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The experimental results were followed:(1) LY402 could degrade chlordane in an aerobic environment. The percent of chlordane degradation at 1.0 mg /L was more than 94% after 4 days at 30℃. When exposed to a concentration as high as 10.0 mg/L, LY402 could still degrade 61% of chlordane. There was no obvious difference between cis-chlordane and trans-chlordane in the mixture on biotransformation rate.

实验结果表明:(1)在好氧条件下,LY402能够有效降解氯丹,对于1mg/L的顺式氯丹和反式氯丹混合物,在30℃下,经过4天的好氧降解,其总降解率接近95%,进一步将氯丹混合物的总量增加到10.0mg/L,其4天的总生物降解速率仍然能够达到64%,其中,顺式氯丹和反式氯丹的生物降解速率没有明显区别。

In addition, some modifications on several computational methods are also presented. Using LMTO method the electronic structure of several systems are studied, and some results are obtained. They are: The ideal Nb (100) surface has three surface states, the multi-layer relaxed surface has two surface states. The surface energy of the ideal surface is higher than that of the relaxed surface, that means that the multi-layer relaxed surface is more stable than the former one, which supports the LEED results. The mono-layer relaxed Ag (111) surface is the most stable one among several" stable surface models"presented by several researchers. The surface energy of Ag (111) surface is higher than that of surface Ag (001), which supports some experimental results such as different reaction rate at different surface orientations for the same material. The surafce states of Si (111) surface not only locate near the Fermi level, but also in the valence band, which agrees well with Cohen's conclusion. Si (111)-H is an effective model for analysing the surface states and H adsorbed on the back surface is a good method for improving the convincingness of the results obtained on thinner slab models. The surface stability depends on three different kinds of MoSi〓(001) surfaces, the surface with mono-layer Si is the most stable one, and the surface with Mo at the first layer is the most unstable one among them. These are consistant with the Kemoda's experimental results. The valence bands of clean or K adsorbed CdTe (111) surface agrees well with the synchrotron radiation studies. The surface of CdTe (111) consists of four kinds of surface models which show different surface electronic structures and different surface structure stabilities. The conclusion agrees well with Wu's experimental work. The different absorbed alkali metals on the CdTe (111) surface give different adsorption characteristics which have relations not only with the valence electrons, but also with the core ones of the alkali metals. The electonic structures of Si-C alloys are different from that of Si-Ge alloys, and the energy band gaps of Si-C alloys do not increase linearly with Carbon concentration, our conclusion supports Alexander's results, but conflicts with Soref's one.

现分述如下: LMTO方法及其应用方面:1)通过对Nb(100)表面电子态分析发现清洁理想表面有三个表面态,多层弛豫表面有两个表面态;表面能大小说明多层弛豫表面更稳定,支持了LEED结果。2)通过对采用不同方法获得的几种不同Ag(111)表面稳定结构的表面能计算分析,给出了单层弛豫表面为Ag(111)表面的最稳定结构;从Ag(111)单层弛豫表面和Ag(001)表面的表面能比较,发现了Ag(001)表面表面能要比Ag(111)小的,表明了同种物质不同表面取向将表现出不同物理、化学性质,这是与实验中得出的结论是吻合的,3)通过对Si(111)表面态分析,不仅发现了Si(111)表面不仅具有居于费米能级附近的悬挂键所对应的表面态,而且还有很多表面态位于价带能量范围内,与Cohen等结果一致,H饱和slab模型背表面相当于增加了slab层的厚度,是一有效的变相增加slab层厚的方法,弛豫表面较清洁理想表面价带谱们低能端的少许移动,预示着总能降低,说明弛豫表面较清洁理想表面稳定。4)MoSi〓具有三种表面,从费米能级上态密度值大小得到单层Si表面最稳定,Mo原子为表层原子的表面最不稳定,双层Si原子表面居中的结论,这与Kemoda等人实验结果是一致的。5)通过对CdTe(111)表面表面电子态、表面结构稳定性及表面H、碱金属吸附的电子结构系列研究,不仅得出了CdTe(111)清洁及碱金属K吸附价带谱与同步辐射光电子谱相吻合的结果,而且发现了CdTe(111)表面具有四类不同原子近邻特征,表现出四类不同的表面结构及电子结构特征:不同表面态分布、不同的表面结构稳定性(表层原子与次层原子成三键有一悬挂键的表面要比表层原子与次层原子成一键有三悬挂键稳定(与Wu等人实验结果一致))、不同的H吸附特性。

The effects of different factors on the laser-induced graft polymerization on the PET surface were analyzed, and the mechanisms were discussed. The factors were: 1 Monomers with smaller molecules resulted in better modification than polymeric monomers. Acrylamide monomer was chosen as hydrophilic modifier finally; 2 Higher concentration of the monomer solution favored the graft reaction; 3 With the increasing laser fluence, the surface hydrophilicity of PET films increased at first, then decreased. More laser pulses led to a more hydrophilic surface; 4 Benzophenone as a photosensitizer hindered the graft polymerization; 5 The homopolymer retardant of ammonium iron sulfate hexahydrate in a proper concentration retarded the formation of homopolymers and promotes the graft copolymerization; 6 The solvent of monomer solution also affected the graft reaction. Different solvents functioned in different ways. Ethanol can promote the graft reaction because of the activity of hydrogen in its structure; 7 pH value of the monomer solution affects the polymerization rate, and a lower pH value was favorable to the graft reaction.

这些影响因素的作用分别为:1小分子单体的表面改性效果好,确定以丙烯酰胺为亲水性改性单体;2较高的单体溶液浓度有利于接枝反应;3激光能量密度增大,薄膜表面亲水性先显著增强,后又减弱;激光脉冲次数越多,改性后表面亲水性越强;4光敏剂BP对PET表面接枝聚合反应有阻碍作用;5适当浓度的均聚物抑制剂六水合硫酸铁铵能减少单体均聚物的生成,促进接枝聚合;6单体溶液的溶剂也影响接枝聚合的反应进程,不同溶剂的影响作用原理不同,含较活泼氢的乙醇能促进接枝反应;7溶液pH值影响单体聚合速率,pH值较低有利于接枝反应。

The company invests mount a horse the project of form a complete set of cooking of defer of 1 million T hydrogenation of 800 thousand T refines and 30 thousand T is sulfureous reclaim project, quality of farther promotion product, reclaim effectively the 2 oxidation sulfur in waste gas, have major economic benefits and social benefit; to invested many yuan 6000 to build two dry gas to make hydrogenous device, make waste gas reclaims rate achieved 95%, reduced the discharge capacity of waste gas substantially, reduce; of the cost that make hydrogen to be in greatly at the same time more than heat, beyond pressure, of more than gas used a respect integratedly to carry out 22 technical reformation, make enterprise ton the banner level that oily treatment specific power consumption reached industry of domestic person of the same trade.

公司投资上马了100万t延迟焦化的配套项目80万t加氢精制和3万t硫磺回收项目,将进一步提升产品质量,有效回收废气中的二氧化硫,具有重大的经济效益和社会效益;投资6000多万元建设了两套干气制氢装置,使废气回收率达到了95%,大幅度降低了废气的排放量,同时大大降低制氢成本;在余热、余压、余气的综合利用方面实施了22项技术改造,使企业吨油加工能耗达到了国内同行业的领先水平。

This project studies the scale-dependent deformation behavior of the metal matrix composite, the void nucleation and void growth mechanisms at the micron/submicron scale. The main results are:(1) In prophase, growth and coalescence of the void embedded in the graded matrix are analyzed in detailed;(2) Based on the infinite solid model containing a micro-void, coupling effects of the void shape and the void size on the void growth are studied carefully, the results show that it seems to exist a critical equivalent void radius, which is associated with the material length. When radius of a microvoid is close to or smaller than the critical void radius, the micro-void growth rate is essentially eliminated;(3) The coupling effects of the particle shape and size on the mesoscopic stress fields within the particle and matrix are also investigated by introducing the conception of inclusion/matrix interfacial energy. The results show that the stress concentration factors within the particle and on the matrix/particle interface are also strongly size-dependent,so the void nucleation mechanism is size-dependent.(4) By employing a specific orthogonal curve coordinate frame and a 'kernel function' conception, a 'unified method'solving the spheriodal and spherical void problems is suggested; by this unified method, size-dependent plastic potentials of the porous materials containing the spheriodal or spherical voids are obtained, which extend the traditional Gurson model for the spherical void and GLD model for the spheriodal voids to the micron scale.(5) Based on the RVE model containing the spheriodal or spherical particles, the influences of the particle shape and size on the size-dependent mechanical behavior of metal matrix composite are studied.

中文摘要:本项目对金属基复合材料在微细观尺度下的尺度相关变形行为、孔洞形核及长大的机理和模型进行了研究,取得了如下主要结果:1)在前期研究中,探讨了基体的梯度分布对孔洞长大和聚合的影响;2)基于含孔洞的无限大体模型,探讨了孔洞形状和孔洞尺寸对其长大的耦合作用,结果表明:可能存在一个与材料特征长度相关的临界孔洞尺寸,当椭球孔洞的等效半径小于临界孔洞半径时,孔洞的长大受到明显抑制;3)通过引入基体/夹杂界面能的概念,分析了夹杂尺寸、夹杂形状对材料细观应力场的耦合影响,结果表明:颗粒内部和界面上的应力集中因子强烈地依赖于夹杂的尺寸和形状,因此,孔洞的形核机理是尺寸相关的;4)采用一种特殊的正交曲线坐标系和引入"核函数"的概念,"统一"地得到了含椭球和球形孔洞的材料的尺寸相关塑性势,它将传统的Gurson球形孔洞模型和GLD椭球孔洞模型推广到微尺度范围;5)基于含椭球和球形夹杂的体胞模型,初步研究了夹杂形状、夹杂尺寸对金属基复合材料尺寸相关力学行为的影响。

At 900℃, alloy M41 and K3 display similar isothermal oxidation rates which are lower than the oxidation rates of their aluminide coatings. At 1050℃, alloy M41 has a lower isothermal oxidation rate and better scale adherence than K3, and the oxidation rates of the two alloys are higher than that of their aluminide coatings.

900℃下M41和K3合金的氧化增重近似,都比气相渗铝涂层的小,氧化膜均无明显脱落。1050℃下M41合金的氧化增重小于K3合金,氧化膜脱落较轻,K3合金氧化膜脱落严重;该温度下两合金的氧化增重都大于渗铝涂层。

It was decided at this meeting that the investigation of gelatin and oxypolygelatin should be discontinued until a product could be supplied that could be characterized physicochemically; with evidence of reproducibility and stability; and of higher molecular size, so that it would not be excreted at an excessive rate, as were the products then in use.

在这次会议上决定了,直到一个产品可以提供理化兼备的特点,有再现性和稳定性的特征,和较高的分子量以使它不能以过高的速率排出,直到将来这样产品被应用,明胶和氧化聚明胶的研究才能中断,在动物身上的忍受性和毒性也应该很理想。

The calculation results of some examples are given. In the unstratified case, the cake cross section at any point is circular. When the flow is stratified, buoyancy cause the wake, which initially grows at the same rate in all directions, to collapse in the vertical direction and flatten out horizontally producing a very wide and thin rectangular shape.

在稳定层化海洋中,潜艇尾流以圆锥形增长;在非层化海洋中,初期尾流也以圆锥形增长,但在浮力作用下,尾流垂向增长崩溃,然后以又薄又宽的近于矩形截面增长,最后垂向尺度趋于常值。

Results Whole course of treatment was completed in 38 PC patients. Among of them, 6 patients ocurred redness and swelling of skin on irradiated region, and curred by cold compress; pain exacerbation in 3 patients resulted from radiation, and then improved by psychotherapy and anodyne. In a follow up phase of 6 months for all 38 patients, the survival rate at half year was 63.15%(24/38), and was 15.79%(6/38)at one year.

结果 38例PC患者中28例(72.1%)完成整个疗程。6例(15.8%)治疗后治疗区皮肤红肿,予冷敷而愈。3例治疗后疼痛加剧,经心理疏导及止痛药治疗后好转。38例均获随访,半年生存率为63.15%(24/38);1年生存率为15.79%(6/38)。

Rresults from those studies can be summariazed as follow:(1) A preliminary study no correlationship between the UV-VIS reflection spectrum of tomato fruit surface and the lycopene amount of tomato fruit was undertaken. Based on observation from this study, a damage-free and in-situ detection technique of lycopene amount from tomato was developed with UV-VIS reflection spectroscopy;(2) The geometrical isomers of lycopene were separated successfully on C30-HPLC-PDA-ELSD. The absorption coefficients of Z-isomers were consequently dedermined. The geometrical isomer composition of lycopene could therefore be assessed. Those efforts formed a solid base to identify the natural product from synthetic compound of lycopene;(3) Lycopene resource from the fruit of Autumn oliver was proved to be available for industrial application. An extraction methos of lycopene from the fruit of Autumn oliver by supercritical carbon dioxide was developed at laboratory scale;(4) A method to extract lycopene by supercritical liquid with improved efficiency was developed; Data from this investigation suggested that a proper raw material pre-extraction process was important for a better extraction efficiency;(5) Variation in the geometrical isomer composition of lycopene during its metabolish in rat was assessed. A large amount of Z-isomers were observed. This variation took place in serum;(6) The absorption rate and accumulation in serum of natural lycopene in rat were assessed;(7) Ability to quench singlet oxygen by different geometrical isomers of lycopene was compared;(8) It was detected that whether natural lycopene had functions to regule blood-lipids and LDL antioxidation;(9) A C31 degradation piece of lycopene was found in the prostate gland of rat.

研究结果包括:[1]应用UV-VIS反射光谱法建立了番茄果实中番茄红素含量的无损伤、现场检测技术;[2]应用C30-HPLC-PDA-ELSD技术实现了对番茄红素几何异构体的分离,测定了不同顺式异构体的吸光系数,建立了天然番茄红素几何异构体组成的检测方法,为区分和鉴定人工合成品和天然产物奠定了基础;[3]证实了秋橄榄果实中的番茄红素资源具有工业开发价值,并建立了超临界CO_2萃取的实验室方法;[4]探索了提高番茄红素超临界流体萃取效率的方法,证明了物料前处理对提高萃取效率起了极其重要的作用;[5]观察了番茄红素在大鼠体内几何异构体组成的变化情况,发现了大量顺式异构体的存在,并证实了几何异构体组成在血清中发生了显著变化;[6]测定了天然番茄红素在大鼠体内的吸收率和在大鼠血清中的动态积累规律;[7]比较了不同番茄红素几何异构体淬灭单线态氧的能力;[8]检测了天然番茄红素是否具有调节血脂作用和抗低密度脂蛋白氧化的功能;[9]首次发现大鼠前列腺内存在番茄红素C31降解片段,并证实其仍具有淬灭单线态氧的能力。

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Cynanchum Lingtai apricot production in the average weight 65 grams, the brightly-colored fruit, juicy rich, sweet-sour taste, sweet from the nucleolus, when the late Qing Dynasty famous Shaanxi, Gansu provinces, the Qing imperial court Tongzhi tribute for years.

灵台生产的牛心杏平均单果重65克,果实色泽鲜艳,汁多味浓,甜酸适口,离核仁甜,清末时就驰名陕、甘两省,清同治年间曾为朝廷贡品。

Chenopodium album,Solanum nigrum, and Amaranthus retroflexus were very susceptible to the herbicides. Polygonum persicaria and Abutilon theophrasti were relatively less susceptible to the herbicides, and Lycopersicon esculentum was not susceptible to it. The relationship between reduction rates of weed biomass and PPM values of weed leaves 2,4, and 6 days after treatment was established.

供试的6种杂草对该混剂的敏感性存在显著差异:红心藜Chenopodium album、龙葵Solanum nigrum和反枝苋Amaranthus retroflexus对该混剂最敏感,ED90值分别为47.65、71.67和29.17g/hm2;春蓼Polygonum persicaria和苘麻Abutilon theophrasti敏感,ED90值分别为96.91、114.20g/hm2;而番茄不敏感。

However, I have an idea.

不过,我有个主意。