异分子聚合

基本解释 (translations)

copolymerize  ·  copolymerized  ·  copolymerizes  ·  copolymerizing  ·  coyolymerization

与异分子聚合相关的网络例句 [注：此内容来源于网络，仅供参考]

By combining the intermediate isomerization products with other polymerizable molecules, new copolymers are also obtained.

相结合的中间异构化的产品与其他聚合分子，新的共聚物，也得到了。

The results showed that the thermo-sensitivity of hairy PNIPA changed obviously in the presence of hairy PAA as polyelectrolyte.4-cyanopentanoic acid dithiobenzoate as soluble reversible addition-fragmentation chain transfer agent was directly added into the above PS particles with photo-initiator on the surface and NVP or NIPA as monomer.

其次，将水溶性RAFT试剂直接引入上述光引发聚合体系，探讨连续相中RAFT试剂的存在对微球表面N-乙烯基吡咯烷酮或N-异丙基丙烯酰胺聚合的影响，考察了RAFT试剂对聚合过程中微球壳层高分子毛发厚度和单体转化率变化趋势。

The conclusions were as follows: theνO-H andνC=O IR absorption maxima shifted towards higher wave numbers after imprinting 17β-estradiol on TFMAA-co-TRIM copolymer with the red shift of theνO-H groups being apparent after precipitation polymerization for 16h while that forνC=O groups being observed after polymerization for 24h. A strong interaction between TFMAA and 17β-estradiol was confirmed by the high selectivity for 17β-estradiol, as indicted by the values of the separation factor of isomers of 17β-estradiol/17α-estradiol (2.28) and the imprinted factor (3.01). Particle diameter of TFMAA-co-TRIM polymer was between 300 nm and 1.5μm, which suited well for solid phase sorbent throughout at low column pressure. The recognition of imprinting TFMAA-co-TRIM polymer for sterol molecules was driven by enthalpy eluted with acetronitile, and low temperature was in favor of the separation of sterol structure analogues on imprinting column. TFMAA-co-TRIM polymer possessed of determinate anti-heat stability, with melting point beginning at 255.84℃, Tp=257.40℃, control TFMAA-co-TRIM polymer and imprinting TFMAA-co-TRIM polymer were respectively decompounded at 267.79℃and 343.11℃, and solid micro-extraction noddle prepared by the special polymerization also showed definite recognition for 17β-estradiol by GC/MS detecting at 270℃. By selection of various washing and elution solvents, elution reagents of close polymerization system were of more advantage in template molecules retention and recognition on molecularly imprinted solid phase extraction column. At a certain extent, progesterone, 17α-estradiol, 17β-estradiol and 4-androstene-3, 17-dione could be intercepted on the MISPE column. Especially, MISPE had high selectivity for progesterone, and imprinting TFMAA-co-TRIM polymer could achieve adsorption balance within 50 min by absorption kinetics test for 17β-estradiol. However, MISPE column showed better selectivity and enrichment property for 17β-estradiol than C18 and CSPE columns according to the data from HPLC and GC/MS analyses. Recovery of 17β-estradiol on MISPE column was up to 85.5% while when prime extracting solution of milk powder was sampled, the recovery of CSPE and C18 columns were 43.7% and 30.7%, respectively.

通过研究阐明：紫外聚合产物TFMAA-co-TRIM中的νO-H振动吸收峰在聚合16h后红移，νC=O振动吸收峰在聚合24h后红移；TFMAA-co-TRIM对雌二醇异构体的印迹因子达到了3.01，α为2.28，优于其它功能单体参与得到的聚合物识别特性；TFMAA-co-TRIM聚合物粒径介于300 nm至1.5μm之间，作为色谱固定相具有良好的通量和低的柱压；在乙腈流动相中，TFMAA-co-TRIM分子印迹固定相的分离过程主要被焓驱动，低温有利于分子印迹固定相分离甾醇结构类似物；TFMAA-co-TRIM分子印迹聚合物在255.84℃时开始熔融，Tp=257.40℃，聚合物CP的降解温度在267.79℃，MIP降解温度在343.11℃，制备的固相微萃取头初步经GC/MS 270℃的耐热性测定；不同的洗提溶剂筛选证明了选择接近聚合溶剂的洗脱体系更有利于MISPE发挥识别效应；分子印迹固相萃取柱对孕酮、17α-雌二醇、17β-雌二醇和雄烯二酮都具有不同程度的保留特性，可作为此类化合物的吸附材料，特别对孕酮强保留的富集特性，可作为孕酮的选择性识别吸附剂，其分子印迹聚合物对17β-雌二醇的吸附动力学测定显示在50 min内基本达到吸附平衡，具有作为传感器核心敏感材料的潜力；对比萃取奶粉中17β-雌二醇性能，MISPE柱比非分子印迹固相萃取柱和C18柱具有更高的保留，回收率依次为85.5%，43.7%和30.7%。

It was applied to analyze the structures of ashless dispersants and their derivatives. The results were obtained and correlated. The molecular weight distribution and dipersity of ashless dispersant, number of polyisobutene R and polymeric degree of R polymerism in addition agent were obtained.

以Ultrastyragel为固定相，四氢呋喃作流动相，用普适标准校正曲线及凝胶渗透色谱法对无灰分散剂及其对应衍生物的结构进行了分析测定，并将测定结果相关联，计算出了无灰分散剂的相对分子质量分布、分散度及添加剂所含聚异丁烯R基的个数及R基聚合度。

The experimental results show that using the feed technique of "starved state" can raise the conversion ratio of monomers, shorten the reactive time and get polymers with much more even distribution of molecular weight; the technique of adding azobisisobutyronitrile as an initiator first and then benzoperoxide as another initiator at later Stage of experiment can get higher initiating efficiency than using one initiator only.

结果表明：采用&饥饿态&聚合工艺可提高单体转化率，缩短反应时间，且所得到聚合物相对分子质量分布均匀；选用偶氮二异丁腈和过氧化笨甲酰两种引发剂进行复配，比选用单一引发剂的引发效果好；选用酯酸丁酯、正丁醇和丙二醇甲醚丙酸酯作混合溶剂，当配比为2：1：1时聚合体系稳定，聚合物的固体质量分数可达70%，且粘度适中。

The nitrophenol and hydroxybenzoic acid isomers imprinted monolithic columns were prepared by in-situ polymerization.

采用原位聚合法制备了硝基苯酚和羟基苯甲酸位置异构体的分子印迹整体柱。

The nitrophenol and hydroxybenzoic acid isomers imprinted monolithic columns were prepared by in-sim polymerization.

采用原位聚合法制备了硝基苯酚和羟基苯甲酸位置异构体的分子印迹整体柱。

Acrylamio-2-methyl propane sulfonic acid is applied in the production of water-based latex,which copolymerizes with acrylic acid,styrene or vinyl acetate to turn out latex resin.

2-丙烯酰胺基-2-甲基丙磺酸应用于水基性胶乳的生产过程中，与丙烯酸、苯乙烯或醋酸乙烯发生异分子聚合而生成胶乳树脂。

objective: to prepare the molecularly imprinted composite membranes with propofol as template.methods: with the ultraviolet light and initiator, template molecular propofol, functional monomer methacrylate and crosslinking agent ethylenegly-coldimethacrylate formed molecularly imprinted composite membrane through polymerization on the surface of polyvinyli-dene fluoride microporous membrane.inspection of the combination of template molecule and functional monomer, characterization of the membrane surface morphology with scanning electron microscopy.results: the morphology of composite membranes was well.propofol bonded to methylacrylic acid with hydrogen bond.conclusion: the method of ultraviolet light-struck is feasible for preparation of molecularly imprinted composite membranes with propofol as template.

目的：制备异丙酚分子印迹复合膜。方法：在紫外光照和引发剂的作用下，模板分子异丙酚、功能单体甲基丙烯酸和交联剂乙二醇二甲基丙烯酸酯在聚偏氟乙烯微孔滤膜表面聚合形成分子印迹复合膜，考察模板分子和功能单体的结合特性，用扫描电镜表征膜的表面形态。结果：复合膜形态良好，异丙酚和甲基丙烯酸以氢键的方式缔合。结论：用紫外光照射法可以制得异丙酚分子印迹复合膜。

The copolymers were systematically characterized by elementary analysis, FT-IR, UV-visible spectroscopy, solution high-resolution 〓H-NMR and solid-state high-resolution 〓C-NMR spectroscopes, solubility examination; circular dichroism technique was firstly used to characterize chain structure of the copolymers.

本文通过在刚性的PD聚合物分子链中引入邻乙氧基苯胺链节，使用化学氧化聚合和电化学氧化聚合两类新型聚合方法，合成了三种PD异构体与PHT的共聚物，并进行了聚合反应、结构和性能表征的系统研究，并且比较了氨基的相对取代位置对聚合活性的影响。

与异分子聚合相关的网络解释 [注：此内容来源于网络，仅供参考]

enolate：烯醇盐

很早以前化学家就知道,异氰酸酯化合物(isocyanates),在碱性磷化物之催化下会进行聚合反应,生成双分子(dimer)或三分子(trimer)化合物(注六),强碱钠胺促使反应物生成烯醇盐(enolate),而后得到重排(rearranged)产物;