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By analyzing the crystal structure of ilmenorutile and the infrared spectrums of ilmenorutile reacted before and after with alkylhydroxyoximate, the adsorption form between ilmenorutile and alkylhydroxyoximate can be proved to be chemical adsorption.

通过铌铁金红石晶体结构和铌铁金红石与烷基羟肟盐作用前后红外光谱的分析,论证了铌铁金红石与烷基羟肟盐的吸附形式为化学吸附,并确定了烷基羟肟盐在铌铁金红石表面的吸附模型。

Under normal temp., PVF2 has a fine corrosion resistance to many organic solvents like halogen, halogenated hydrocarbon, strong oxidant, boiling acid and alkali; UHMWPE has a fine corrosion resistance to inoxidable acid (dilute sulfuric acid, nitric acid and large concen-tration hydrochloric acid, phosphorus acid, hydrofluoric acid, formic acid and acetic acid), ammonia, amine and various alkali and salty solutions. Both materials can't resist the corrosion of strong oxidable acid.

在常温下,PVF2对卤素、卤代烃、强氧化剂、沸、碱等多种有机溶剂都有良好耐蚀性;UHMWPE对非氧化性(稀硫、硝及浓度较大的盐、磷、氢氟、甲、乙)、氨和胺及各种碱、盐溶液都有良好的耐蚀性,两种材料都不耐强氧化性的腐蚀。

Under normal temp., PVF2 has a fine corrosion resistance to many organic solvents like halogen, halogenated hydrocarbon, strong oxidant, boiling acid and alkali UHMWPE has a fine corrosion resistance to inoxidable acid (dilute sulfuric acid, nitric acid and large concen-tration hydrochloric acid, phosphorus acid, hydrofluoric acid, formic acid and acetic acid), ammonia, amine and various alkali and salty solutions. Both materials cant resist the corrosion of strong oxidable acid.

在常温下,PVF2对卤素、卤代烃、强氧化剂、沸、碱等多种有机溶剂都有良好耐蚀性;UHMWPE对非氧化性(稀硫、硝及浓度较大的盐、磷、氢氟、甲、乙)、氨和胺及各种碱、盐溶液都有良好的耐蚀性,两种材料都不耐强氧化性的腐蚀。

Under normal temp., PVF2 has a fine corrosion resistance to many organic solvents like halogen, halogenated hydrocarbon, strong oxidant, boiling acidalkali; UHMWPE has a fine corrosion resistance to inoxidable acid (dilute sulfuric acid, nitric acidlarge concen-tration hydrochloric acid, phosphorus acid, hydrofluoric acid, formic acidacetic acid), ammonia, aminevarious alkalisalty solutions. Both materials can't resist the corrosion of strong oxidable acid.

在常温下,PVF2对卤素、卤代烃、强氧化剂、沸、碱等多种有机溶剂都有良好耐蚀性;UHMWPE对非氧化性(稀硫、硝及浓度较大的盐、磷、氢氟、甲、乙)、氨和胺及各种碱、盐溶液都有良好的耐蚀性,两种材料都不耐强氧化性的腐蚀。

Mol/L. 3 A study on the ECL of acridinum esters including 10--acridinium-9-carboxyl-phenyl-ester iodinate and 10-methyl-9-(p-formylphenyl)-acrdiniumfluorosulphonate in neutral solution was carried out. It was found both CACPEI and MFPA give strong ECL in KNO〓 solution when an appropriate voltage was applied on Pt electrode.

本文研究了碘化10-乙羧基吖啶-9-羧苯酯和对甲酰基苯基-10-甲基吖啶-9-羧酯氟磺盐的ECL行为,发现在中性KNO〓介质中,这两种吖啶酯都能在一定的电位下产生很强的ECL信号,考察了各种影响因素,确定了发光的最佳条件,探讨了可能的发光机理。

Thirdly, on the basis of the optimal reaction conditions of synthesis of borneolacetate, using borneol 、 isoborneol, acetic acid, propionate、 butyrate and isobutyric acid as the starting material and nanometer solid superacid (S_2O_8)~(2-)/ZrO_2 or (SO_4)~(2-)/ZrO_2-La_2O_3 as the catalyst ,a series of compounds ( borneol ester and isoborneol ester ) which had six new compounds were prepared.

以合成乙冰片酯的最佳反应条件为基准,采用纳米固体超强S_2O_8~(2-)/ZrO_2或SO_4~(2-)/ZrO_2-La_2O_3为催化剂,以冰片、异冰片、乙、丙、丁、异丁为原料,合成了系列正、异冰片酯(其中6个末见文献报道)。

In this work, isobutyl isobutyrate was prepared by the condensation of two molecular isobutyraldehyde in the presence of aluminium isobutoxide catalyst system.

依据间歇反应所得一系列数据,确定了异丁醛连续缩合反应工艺流程;考察了以异丁醛为原料,在 5~10℃,停留时间 1 5~ 2h ,在异丁氧基铝催化体系作用下,两分子异丁醛缩合成一分子异丁异丁酯;脱除催化剂后,粗产品精制得到纯度≥ 99 5 %的异丁异丁酯,异丁醛的转化率≥ 98 5 %,异丁异丁酯的选择性≥95 %。

With LaCl_3·7H_2O as catalyst to replace conventional liquid inorganic acid,and the esterificationbetween isobutyric acidand n-butyl alcohol as a probe reaction,the optimum conditions were investigated and various isobutyrate s were synthesized over it in this paper.

7H2O替代传统液体无机为催化剂,以合成异丁正丁酯为探针反应考察催化酯化反应的优化条件,并在此条件下合成了多种异丁酯,比较了不同催化剂对催化合成异丁正丁酯的影响。

At first, urea decomposed into isocyanic acid, which interacted with ZnO to form a relatively steady isocyanate species. Then propylene glycol reacted with isocyanate species to form hydroxypropyl carbamate, and the HPC lost ammonia to form PC.

结果表明,该反应是分步进行的,首先尿素分解生成氨气和异氰,异氰与ZnO作用形成异氰物种,在丙二醇的作用下生成中间产物羟丙基氨基甲酯,然后由HPC脱氨气生成PC。

Isocyanurate based on TDI was synthesized and the heat-resistance property of casting polyurethane elastomer which synthesized using isocyanurate based on TDI and PEPA was obviously enhanced compared to polyurethane elastomer which did not introduce the isocyanurate by the TGA under the different temperature and the mechanics performance maintenance rate at high temperature.

在催化剂作用下,合成了TDI-100型异氰脲酯,并与己二乙二醇丙二醇酯合成了浇注型聚氨酯弹性体,通过不同温度下的热失重分析和弹性体的力学性能高温保持率对比分析表明,在TDI型聚氨酯弹性体中引入异氰脲酯基团,可明显提高弹性体的耐热性能。

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