查询词典 ammine complex

In this thesis, a series of complexes based on aromatic multicarboxylic acids have been successfully synthesized in solutions or under hydrothermal conditions. Their structure and properties are investigated.(1) Eight complex compounds have been synthesized and characterized by X-ray single crystal diffractive technology: The eight complexes are listed as following: [Cu242] complex 1 [Cd22(H2O)4]·4H2O complex 2 [Co(H2btc)(H2O)3] complex 3 [Co2(H2O)2]·H2O complex 4 [Ni22(H2O)4] complex 5 [Cu22(H2O)4] complex 6 [Co(H2biim)2(H2O)2](H2btc) complex 7 [Zn(H2biim)2(H2O)2](H2btc) complex 8 The structure of complex 1 is dinuclear complex resulted from weak interactions（0-D chain）; complex 2 is 1-D chain stucture result from interactions of water molecules; complex 3、4、5、6 are coordination polymers using hydrothermal synthses, where the first kind ligand is H4btc, the second kind ligand is phen and Co2+、Ni2+、Cu2+ as center ions, respectively. While the coordination enviroment of Co2+ is the same in complex 3, the coordination geometries around the Co atoms in complex 4 are obviously different because of the different reaction conditions. In complex 4, the 1-D chains are connected into 2-D layer through carboxy groups of ligand H4btc. The structures of complex 5、6 are 1-D chain stucture result from interactions of carboxy groups in ligand H4btc. Complex 7、8 are homeomorphy compounds. Either of them are linked to the 3-D chains through intermolecular hydrogen bonds. Each H4btc lose two protons and H2btc2- acts as negative electron balance.

合成了8个结构新颖的配合物，并用X-射线单晶结构分析方法确定了晶体结构，分别为： [Cu242] 配合物1 [Cd22(H2O)4]·4H2O 配合物2 [Co(H2btc)(H2O)3] 配合物3 [Co2(H2O)2]·H2O 配合物4 [Ni22(H2O)4] 配合物5 [Cu22(H2O)4] 配合物6 [Co(H2biim)2(H2O)2](H2btc)配合物7 [Zn(H2biim)2(H2O)2](H2btc)配合物8 配合物1是一个依靠弱作用连接的双核铜结构；配合物2借助水分子形成一维链状结构；配合物3、4、5、6是以H4btc为第一配体、phen为第二配体，通过水热法合成的配合物，其中，Co2+、Ni2+、Cu2+为中心离子；配合物3中的二价钴离子具有相同的配位环境，不同反应条件下得到的配合物4中的二价钴离子存在不同的配位环境，在配合物4中，一维链通过H4btc上的羧基形成一个二维层结构；配合物5、6是借助H4btc上的羧基形成的一维链状结构；配合物7、8属于异质同晶结构，它们的分子通过分子间氢键形成三维网状结构，H4btc上的羧基失去2个质子，作为一个二价负离子起到电荷平衡作用。

The atomic resolved density of state shows that there is density of Ru on the HOMOs. All the density is localized on the ammine, which reveals that the excited electrons in the Ru complex are delocalized over the ammine ligand.

首先原子分辨的态密度显示HOMO上的密度主要在Ru上，LUMO 上的态密度在ammine上，这说明Ru上激发的电子会转移到ammine配体上。

The first stage was actually the primary purification process, in which most of inorganic ammonium and some total ammine can be removed along with the primary purification process, the second stage was liquid phase oxidation method by sodium hypochlorite, in which inorganic ammonium and total ammine can be further removed.

一段除铵为原有的尾盐一次精制工艺。研究发现，在一次精制的同时，可以除去尾盐中的大部分无机铵及部分总胺，二段除铵采用次氯酸钠液相氧化法，以进一步除去尾盐中无机铵及总胺。

In this paper,fuzzy complex numbers,limits of the sequence of fuzzy complex numbers,the metrical convergence and levelwise convergence,the continuity offuzzy complex functions,the calculus of fuzzy complex functions,theseries whose terms are fuzzy complex numbers,the series whose terms arefuzzy complex functions,the fuzzy complex measure and fuzzy differentialequation are investigated in details.All this may be a foundation forfurther researching fuzzy complex analysis.

本文对模糊复数、模糊复数列的极限、度量收敛与水平收敛、模糊复函数的连续性、模糊复函数的微积分、模糊复数项级数、模糊复函数项级数、模糊复测度及模糊微分方程理论进行了详细的研究，为模糊复分析的进一步研究打下一定基础。

On the basis of Ritter real morphological associative memory, complex lattices and complex rings are defined respectively through introducing two ordinal relationships between complex numbers, consequently the same recall rules are obtained as RMAM in complex domain and construct a class of complex MAM, called extended RMAM. The CMAM can directly process complex signals such as FFT-ed complex data.

在Ritter的实域形态联想记忆(real morphological associative memory，简称RMAM)模型的基础上，通过在复数域中序关系的引入构成复数格和环，导出了在复数域上与RMAM相一致的联想规则，构建了一类复域MAM(complex MAM，简称CMAM)，从而将RMAM从实域推广至复域，使其可直接处理复信号如经FFT(fast Fourier Transformation变换所得数据。

The method for determining a phase-noise spectrum comprises generating real complex samples, by digitally sampling a phase component and phase quadrature component of the input signal in baseband, determining ideal complex samples from generated real samples, establishing complex quotients from the real and ideal complex samples, generating modified complex quotients by assigning the value 1 to the complex quotients, and subjecting the modified complex quotients to a Fourier transform.

所述方法包括以下步骤：通过对基带中的所述输入信号的相位分量和相位正交分量进行数字采样，产生实际复数采样Areal(n(S100)；根据产生的实际采样Areal(n确定理想复数采样Aideal(n(S101)；根据实际复数采样Areal(n和理想复数采样Aideal(n形成复数商ΔA1(n＝Areal/Aideal；通过对所述复数商指定值1，产生经修正复数商B(n(S106)；以及对经修正复数商B(n进行傅立叶变换(S107)。

Catalysts are made by impregnating a porous transition alumina support with an aqueous solution of a copper ammine carbonate complex, draining off any excess of the impregnating solution, and then heating the impregnated support to a temperature above 80 DEG C to decompose the complex thereby depositing a basic copper carbonate compound on the surfaces of the pores of the transition alumina support.

用作例如催化剂的铜／氧化铝组合物，通过用碳酸铜氨配合物的水溶液浸渍一种多孔氧化铝载体，排出任何多余的浸渍液，然后加热所浸渍的载体到80℃以上的温度来分解所述配合物，从而在所述过渡型氧化铝载体的气孔表面沉积一种碱式碳酸铜来制备。

A simple estimation method for molar Gibbs free energy and enthalpy of formation for complex oxysalt minerals is proposed. Complex oxysalt minerals are divided into complex oxysalt minerals with water and complex oxysalt minerals without water. Complex oxysalt minerals without water can be considered as the composite of acidic oxides and alkaline oxides, so their molar Gibbs free energy or molar enthalpy of formation can be calculated by the summation of molar Gibbs free energy or molar enthalpy of formation of the acidic oxides and alkaline oxides which are combined into the complex compounds.

提出了一种复杂含氧盐矿物的摩尔生成Gibbs自由能和摩尔生成焓的简单估算方法，并把复杂含氧盐矿物分为不含水复杂含氧盐矿物和含水复杂含氧盐矿物，不含水复杂含氧盐矿物可以看作是酸性氧化物和碱性氧化物组成的物质，其摩尔生成Gibbs自由能或摩尔生成焓都可以看作是酸性氧化物和碱性氧化物复合成的化合物摩尔生成Gibbs自由能或摩尔生成焓之和。

Three methods including the atomic resolved density of state, charge difference density, and the transition density matrix are used to visualize metal to ligand charge transfer in ruthenium ammine complex.

利用三种方法可视化化了Ru ammine的金属到配体的电荷转移。

It is first reported and studied systematically about the changes occured during calcination, reduction and re-oxidation treatments of Pt ammine complex supported on β zeolite.

一。首次系统地研究了β沸石上Pt胺化合物经分解、还原及再氧化等处理过程中发生的变化，并提出关于Pt粒子大小及其状态变化的模型。

Bob Eckert has been chairman and chief executive of Mattel for eight years.

美泰董事长兼首席执行官鲍勃·埃克尔特在任已8年。

The outlook for honors and disgraces carries on and surpasses the traditional outlook for honors and disgraces theoretically, and carries on and develops the theory of construction of socialist mora...

社会主义荣辱观的提出在理论上是对传统荣辱观的一次继承和超越，是对社会主义道德建设理论的继承和发展，在实践上有利于形成良好的社会风尚。