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The optimum reaction condition for preparation of CoPcY is as follows: a , using CoCl2 as the exchanged salt ; b , complexation temperature of 180 ; c . complexation catalyst of NH4C1 and A1C13 .2, The unsymmetrically substituted cobalt phthalocyanine complexes were synthesized by statistical condensation of phthalic anhydride and tetrabromophthalic anhydride, and further immobilized in MCM-41 molecular sieves by zeolite synthesis method, as well as characterized by XRD,FT-IR,DRS, 1HNMRetc. The catalytic property of CoPcBrx/MCM-41was tested by cyclohexane oxidation using H2O2 or t-BOOH as oxidant.

2采用本路线制备CoPcY的最佳条件为:a、采用氯化钴作为待交换的金属盐;b、络合温度以180℃为宜;c、起始反应物为苯酐、尿素、氯化铵、氯化铝、CoY时,制备出的CoPcY的催化性能最好; 2、首次采用苯酐和四溴苯酐均相浓缩统计合成法制得了不对称取代的金属钴酞菁络合物,并采用~1HNMR、FTIR、DRS等对其进行了结构表征;此外,采用沸石合成法将其固定于MCM-41中孔分子筛,并对其催化性能进行了考察。

The major content of this thesis are as follows:1 Performed FEM analysis before strengthening, and to find out the reason for the cracking and present a strengthening scheme;2 Performed nonlinear FEM analysis before and after strengthening, and to get the varying rule of the relative displacement between the on-site cast concrete side wall and that between the precast concrete arch and the floor, as well as the stress distribution of the gallery;3 Performed on-site observation experiments on the 7~th gallery, and to get the varying rule of the relative displacement between the on-site cast concrete side wall, as well as that between the precast concrete arch and the floor.4 The results of the computation were compared with those of experiments, which verified the effect of the strengthening.

本文的主要工作有: 1 对加固之前的廊道结构进行有限元计算,找出廊道底板开裂的原因,提出加固方案; 2 对加固前后廊道结构进行非线性有限元计算,得到加固前后廊道两现浇边墙相对位移、拱顶与底板相对位移随水库水位变化的规律和廊道结构的应力分布情况; 3 进行廊道加固前后现场观测试验,得到廊道两现浇边墙相对位移以及拱顶与底板相对位移随水库水位变化的规律; 4 对比分析加固前后现场观测试验与非线性有限元计算所得结果,论证加固方案的合理性,验证加固效果。

Where is a partial loss of goods, merchandise, or other moveables, the measure of indemnity, subject to any express provision in the policy, is as follows:(1)Where part of the goods, merchandise or other moveables insured by a valued policy is totally lost, the measure of indemnity is such proportion of the sum fixed by the policy as the insurable value of the part lost bears to the insurable value of the whole, ascertained as in the case of an unvalued policy:(2) Where part of the goods, merchandise, or other moveables insured by an unvalued policy is totally lost, the measure of indemnity is the insurable value of the part lost, ascertained as in case of total loss:(3) Where the whole or any part of the goods or merchandise insured has been delivered damaged at its destination, the measure of indemnity is such proportion of the sum fixed by the policy in the case of the valued policy, or of the insurable value in the case of an unvalued policy, as the difference between the gross sound and damaged values at the place of arrival bears to the gross sound value:(4)"Gross value" means the wholesale price, or, if there be no such price, the estimated value, with, in either case, freight, landing charges, and duty paid beforehand; provided that, in the case of goods or merchandise customarily sold in bond, the bonded price is deemed to be the gross value.

货物、商品或者其他动产发生部分损失的,除保险单另有明文规定外,赔偿范围如下:(1)如果定值保险单承保的货物、商品或者其他动产的一部分发生全损,赔偿范围为保险单确定的保险金额中的比例部分,该比例为灭失部分的可保价值占全部可保价值的比例部分。可保价值的确定与不定值保险相同;(3)若不定值保险单承保的货物、商品或者其他动产的一部分发生全损,赔偿范围为损失部分的可保价值,可保价值的确定与全损时相同;(4)如果被保险货物或商品的全部或者一部分以受损状态运抵目的地,赔偿范围以完好毛值与受损价值的差额占完好毛值的比例计算,在定值保险单情况下,是保险单确定的金额的该比例部分,或者,在不定值保险单情况下,是可保价值的该比例部分;(5)&毛值&是指货物的批发价格,如果没有这种价格,则是货物的估计价值,不论哪一种情况,再加上已预先付讫的运费、卸货费和关税之后的价值;但是,如果货物或商品按惯例在关仓出售,那么关仓价格就视为毛值。

This paper deals with and summarizes the research and importance of ductile shear zones and presents the future direction and aim for the research of the ductile shear zones around the world. Four aspects of studies of the ductile shear zones have been proposed in this paper as follows:(1) The stress environment including the mineral assemblages, deformation, stress-shearing parameters;(2) The major element sequence and activation under condition of stress;(3) The variations of trace elements and REE, their transportation distributions under strong natural deformation as well as variations of mineral crystal parameters, which can also control the element changes during the ductile deformation;(4) The relationship between element migrations, activation and stress, which will present the new evidences for the studies of dynamic diagenesis and mineralization as well as the studies of evolution of ductile shear zones developed in middle and low levels.(5) The analysis of elements and isotopes in mylonites on the micro-scale are crucial for the understanding of component migrations during the mylonization.

对韧性剪切带及其变形岩石的研究现状和研究意义进行系统的综述,提出了未来韧性剪切带及其糜棱岩的研究方向和目标:①系统研究糜棱岩中主要造岩矿物组合及其变形特征,计算剪切变形岩石的应力-应变参数,搞清韧性剪切带所处的应力应变环境;②系统研究韧性剪切带岩石在天然分强剪切应力作用条件下常量元素迁移机制及活化转移的应力排序问题;③系统研究剪切变形作用过程中岩石化学组成的微量和稀土元素变化,讨论强变形条件下岩石中微量元素活化和迁移规律,深入探讨微量元素迁移的动力控制,包括稀土元素配分变化的应力制约以及应变矿物晶格化学变化行为及其对其寄主的变形岩石元素在应变过程中迁移变化的制约和影响;④从理论上探讨天然强剪切应变条件下岩石中组分活化、转移与应力的因果联系,为深入探讨韧性剪切带动力成岩作用提供理论的科学依据,为探讨中、下地壳中韧性剪切带的形成和演化提供科学依据,同时为韧性剪切变形作用条件下成岩、成矿地球化学作用提供理论和实验依据;⑤现代分析技术如激光同位素原位分析以及激光ICP-MASS分析技术对研究变形域内的岩石的元素和同位素的活化迁移规律,对深刻揭示糜棱岩化过程中的元素活化迁移机制提供更高质量的地球化学证据具有重要的作用。

The translators' translation strategies and especially their thinking at various stages are the major concerns of the investigation. The findings are as follows: 1. As soon as the translator uses his visual recognition system to build a linear sentence, the sentence will move down to the translator's FLS and FSS, which functions as sifters. 2. It is important to analyze out "participants","process" and "relations among them" by semantic analyzer. 3. Pragmatic analysis is sometimes conscious and sometimes unconscious. 4. During the synthesis stage, translators tend to retain products synthesized from synthesis stage same in meaning, structure and style as the products analyzed from analyzer, which is the default way. However if he was not satisfied with the tentative products, he would send them back to syntactic analyzer or semantic analyzer to process them again. 5. Relative to synthesis, analysis is supposed to be the starting point.

主要推论如下:1、当译者用视觉辨认系统建立起线性的句子以后,句子就进入了译者的常用词汇存储和常用结构存储中,它们就像一个筛子,句子经过它们之后,在译者的短暂记忆中就剩下与它们没有重叠的生词和新句式结构了,然后这些生词和新句式结构就分别进入译者的词汇搜索机制和句法分析器中了。2、在翻译过程中进行&参与者&,&事件过程&以及&参与者与事件之间的关系&的语义分析,对于得到正确合适的翻译是非常重要的。3、语用分析有时是有意识的有时是无意识的。4、在合成阶段,译者通常都保持合成的结果和分析的结果在意义、形式、风格上一致,这是默认的途径,但是如果译者在合成阶段发现可能得到的结果不通顺或者译者不满意,他则会返回分析阶段,重新进行语用、语义或句法分析。5、分析是起点,合成是终点。

The results of base temperature for development and effective thermal summation of post-diapaused pupas and the first generation eggs are as follows:.pupas post-diapaused: Population of haw"s are 8.85℃ and 197.74℃/D,while apricot "s as 6.07 ℃ and 218.94℃/D,and apple"s as 8.76℃ and 189.48℃/DoThe first generation eggs: Population of haw"s are 8.57℃ and 86.12℃/D,yet apricot"s as 7.59℃ and 92.64℃/D and apple"s as 8.17℃ and 88.65℃/D

滞育后蛹的发育起点温度和有效积温测定结果:山楂桃蛀果蛾分别为8.85℃和197.74日度;杏桃蛀果蛾分别为6.07℃和218.94日度;苹果桃蛀果蛾分别为8.76℃和189.48日度。

The optimum condition of the ELISA are set as follows: 1ug/mL of NFLX -HSA(norfloxacin -human serum albumin) conjugation used as a coated antigen dissolved in carbonate buffer solution(CBS,pH 9.6,0.05mol/L), 0.5 % glutin in PBS(pH7.4,0.01mol/L) as a blocking agent post-coating, horse radish heroxidase-labeled sheep anti-mouse IgG(HRP-anti IgG) diluted by PBS(pH 7.4,0.1mol/L) in 1:1000 as a secondary antibody, and TMB (3,3",5,5"-tetramethyl benzidine dihydrochloride) as a sbustrate.

成功建立了检测抗诺氟沙星抗体的间接ELISA方法,其主要条件如下:pH9.6、0.005mol/L的碳酸盐缓冲溶液为包被液,1μg/mL的连接抗原NFLX-BSA(诺氟沙星-牛血清白蛋白)为包被抗原,1%明胶为封闭液,1:1000稀释的HRP酶标记的羊抗小鼠抗体作为二抗,TMB(3,3,5,5-四甲基联苯胺)作为底物。

The reclamation mode of Qidashan iron mine is combination of the forest, garden, shrub, grass and fishery, which can be concluded concisely as follows: the flat field as garden and forest, the convenient water and traffic as meadow, the sloping field as shrub and grass, the low land as fishing pool.

齐大山铁矿废弃地的复垦模式为林、园、灌、草、渔相结合,可以精炼地概括为:平为园林,水利为牧,坡为灌草,低为渔塘。

Action research is adopted as the research method. Based on the difficulty faced while teaching music, this researcher feels that students in general lack the motivation to be creative. Eurhythmics, a favorite activity of students, is thus used as the main strategy to design teaching activities, with the aim to enhance the ability of improvisation. In addition, experimental teaching is adopted and the results presented by the researcher with a behavior observation record sheet and statistics, as well as audiovisual files of improvisation and musical diaries from the students. It is a combination of qualitative and quantitative research, whose results are presented as follows: 1. Designing the principle of a eurhythmics lesson: It starts from "listening" and applies elements of eurhythmics (force→space→time→relationship→locomotor →group formations) in teaching rhythm. It not only accumulates musical ability and experience, but also becomes the source of improvisation.

研究方法采行动研究法,根据研究者在教学现场所面临的困境:学生普遍缺乏创作的动机,因此,以提升即兴创作能力为目标,运用学生最喜爱的肢体律动为教学策略,设计教学活动行动方案,并且采用实验教学,以行为观察纪录表与统计、即兴创作影音档案及音乐日记作为呈现实验结果的依据,是属於质、量并陈的研究,其研究之结果分述如下:一、律动课程之设计原则:由「聆听」开始,运用律动的元素(力量→空间→时间→关系→移动→团体组成等)於节奏教学中,不但累积了音乐能力与经验,成为即兴的创作来源。

The main research work of this dissertation is as follows: Based on the chemical reaction engineering theory and the nitrobenzene electroreduction mechanism, the plate and frame electrolyzer was designed and applied to the process of electroreduction nitrobenzene to p-aminophenol. This dissertation measured the residence time distribution data of the electrolyzer by means of the pulse response method and studied the rule of flow pattern along with the current capacity change. Under different conditions ,this dissertation studied the cyclic voltammetry properties of nitrobenzene on different electrodes by means of the dynamic cyclic voltammetry method and the electrode materials applied to the NB electroreduction have been selected primarily.Baseed on the results of cyclic voltammetry tests, this dissertation used p-electrode systems to measure the steady-state- polarization curves of nitrobenzene on different electrodes in H-type diaphragm cell, and obtained each primary factor s influence rule and the exchange current density value of each electrode.And then on the basis of the conclusions of fundamental researchs upword, the effects of influence factors on the the yield of p-aminophenol and the current efficiency,such as electrode material, current density, quantity of electricity circulated, nitrobenzene concentration . sulpuric acid concentration and so on, have been studied in detail in the systems of hign temperature , strong acidity and oxygen-poorthrough a series of electrolysis experiments in this paper.After all using Pb as anode Monel metal as cathode Dupont Nafion 417 cation-exchange membrane as membrane, this dissertation obtained the optimum technological condition: reaction temperature about 85C, current density 500A m-2, sulphuric acid concentration 20%wt.

论文的主要研究工作为:运用化学反应工程理论,结合硝基苯的电还原机理,设计出用于硝基苯直接电还原合成对氨基苯酚实验的板框式电解槽,并利用脉冲响应法测定了该板框式电解槽的停留时间分布数据,研究了流型随流量变化的规律;通过动态循环伏安法研究了硝基苯在不同电极上、不同条件下的循环伏安特性,初步评选出了用于硝基苯电还原的电极材料;结合循环伏安的测定结果,在H型隔膜电解槽中采用三电极体系测定了硝基苯在不同电极上、不同条件下的稳态极化曲线,得到了各主要因素的影响规律及硝基苯在各个电极上电还原的交换电流密度数值;在基础研究结论指导下,采用板框式电解槽,在高温、强酸、贫氧系统中,进行了一系列的电解实验,分别考察了电极材料、电流密度、通电量、硝基苯浓度、硫酸浓度等因素对收率及电流效率的影响,最终选择以蒙乃尔合金电极作为阴极、铅合金为阳极、Dupont Nofion 417阳离子交换膜为隔膜,得到由硝基苯直接电还原制对氨基苯酚的最佳电解工艺条件:反应温度85℃,电流密度500A·m~(-2),硫酸浓度20%wt。

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Methods: Five patients with parkinsonism or dystonia were assigned to general anesthesia using an modified endotracheal tube.

本实验依照人体实验之相关规定进行,五位患有帕金森氏症或肌张力异常的病人接受神经立体定位手术。

If you can benefit from this book, it is our honour.

如果您能从本书获益,这将是我们的荣幸。

The report also shows that the proportion of unmarried men and women living together has doubled between 1986 and 2006, with 13 per cent of those aged 16 to 59 now cohabiting.

报告还指出,从1986年至2006年,英国未婚男女同居的比例增长了一倍,在16岁至59岁的人群中,有13%的人同居。