亚钯的

基本解释 (translations)

palladious  ·  palladous

与亚钯的相关的网络例句 [注：此内容来源于网络，仅供参考]

Methodological furan and reaction of Diels-Alder of course of Ma Lai anhydride are generated go armour goes element of hydrogenous Chinese blister beetle, reductive below palladium charcoal catalysis into go element of armour Chinese blister beetle, with replace aniline condensation to become nitrogen - phenyl goes acyl of armour Chinese blister beetle inferior the ramification of amine.

方法呋喃和马来酐经过Diels-Alder反应生成去甲去氢斑蝥素，在钯炭催化下还原成去甲斑蝥素，和取代苯胺缩合成氮-苯基去甲斑蝥酰亚胺的衍生物。

It was discovered that when ethyl nitrite was introduced to the surface of catalyst, Pd ethoxyl compound was formed and simultaneously the active site Pd was transferred to the surface of catalysts with the change from Pd〓 to Pd〓. Then lined-adsorbed CO inserted into Pd alkoxyl compound to form the carboethoxypalladium complex.

研究结果表明，在CO偶联反应过程中，亚硝酸乙酯在催化剂上吸附，生成钯乙氧基络合物，同时将催化剂表面上的活性中心氧化，由Pd〓→Pd〓，并向催化剂表面上迁移。

In this paper,the mechanism,property and theoretically study of the solvent extraction of Pd and Pt with sulfoxide were introduced,and the research with the emphasis on the structure-extraction property relationship was reviewed.

本文回顾了国内外有关亚砜萃取钯和铂的3个主要研究领域：萃取性能与亚砜结构的关系、萃取机理及萃合物结构和亚砜萃取钯铂的理论研究。

Copolymers with the naphthoyimine chromophores were firstly obtained through Pd-catalyzed Heck reaction. The copolymers had good solubility in common solvents due to the presence of alkoxyl substituents in the molecular chains.

在钯催化下利用Heck耦合反应制备了以萘酰亚胺为发色团的共聚物，通过侧链上引入丁氧基醚链，使得聚合物具有很好的溶解度，能溶解在常用有机溶剂中。

Bis-(4-bromobenzoyl) benzene as the monomer of poly was synthesized by Friedel-Crafts benzoylation reaction. Poly-Ⅱ synthesized via palladium-catalyzed aryl amination reaction using 1, 4-bis-(4-bromo-benzoyl) benzene and 4, 4'-diaminodiphenyl ether as monomers.

通过傅－克酰基化反应合成了1，4-双－（4'-溴苯酰基）苯，以1，4-双－（4'-溴苯酰基）苯和4'4-二氨基二苯醚为单体，通过钯催化的胺基化缩聚反应合成了高性能聚合物－聚亚胺酮－Ⅱ。

A2D iim ine nickel, palladium complexes and pyridine bisimine iron, cobalt complexes are discovered in recent years to be new generation late transition metal catalysts for olefin homogeneous poly merization and oligomerization.

A2二亚胺镍、钯络合物和吡啶二亚胺铁、钴络合物是近几年来发现的新一代烯烃均相聚合后过渡金属催化剂。

This dissertation is mainly focused on the reactivity of methylenecyclopropanes and comprises six parts. 1 The reactions of methylenecyclopropanes with phenylsulfenyl chloride, phenylselenyl chloride and diphenyl diselenide; 2 The coupling reactions of the ring-opening products derivated from methylenecyclopropanes; 3 The palladium-catalyzed ring-enlargement of mono-aryl group substituted methylenecyclopropanes to cyclobutenes. 4 The gold-catalyzed domino ring-opening and ring-closing hydroamination of methylenecyclopropanes with sulfonamides; 5 The Lewis acid-catalyzed reactions of mono-aryl group substituted methylenecyclopropanes with diethyl ketomalonate in the presence of water; 6 The iodobenzene diacetate mediated novel 1,3-dipolar cycloaddition of methylenecyclopropanes, vinylidenecyclopropanes, and methylenecyclobutane with phthalhydrazine.

本论文主要研究了亚甲基环丙烷类化合物的一些化学反应性能，共由以下六部分组成：1、亚甲基环丙烷类化合物与苯硫氯、苯硒氯及二苯基二硒的反应；2、亚甲基环丙烷类化合物开环产物的偶联反应；3、单芳基取代的亚甲基环丙烷类化合物在钯催化剂作用下的扩环反应；4、金化合物催化磺酰胺对亚甲基环丙烷类化合物的串联开环关环氨氢化反应；5、路易斯酸催化亚甲基环丙烷类化合物与丙酮二羧酸二乙酯在有水存在下的反应；6、醋酸碘苯促进的亚甲基环丙烷类化合物、亚乙烯基环丙烷类化合物及亚甲基环丁烷类化合物与邻苯二甲酰肼的新型1，3-偶极环加成反应。

A series of light-weighted metal coated functional composites have been fabricated by electroless metal plating on activated ultrafine particles, with nickel or copper as the shell, ultrafine particles as the core templates, such as alumina, titania, ferriferous oxide, natural pollen, hollow microspheres.

结合分子自组装技术在硅片表面制备了密堆积的胶体钯纳米薄膜，并首次提出了一种无需氯化亚锡敏化、基于分子自组装膜化学吸附胶体钯纳米微粒的活化方法，成功地引发了金属铜或镍在金属与非金属表面的无电子沉积，制备了一系列金属包覆非金属粉末的轻质超细核壳结构功能材料。

This Palladacycle catalyzed Heck reaction was characterized by a wide variety of substrates, mildness of reaction conditions, freedom from protection of inert gases and high catalytic activity retainable after repeated uses.

二茂铁亚胺环钯化合物催化的Heck反应具有底物范围较广，反应条件温和，不需要惰性气体保护，催化活性高且催化剂可重复使用仍能保持活性的优点。

The coupling reaction of aryl iodides, bromides and chlorides with differentolefins catalyzed by catalyst 2 and 4 was studied. It was found that compounds 2 and 4 anchored on active carbon are efficient catalyst for the Heck reaction in the case of aryl bromides and aryl chlorides as substrates (Scheme 3). It is notable that catalyst 4 has higher efficiency for aryl chlorides.___^H Cat.2 or 4, Base HXSolution, 100C or 140

以化合物2和4为代表，重点研究了活性炭负载的二茂铁亚胺环钯化合物催化碘代苯、溴代苯和氯代苯与活泼烯烃之间的偶联反应(Scheme 3)，发现活性炭负载的二茂铁亚胺环钯化合物2和4均可用于催化多种溴代和氯