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饱和化合物

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Since the atomic radius of cerium or yttrium is at the border between the Th〓Ni〓-type and the rhombohedral Th〓Zn〓type structure, the influence of different annealing temperatures on the crystal structure of Ce〓Co〓 and Y〓Co〓 compound was clarified.

测量并获得了这些化合物的晶体结构类型、点阵常数、晶胞体积、居里温度、在5K和300K时化合物的饱和磁化强度和每个Co原子的平均磁矩、各向异性场、各向异性常数、自旋重取向温度以及补偿温度等,并获得了相应化合物的磁相图。

By the comparison of electronic spectrum and Z-scan of different substituted MPc and MNc, the peripheral substituted MNc had better nonlinear optical properties. It provided a new method to the improvement of the performance of reverse saturable absorption of the laser protective materials.

对不同金属轴向取代的萘酞菁化合物的电子光谱和Z-扫描进行了横向比较,并对相同取代基、金属轴向取代的酞菁化合物和萘酞菁化合物进行了纵向比较,发现周围取代的金属萘酞菁化合物具有较好的非线性光学性能,为提高材料的反饱和吸收性能提供了一种新的途径。

The results show that there are mainly lead、zinc、 CuZn〓、FeZn〓 and four phases in hard—zinc: zinc—lead solid salution of saturation lead、lead—zinc solid solution of saturation zinc、high iron multicomponent solid solution and high arsenic multicomponent solid solution.

且硬锌中有四相存在:饱和铅的锌铅固溶体、饱和锌的铅锌固溶体、高砷多元固溶体和高铁多元固溶体,其中铁锌固溶体为白色板条状结晶,砷化合物为灰微带棕色粒状物。

Furthermore, a biogenesis-based synthesis of CET was developed, which realized the plausible biogenetic transformation by a transannular reductive skeletal rearrangement of cyclic amino enone 45 to key ring skeleton of CET under mild condition directly.

化合物17经Wacker氧化、环化得到重排前体不饱和酮45,45在温和的还原条件下重排得到三尖杉碱五环骨架化合物34,从而实现了三尖杉碱的全合成。第二条路线较前一条步骤更短,合成更方便,收率更高(从二酯化合物8计合成三尖杉碱的总收率可达10%)。

Thus,α,β-unsaturated ketones were prepared by base-catalized aldol condensation between substituted arylaldehydes and acetones. Using iodosobenzene diacetate as oxidants, the resulting α,β-unsaturated ketones will be transformed to β,γ-unsaturated carboxylic acid esters.

以不同取代的芳香醛跟丙酮缩合后可以得到α,β-不饱和酮,再用iodosobenzene diacetate做氧化剂氧化,可以成左卤o到β,γ-不饱和碳酸酯类化合物。

On the basis of molecular design and assembly, the polyoxometalate compounds supported by Keggin, Dawson, lacunary Keggin, and Silverton-type etc. polyanions on the basis of well-known and novel polyanions as building blocks were successfully synthesized by the hydrothermal technique, which are"decorated"or"bridged"by organic N-donor and/or O-donor ligands. The study on synthetic conditions and rules for these hybrid compounds and characterization by X-ray crystallography, spectroscopic, thermal, electrochemical and magnetic properties are carried out.

本文主要利用水热合成方法,从分子设计及组装的思想出发,借助不同N和含O的有机配体对多金属氧酸盐阴离子结构进行&修饰&或&桥连&,合成了一些以饱和Keggin结构、饱和Dawson结构、缺位Keggin结构和Silverton结构等阴离子为构筑模块的多金属氧酸盐化合物,研究了这些化合物的合成条件及规律并对它们的晶体结构、谱学性质、热性质以及磁性质进行了研究。

Qualitative and quantitative analysis of chemical constituents.(1) Based on the GC spectrum of 2 species, Whitmania pigra and Poecilobdella manillensis shows little difference between them. 24 kinds of fatty acid in Whitmania pigra was firstly separated and determined by GC/MS. Among them, phenylacetic acid is a component which has active of anticancer. The existence of many unsaturated fatty acid provides chemical evidence for ShuiZhi's functions of invigorate the circulation of blood.

六首次对两种水蛭的脂肪酸类化合物进行了GC定性分析,发现其脂肪酸组成未见明显差异,后又对宽体金线蛭的脂肪酸类化合物进行了GC-MS分析,初步鉴定出24个化合物,包括苯乙酸、龙脑和22种脂肪酸,其中所含的苯乙酸具有抗肿瘤活性,大量不饱和脂肪酸的存在为水蛭在血液流变学方面的药理作用提供了一定的化学依据。

In addition, the method for producing an amide-based polymer of the present invention is characterized by homopolymerizing the amide compound or by copolymerizing the amide compound and at least unsaturated monomer copolymerizable with the amide compound.

本发明的制备酰胺类聚合物的方法的特征在于均聚所述酰胺化合物、或共聚所述酰胺化合物和能与酰胺类化合物共聚的至少一种不饱和单体。

The results show that: processing aids which mainly consist of unsaturated aromatic hydrocarbon and aliphatic hydrocarbon resin are able to improve the dispersion of the wood flour in PVC matrix, and amend the interfacial compatibilities between PVC matrix and wood flour, and enhance the mechanical and processing properties of PVC/ wood flour composites; Processing aids which mainly consist of calcium soap and saturated fatty acid amide mixture, as well as fatty alcohol and fatty acid ester mixture, are also able to improve the dispersion of the wood flour in PVC matrix and enhance the processing property of the composites, but when the use amount is big, they have adverse effects on mechanical properties of the composites.

结果表明,以不饱和芳香族碳氢化合物、脂肪烃树脂为主要组分的加工助剂,能够提高木粉在PVC 基体中的分散性,改善木粉与PVC 的相容性,从而明显提高PVC木塑材料的力学性能和加工性能;以钙皂和饱和脂肪酸酰胺混合物、脂肪醇和脂肪酸酯的混合物为主要组分的加工助剂,对木粉的分散性和复合材料的加工性能有一定的改善,但其用量较大时对复合材料的力学性能有不利影响。

The principal component of water-soluble acids is the saturated aliphatic diacids of C〓 to C〓 and the saturated aliphatic monoacids of C〓 to C〓; and the water-insoluble acids are organic macromolecular compounds containing a large amount of carbonyl, carboxyl structures and aromatic group.

水溶酸的成分以C〓~C〓的饱和二元脂肪酸和C〓~C〓的饱和一元脂肪酸为主;水不溶酸是含有大量羰基、羧基结构和芳环的有机大分子化合物,其结构非常接近腐植酸。

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We will see more and more activist government policies that distinguish economic activities according to the nationality of the actors.

我们将看到越来越多激进的政府政策,这些政策根据企业的国籍来区分经济活动。

If we can prove the independence of an axiomatic system, then we can guarantee the conciseness of this system, ie.

如果能够证明某个一阶谓词系统的独立性,那么就能够保证该系统的建立是精炼的,即没有任何一条公理或推理规则是多余的。

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如果能使你的垃圾废物减少10%,就能减少1200磅的二氧化碳排放。