英语人>词典>汉英 : 钌酸盐 的英文翻译,例句
钌酸盐 的英文翻译、例句

钌酸盐

基本解释 (translations)
ruthenate

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New ruthenium benzylidene complexes benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] [k~2-diphenylphosphinoacetato] monochlororuthenium (46), benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene][k~2-3-propionato]monochlororuthenium (47), benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] [k~2-2-benzonato]monochlororuthenium (48) featured five-membered, flexible six-membered and rigidsix-membered chelating rings respectively are prepared by reactions of complex 41 withcorresponding sodium phosphino-carboxylates. It is confirmed by X-ray crystallographicanalysis that the coordination geometries of complexes 46 and 47 are distorted squarepyramids with phosphino-carboxylate ligands chelating to ruthenium, and the coordinationbetween ruthenium and benzylidene ligands are strengthened.

用二苯基瞵乙酸盐、二苯基膦丙酸盐、二苯基膦苯甲酸盐与钌卡宾配合物41反应合成了三个新的钌卡宾配合物:含五元膦-氧螯合环的1,3-二-(2,6-二甲苯基)-4,5-二氢咪唑基1-苯亚甲基--一氯合钌(46)、含六元柔性膦-氧螯合环的[1,3-二-(2,6-二甲苯基)-4,5-二氢咪唑基1-苯亚甲基--一氯合钌(47)及含六元刚性膦-氧螯合环的[1,3-二-(2,6-二甲苯基)-4,5-二氢咪唑基]-苯亚甲基--一氯合钌(48)。X射线单晶衍射分析证明,配合物46、47都为变形的四方锥构型,膦-氧与钌形成螯合配位,其中苯亚甲基与钌的配位得以加强。

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persalt:过酸盐

perruthenate 过钌酸盐 | persalt 过酸盐 | persian red 铬红

perruthenate:过钌酸盐

perrhenic acid 高铼酸 | perruthenate 过钌酸盐 | persalt 过酸盐