查询词典 X-ray diffraction

This could be a fascinating method for the practical syntheses of chiral synthons as valuable building blocks and important medicinal intermediates.3.Series of novel optical pureγ-aryl-1H-1,2,4-triazole derivatives were designed and synthesized by using the chiral auxiliary(Oppolzer\'s sultam),and all these target compounds were structurally characterized by ~1H NMR,~(13)C NMR,MS and elemental analysis,at the same time,some representative compounds have been elucidated by X-ray diffraction analysis.

应用手性辅剂樟脑磺内酰胺的手性诱导作用，设计合成了一系列光学纯的γ-芳基-1H-1，2，4-三唑类衍生物，所有目标化合物都采用了~1H NMR、~(13)C NMR、MS和元素分析进行了结构表征，同时也获得了部分代表性化合物的晶体结构，进一步确证了化合物的结构。

X-ray single crystal diffraction study reveals that the Zn atom is five-coordinated, Furthermore, a 2D superamolecular network is constructed via the tetracarboxylate bridged binuclear of Zinc SBU ,and the amino substituent results in the formation of hydrophilic 2D structure of the title complex.

该配合物中，锌离子为5配位，2个Zn原子和4个羧基形成的双核锌结构单元，进而形成二维方格式平面结构，氨基取代基导致配合物具有亲水性。

Two organosulfonate complexes, [M22]·H2O (M=Cd 1, M=Pb 2), were obtained from the reaction of 1,10-phenanthroline, sodium 4-aminonaphthalene-1-sulfonate tetrahydrate and Cd2·2H2O or Pb (NO3)2 in a mixed solvent of water and methanol at 25 ℃. The compounds were characterized by elemental analysis, IR, and X-ray diffraction single crystal structure analyses.

合成了2个新型有机磺酸配合物，[Cd22]·H2O(1)和[Pb22]·H2O(2)(phen=1，10-邻菲咯啉，ans=4-氨基-1-萘磺酸根)，通过元素分析、红外光谱等对配合物进了表征，用X-射线单晶衍射方法测定了配合物的单晶结构。

1H-imidazolyl)-1H-imidazolium chloride-4-aminobenzoic acid, 2,2-bi-1H-imidazolium bis(3,4,5-trihydroxy benzoate) tetrahydrate and bis2-(2-1H-imidazolyl-1H-imidazolium 3-carboxy-4-hydroxybenzene-sulfonate monohydrate have been synthesized and characterized by X-ray diffraction methods.

在化合物中，晶体结构中的基本单元是一个通过氢键模式R_2~2(9)和R_2~1(7)构成的氢键三聚体PABA…H_3biim~+…Cl~-，这个三聚体基本单元又通过N-H…Cl氢键相互作用形成了一维带状结构。

These complexes are structurally identified by single-crystal X-ray diffraction to show a variety of metal nuclearity from mononuclear to tetranuclear and dimensionality from 1-D to 3-D.

单晶结构分析表明这些化合物具有多种金属核数（从1到4）以及多种结构维数。

All the ligands and complexes have been characterized with ~1H-NMR, MS and EA.X-Ray single crystal diffraction reveals that zirconium complex containing the tert-butyl substituted N_2O_2 ligand is an oxo- and hydroxyl-bridged dinuclear structure, which is possibly formed by partial hydrolysis of chlorides at one of the zirconium centers. A tetranuclear zirconium complex has been obtained and chacaterized, which is formed by complete hydrolysis of the chlorides at the zirconium centers.

通过研究配合物的单晶结构，我们发现叔丁基取代的不对称N_2O_2配体与ZrCl_4反应生成的锆配合物为氧桥和羟基桥连接的双核锆配合物，中间过程涉及单核锆配合物中氯原子部分水解，并得到氯原子部分水解的双核锆配合物和全部水(来源：8e6eAB67C论文网www.abclunwen.com)解的四核锆配合物的晶体结构，在晶体培养过程中发现双核锆配合物能够以手性自发拆分结晶析出。

The tetravalence vanadium was found in V2O5 gel thin films by measuring the electrical resistance change of V2O5 gel thin films with temperature, ESCA and X-ray diffraction analysis. in this paper, from miniamount redox in melting V2O5 and crystal structure, the influencing mechanism of miniamount redox on changing valence of vanadium was analyzed and discussed in detail.

通过对V2O5凝胶薄膜试样的电阻随温度的变化测试和电子能谱和X射线衍射分析发现V2O5凝胶薄膜中有四价钒的存在，本文从V2O5熔体的微量氧化还原和晶体结构的角度分析讨论了微量氧化还原影响钒离子价态变化的机理。

Effects of temperatures on thaumasite formation were investigated.X-ray diffraction,scanning electron microscope,energy dispersive spectrum and laser Raman spectrum analysis were used to identify thaumasite in paste sample stored in 10% of MgSO 4 solution at different temperatures.

研究了环境温度对碳硫硅钙石形成的影响。降浸泡于不同温度的质量分数为10%的MgSO 4 溶液中的含石灰石粉水泥石试样进行X射线衍射分析、扫描电子显微分析、能谱分析和激光Raman光谱分析。

X-ray diffraction, scanning electron microscope, energy dispersive spectrum and laser Raman spectrum analysis were used to identify thaumasite in paste sample stored in 10% of MgSO_(4) solution at different temperatures .

钙矾石型和石膏型等硫酸盐侵蚀破坏机理已得到广泛研究与认同，然而另一种硫酸盐破坏类型———碳硫硅钙石型却没有受到应有重视。

Provided are carbide derived carbon materials prepared by thermochemically reacting carbide compounds and a halogen containing gas and extracting all atoms of the carbide compounds except carbon atoms, wherein the intensity ratios of the graphite G band at 1590 cm -1 to the disordered-induced D band at 1350 cm-1 are in the range of 0.3 through 5 when the carbide derived carbon is analyzed using Raman peak analysis, wherein the BET surface area of the carbide derived carbon is 1000 m 2 /g or more, wherein a weak peak or wide single peak of the graphite (002) surface is seen at 2 = 25 DEG when the carbide derived carbon is analyzed using X-ray diffractometry, and wherein the electron diffraction pattern of the carbide derived carbon is the halo pattern typical of amorphous carbon when the carbide derived carbon is analyzed using electron microscopy.

提供了得自碳化物的碳，其通过热化学反应碳化物化合物和含卤族元素的气体并提取除了碳原子之外的碳化物化合物的全部原子制备，其中当使用拉曼峰分析法分析该得自碳化物的碳时，在1590cm -1 的石墨G波段与在1350cm -1 的无序引发的D波段的强度比为0.3至5，其中该得自碳化物的碳的BET表面积是1000m 2 /g或更大，其中当使用X射线衍射法分析该得自碳化物的碳时，在2θ＝25°观察到石墨(002)面的弱峰或宽单峰，以及其中当使用电子显微法分析该得自碳化物的碳时，得自碳化物的碳的电子衍射图是代表无定形碳的晕图案。该发射体具有良好的均匀性和长寿命。可以使用比用于生产常规碳纳米管的方法更廉价的方法制备发射体。

What was it that made you want to change sider ?

是什么使你临阵倒戈？

I don't know what he wants, but let's play along with him.

我不知道他要干什么，可我