长

Between east and west, the mineralization in subalkalic intrusive complex is different. In the west, the veins are chiefly quartz veins, quartz veinlets and network veins, the wall rocks are mainly syenite and quartz monzonite. In the east, the fine quartz network veins, altered kata-rocks, alkali-syenite and syenite are dominant.

成矿作用在偏碱性侵入杂岩体的东部与西部有所不同，西部多以石英脉、石英细脉、网脉型为主，围岩以正长岩、石英二长岩为主；东部则多为石英细网脉和破碎蚀变岩型，围岩主要是碱长正长岩、正长岩。

The formation process of the rocks is divided for thefirst time into three cycles corresponding to J2, J3, and K1, respectively, and each cycle into early,middle, and late periods based on intruding contact relationship among different types ofgranitoids.3. A detailed study on the petrological characteristics of different cycles of theMesozoic granitoids supports classification of the rocks into three lithological associationsincluding A-type, high-K calc-alkaline, and calc-alkaline granitoids, of which the first associationbelongs to alkaline series, and the others belong to calc-alkaline series. It is shown that thelithologies change from diorite, quartz monzonite, and granodiorite to monzonitic graniteand syenogranite with periods from early to late in each cycle.4. A preliminary summarization hasbeen made on the evolution characteristics of the rocks.

首次将中生代花岗岩类划分为J2旋回、J3旋回、K1旋回等三个旋回，并依据不同岩石类型间的侵入接触关系，将每个旋回又划分为早、中、晚三期。3、在详细研究区内中生代不同时期花岗岩类岩石特征的基础上，首次将区内中生代花岗岩类划分为碱性系列碱质A型花岗岩类以及钙碱性系列高钾钙碱性花岗岩类和钙碱性花岗岩类等二个系列三种岩石组合类型，确定每个旋回从早期到晚期，岩石均具有从闪长岩、花岗闪长岩、石英二长岩-二长花岗岩-正长花岗岩演化的趋势。4、初步总结了区内中生代花岗岩类的演化特征。

The original defined adakitesare sodium igneous rocks, they are tonalite, trondhjemite or (plagioclase-rich) granodiorite in whole-rock chemistry; however, the K-rich "C-type" adakite defined by Chinese scholars are potassic igneous rocks, they are granite, quartz monzonite and (alkali feldspar-rich) granodiorite, etc.

最初定义的埃达克岩是钠质火成岩，其全岩化学成分相当于英云闪长岩、奥长花岗岩和花岗闪长岩；而富钾的"C型埃达克岩"全岩化学成分相当于花岗岩、石英二长岩和花岗闪长岩。

Calidonian granites are widely developed in the Yema Nanshan area in the western segment of the Qilian orogenic belt. The geochemical characteristics of most of the granites are similar to those of adakites: SiO2≥56%, Al2O3≥15.0%, low MgO (average 2.04%), high Sr (257-889μg/g, average 546.42μg/g), low Y (7.1-25.3μg/g,average 16.67μg/g), average Sr/Y=5.89, no pronounced Eu anomaly and Sr positive anomaly. Adakites in this area have five rock types, quartz diorite, quartz monzodiorite, quartz monzonite, monzogrannite and hornblende granite. These rocks commonly contain hornblende, belonging to I-type granites.

提要：祁连西段野马南山一带发育大量的加里东期花岗岩，其中大部分花岗岩具有与adakite岩相似的地球化学特征，SiO2≥56%， Al2O3≥15.0％，低MgO（平均2.04％），高Sr(257～889μg/g，平均值546.42μg/g)，低Y（7.1～25.3μg/g，平均16.67μg/g），Sr/Y平均为35.89μg/g，Eu无明显负异常，Sr正异常，Adakite岩石类型有石英闪长岩、石英二长闪长岩、石英二长岩、角闪花岗岩、二长花岗岩，岩石中普遍含有角闪石，属I型花岗岩，地球化学图解反映该花岗岩形成环境为板块碰撞前的岛弧型，锆石U-Pb同位素年龄为444+38/-33 Ma，处在祁连造山带板块俯冲收缩阶段，因此可以推断野马南山埃达克质Adakite花岗岩是俯冲板片部分融熔和壳幔岩浆混合形成的。

The Dabie Mountains are unique among ultrahigh pressure metamorphic terranes in having the most profound post collisional plutonism The Mesozoic shoshonitic and calc alkaline intrusive rocks can be divided into three groups with different isotopic ages, rock assemblages and chemical features Group I consists of late Triassic (~ 210 Ma) mafic monzodiorites It could have been generated by partial melting of enriched subcontinental lithosphere mantle due to slab breakoff Group II consists ma...

第 I组，主要由晚三叠世（约210 Ma）二长闪长岩辉长岩体组成，它可能是在板片断离过程中富集的大陆岩石圈地幔部分熔融的产物；第I I组，由中侏罗世－早白垩世（160～120 Ma）的角闪石英二长岩、黑云母二长花岗岩和正长花岗岩组成，主要是由幔源岩浆的分离结晶与地壳混染共同作用的产物；第II I组，以白垩纪（125～95 Ma）的花岗岩和花岗斑岩为代表，是在热穹窿作用过程中大别杂岩深熔作用和高度演化的产物。

The part of a historical period is single, be born on stem tuber, petiole grows 8 ～ 25cm, constant purple or green have violet spot, in mid and the following give birth to one bead bud; Form of form of egg of shape of blade long circle, egg of long triangle shape or form of heart shape halberd, grow 20cm of 5 ～, wide 3 ～ 8cm; Tip is long gradually pointed or submit end form sometimes, base form of ministry deep heart, often be above sinuosity have 1 bead shoot, above green, often take below lilac, whole reason, side arteries and veins feather shape, combination is in in close brim.

叶单一，生于块茎上，叶柄长8～25cm，常紫色或绿色具紫斑，在中部以下生一珠芽；叶片长圆状卵形。长三角状卵形或心状戟形，长5 ～20cm，宽3～8cm；先端长渐尖或有时呈尾状，基部深心形，常在弯曲处上面有1珠芽，上面绿色，下面常带淡紫色，全缘，侧脉羽状，在近边缘处联合。

Leaves tufted; stipes 15-30 cm long, densely scaly at base, glabrous above; sterile lamina about 60 cm long and 20 cm wide, simply pinnate; pinnae numerous, alternate or subopposite, linear-lanceolate, the largest about 12 cm long and 1 cm wide, base cordate, apex acuminate, margin finely toothed; veins close, forking once or twice and forming areoles near the midrib; fertile lamina similar to sterile ones, but somewhat reduced, about 8 cm long and 0.4 cm wide, lower surface almost entirely covered with sporangia.

叶簇生；叶柄长15-30厘米，基部密被鳞片，向上近光滑；不育叶片长约60厘米，宽20厘米，一回羽状；羽片多数，互生或近对生，线状披针形，最长者长达12厘米，宽约1厘米，顶端长渐尖，基部心形，边缘有细密锯齿；叶脉1-2次分叉，近中脉形成网眼；能育叶与不育叶相似，但较小，长约8厘米，宽约0.4厘米，下部满布孢子囊。

Leaves in opposite pairs, thin coriaceous, oblong, or phi needle-shaped, long 6-14 cm, the top length gradually sharp, pointed or slightly blunt wedge base, edges wavy or light wavy; petiole length 8-15 mm; stipule wide and triangular, was born in the Ministry of young vine at the top of drill-like long-tip , was born in the old vine, 3-6 mm long, the top regular convex tip.

叶对生，薄革质，矩圆形或披针形，长6—14厘米，顶端长渐尖，基部楔尖或略钝，边缘波状或浅波状；叶柄长8—15毫米；托叶宽三角形，生于幼枝上部的顶端钻状长尖，生于老枝上的长3—6毫米，顶端常凸尖。

The Indosinian granitoid belt in South Qinling, Central China, is lithologically composed of diorite, monzodiorite, tonalite, granodiorite and granite, as well as widely distributed mafic microgranular enclaves and dykes within the intrusions.

南秦岭印支期花岗岩带的岩石组合包括闪长岩、二长闪长岩、英云闪长岩、花岗闪长岩和花岗岩等，岩体内广泛存在镁铁质微粒包体和脉体。

In this thesis,the AM1,MNDO,MINDO/3(mainly AM1)and INDO/S-CI semiempirical MO methods were used toinvestigate the excited-state intramolecular protontransfer reactions of salicylic acid derivatives—salicylic acid,methyl salicylate,salicylaldehyde,o-hydroxyaceto-phenone,salicylamide and 3-hydroxy-picolinamide (6 conformers and 2-3 anion species);2-(2'-hydroxy-5' methylphenyl) benzotriazole(4 conformers),2-(2' hydroxyphenyl) benzimidazole (3 conformers and 3anion species),Bis-2,5-(2-benzoxazolyl)hydroquinone(3 conformers),2-(2'-hydroxyphenyl)benzothiazole(2conformers) and 7-azaindole dimer (2 conformers).Theinvestigations were described as follows.Geometry optimization,relative stability andhydrogen bonding energy First,for sylicylic acid derivative molecules,the AM1,MNDO and MINDO/3 methods were used toinvestigate ground-state geometry optimization,energies,relative stabilities and hydrogen-bondingenergies on the five kinds of the molecules(designing 6 conformers and 2-3 anion species).Comparing with experimental data,the optimizedgeometry,the order of stability,the hydrogen-bonding energies and the distances between O-O in O-H..O hydrogen bonds by AM1 method were in agreementwith the experimental data,however,the C-C bondlengths optimized by MNDO and MINDO/3 were longer,C-O and O-H bond lengths were shorter;for C-N bondlengths,the results opitimized by MNDO method werethe same as those by AM1 method,nevertheless the C-Nbond lengths given by MINDO/3 method were muchshorter.For some sylicylic acid derivatives(e.g.methyl salicylate,salicylamide),the order ofstabilities on the conformers given by MNDO andMINDO/3 methods were not in agreement with theexisting conformers deduced by experimental methods,and the hydrogen bonding energies calculated by MNDO.and MINDO/3 methods were smaller.Second,the studyon the other systems found that the optimizedgeometry of the proton-transfered product with INDOmethod could not be obtained,only could theoptimized geometry of reactant be obtained,and thecalculated hydrogen bonding energies were greater.Many results of calculation indicated that the studyon the excited-state intramolecular proton transferreaction system using AM1 method was suitable andreliable.

本论文用AM1、MNDO、MINDO/3（主要是AM1）和INDO/S-CI半经验分子轨道方法对水杨酸衍生物系列——水杨酸、水杨酸甲酯、水杨醛、O-羟基乙酰苯酮、水杨酰胺和3-羟基吡啶酰胺（6种异构体和2-3种阴离子）；2-（2'-羟基-5'-甲基苯基）苯并三〓唑（4种异构体）；2-（2'-羟基苯基）苯并咪唑（3种异构体和3种阴离子）；2，5-二间氮杂氧茚氢醌（3种异构体）；2-（2'-羟基苯基）间〓杂硫茚（2种异构体）和7-〓吲哚二体（2种异构体）的激发态分子内质子转移反应在以下几个方面进行了较系统的理论研究：几何构型优化和相对稳定性及氢键能首先以水杨酸衍生物系列分子为例，用AM1、MNDO和MINDO/3方法考察了5种分子（每种分子设计6种异构体和2-3种阴离子）的基态几何构型优化，能量、相对稳定性和氢键能计算，通过和实验数据进行比较，AM1方法给出的优化几何构型、稳定性次序、氢键能和O—H。。。O氢键的0—0距离与实验数据吻合最好，MNDO和MINDO/3方法优化的C-C键长偏长，C-O键和O-H键长偏短；对于C-N键长，MNDO和AM1优化结果差别不大，而MINDO/3给出了过短的C-N键长，MNDO和MINDO/3方法给出的有些水杨酸衍生物分子（如水杨酸甲酯和水杨酰胺）异构体的稳定性次序和实验上推测的可存在异构体结果不一致，MNDO和MINDO/3方法给出的氢键能偏低，对其他体系的研究发现INDO方法常常不能得到质子转移产物的优化几何构型，只能得到反应物的优化构型，并且估算的氢键能偏高，大量的计算结果表明AM1方法对本论文研究的激发态分子内质子转移反应体系是适宜和可靠的。

In her eyes, because that is the doorway toher heart * the place where love resides.

女人的漂亮必須從她的眼睛中去看，因為那是她心靈的窗戶和愛居住的地方

I will send some postcards to you.

我会向你发送一些明信片。