoS〓-TiO〓催化剂的氧化还原性能有一定影响，硫化物催化剂平均粒径要小，但助剂并未改变催化剂的电子结构，对于氨分解克劳斯反应的活性改变不大明显。

A series homopolyme of ethylene synthesised by metallocene catalyst was analyzed by the high temperature gelatin permeation chromatography. The results showed that the molecular weight distribution changed not too much when the ratio of Al/Ti ranging between 1000 and 4000, while the molecular weight distributed increased from 2.48 to 2.81 when the ratio ranging between 4000 and 7000; catalyst D had the lowest activity to be used as asymmetric metallocene catalyst; the curve of molecular weight moved much to the left with the increases of temperature and two active centres appeared when the temperature is 70℃.

通过高温凝胶渗透色谱对茂金属催化合成的一系列乙烯均聚物进行了分析，可以看出Al/Ti比从1000变到4000时，分子量分布曲线图变化不大，而从4000变到7000时，变化相当大，分布宽度从2.48增至2.81；催化剂D的活性最小，可作为非对称性茂系金属催化剂；该聚合体系分子量的大小受聚合温度的影响很明显，随温度的升高，分子量分布曲线图向左发生很大位移，在聚合温度为70℃时存在两个活性相当的活性中心。

Based on KT-01 nickel catalyst, the scientific research personnel of our company and the expert group of the former subject group from Lanzhou University made joint efforts to tackle the key problems and successfully developed the 2nd generation of KT-02 supported nickel catalyst through in-depth study on the technical formula, catalytic activity and other mechanisms and taking modified carrier, the properties of acid and alkali, the degree of decentralization of active ingredients on the carrier surface, and fundamental breakthrough has been achieved on the aspects of catalytic activity, specific surface area, bulk density, etc, and the technical defects of KT-01 nickel catalyst are completely overcome; the catalytic activity becomes higher, the starting temperature becomes lower, the industrial serviceability temperature is lowered and the yield increased.

在KT-01型镍催化剂的基础上，我公司科研人员与兰州大学原课题组专家联合攻关，通过对工艺配方及催化活性等机理的深入研究，从载体改性、酸碱性、活性组分在载体表面的分散程度等方面入手，成功开发出第二代KT-02负载型镍催化剂系列产品，在催化活性、比表面积和堆密度等方面都有根本性突破，彻底克服了KT-01型镍催化剂的技术缺陷，使催化活性更高、启动温度更低，降低了工业使用温度，提高了生产收率。

On the NiO/SiO〓 catalyst prepared by IM, the main hydrogenation product of MA was SA, the activity and selectivity were almost no relation with the nickel content and nickel species 3. Summarizing the characterization and activity evaluation of the catalysts, we concluded: On nickel based catalyst, when NiO was crystallite, and the Ni〓 that was prepared by reducing, hydrogenation of the MA could lead to SA but not to γ-BL; when NiO was cluster and had a properly interaction with the support, the Ni〓 prepared by reducing, could hydrogenate MA to SA then to γ-BL. When NiO cluster and crystallite were both existed on the catalyst, the hydrogenation products were mixture of SA and γ-BL, and the amounts of SA and γ-BL were related with the ratio of cluster and crystallite.

综合催化剂的表征和活性评价得出：当镍基催化剂上氧化镍以结晶态存在，经氢还原后的零价镍可使顺丁烯二酸酐加氢得到丁二酸酐，丁二酸酐难以进一步加氢为γ-丁内酯；当镍基催化剂上氧化镍以簇团形式存在，与载体之间有适当的相互作用时，经氢还原后的零价镍可使顺丁烯二酸酐加氢得到的丁二酸酐进一步加氢为γ-丁内酯；若催化剂上氧化镍既有结晶态又有簇团形式时，随二者含量比例不同而得到丁二酸酐和γ-丁内酯的混合物。

The experimental results indicate that methanol synthesis gas can be produced by steam gasification of lauan sawdust at 680℃ without catalyst addition. However, in the presence of steam reforming catalyst (RKNR+RKS-1), weight ratio of catalyst to dry wood sawdust =1, methanol synthesis gas can be produced at 580℃.

实验结果显示：未加触媒时，本屑在680℃气化所产生的气体可用於甲醇的合成；而使用蒸气重组触媒(RKNR+RKS-1)，在580℃、触媒与全乾木屑的重量比为1时，所产生的气体即可用於甲醇的合成。

An extremely high temperature of anode humidification is also unreasonable; as a result, when the current density is high, the liquid water should be injected directly into anode gas channel to guarantee both high inlet H〓 concentration and well-humidified membrane. 4. The utilization of Pt in the cathode catalyst layer will decrease with the increasing current density; as a result, based on the principle of maximal Pt utilization, the catalyst layer can be designed much thinner or not uniformly in the catalyst distribution.

而在此截面上，交指型流场燃料电池阳极侧的液态水饱和度的极值位置并不确定；在电池阴极处，液态水饱和度的极值总是出现在z=0.002m处的气体扩散层和膜的界面上，并且该处的液态水饱和度沿x方向存在一个最大值，与此相应的氧气的质量浓度分数在该处达到极小值，因此极限电流密度将首相出现该处，但总体来说液态水饱和度沿x方向的分布较为均匀。4。

Uses: Suitable for gas adsorption, the decolorization and refining of catalyst carriers and monosodium glutamate, citric acid and oil; used in catalyst of phosgene synthesis; as catalyst carrier for high mercury chloride, vinyl acetate synthesis, etc.

用途： 适用于气相吸附，催化剂载体和味精、柠檬酸、油类的脱色、精制以及光气合成用的触媒、氯化高汞、醋酸乙烯等合成工艺的触媒载体。

Therelationship of the amount of catalyst and the ee% of product was seen to be negative nonlin-ear. Catalyst 3 was used in the enantioselective addition of diethylzinc to aromatic aldehydesand gave good results. The configuration of products was determined by the configuration ofthe catalysts' chiral carbon linked with hydroxy group. Using β- amino alcohols bearing only one chiral center as catalysts for the enantiose-lective addition were studied. D-N, N-dialkyl-2-amino butanol gave poor catalytic effect be-cause of their structure. The configuration of the product is the same as the catalyst. Anotherkind of β- amino alcohols - phenylglycine derivatives and valine derivatives have chiralcenter on the carbon linked with amino group. Catalyzed by-phenylglycine derivatives 6,7, 9, 10, the reactions gave satisfied results. The optical yields exceeded 80%.

在探讨了含有两个手性中心的β-氨基醇之后，选择了只有一个手性中心的β-氨基醇，一是手性中心为连羟基的手性碳原子：D-N，N-二烷基-2-氨基丁醇；二是手性中心为连氨基的手性碳原子：D-苯基甘氨酸衍生物和L-缬氨酸衍生物。D-2-氨基丁醇的催化效果不太好，这与其结构的空间位阻较小有关系，反应产物与连羟基手性碳构型一致；由苯基甘氨酸和缬氨酸出发合成五种β-氨基醇6-10，研究了不同ee％的-6作用下的二乙基锌-苯甲醛加成反应，发现该催化剂具有不对称放大效应；-7，9，lO的催化效果也比较令人满意，光学产率80％以上，所得产物构型与催化剂构型一致。

What was it that made you want to change sider ?

是什么使你临阵倒戈？

I don't know what he wants, but let's play along with him.

我不知道他要干什么，可我