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The affections on the yield of DLLA caused by catalyst, temperature and time etc. were studied. By using ethylene glycol as diluent, the distillate temperature of DLLA was lowed and the carbonization phenomenon could be avoided, which caused the yield of DLLA increasing from 36.8% to 51.3%. The molecular weight of PDLLA prepared by this method could reach 184,000. DLLA and PDLLA was characterized and analyzed by DSC, XRD and IR.The key of direct method to synthesize PDLLA is the exclusion of H2O from reaction system.

丙交酯开环聚合制备PDLLA的关键在于中间体D,L-丙交酯的制备,研究了催化剂、反应温度、反应时间等因素对DLLA产率的影响,通过在反应体系中加入稀释剂乙二醇,DLLA的馏出温度明显降低,避免了DLLA在蒸馏过程中产生碳化现象,并使DLLA的平均产率由36.8%提高至51.3%,制备的PDLLA分子量最大值达18.4万。

Such a phenomenon suggests that the outline of the hyperbranched polymers formed in the polycondensation of ABg type monomers is almost independent of the g at any specified conversion, since that the radius of gyration is decided by the shape and distribution.

这一现象表明在任何指定的A转化率,ABg型缩聚中形成的超支化聚合物的分子轮廓与g无关,随着2增大而在超支化聚合物中增加的结构单元(或聚合度1必定分布在分子内部。

The results indicated that the nanocomposites under applied magnetic field exhibited the hysteresis loops of...

结果表明,复合物在室温外加磁场下表现出亚铁磁性物质具有的磁滞现象,铁氧体颗粒对苯胺的聚合起到了核的作用;复合物中铁氧体与聚苯胺之间存在着比较明显的键合作用,探讨了铁氧体与聚合物分子链之间的键合机制。

The semicrystalline precipitation phenomenon of the thiourea/formaldehyde polycondensation was described for the first time.

首次报道了硫脲甲醛聚合反应中的半结晶沉淀现象。

We assumed that after the PACl〓 was dosed into water, its hydrolysis-aggregation-precipitation process combined the most popular"core-link"or hexameric ring scheme and the more recent model of polynuclear formation involving a typical specie of tridecameric,〓. The integrate pattern can nicely explained the phenomena.

另外,研究表明,PACl中预制的Alb形态和铝盐在混凝过程投加入水后形成的Alb形态在稳定性上有很大的区别,这无疑是由于它们的化学结构上的不同造成的,推测铝盐在投加入水后,其水解聚合过程按&六元环&模式〓和&核环&模式〓结合进行,这种综合模式可以很好的解释实验中的现象。

The results of RT-PCR show that zebrafish treaded TAA 10th day made adipogenetic and lipogenetic up-regulated on the 3th and 5th day, because on TAA treated control Data show that lipogenetic gene would up-regulate at 9th day, so overexpression of PPARγ enhance TAA induced fatty liver.

反转录聚合链反应结果显示转殖PPARγ经TAA处理十天后,在第三有提高的现象,但是从硫乙胺处理控制组的结果显示第9天时,脂肪生成相关基因才会上升,故PPARγ的表现加强了硫乙胺诱导脂肪肝的形成过程。

The stability of GA-PBCA-NP was also studied.ResultsDue to the agglomerationg of nanoparticles with no stabilizer,it was difficult to preparate.GA-PBCA-NP produced by the two methods both had spheric and smooth outer appearance,uniform distribution,nonadherence and stability.The diameter,ebeding ratio and drug loading in GA-PBCA-NP produced by emulsification polymerization and interfacial polymerization methods were 90~600 nm and 200 nm,60.49% and 73.87%,18.15% and 22.23%,respectively.

结果未添加稳定剂的纳米球表面粘连团聚现象严重,难以成球;乳化聚合法制备的GA-PBCA-NP在透射电镜下观察表面圆整光滑,粒子之间不团聚,不黏连,粒径范围在90~600 nm,包封率为60.49%,载药量为18.15%;界面缩聚法制得的纳米粒表面圆整光滑,粒子之间不团聚,不黏连,粒径大小均匀,都在200 nm左右,包封率为73.87%,载药量为22.23%,两种方法制备的稳定性都较好。

GA-PBCA-NP produced by the two methods both had spheric and smooth outer appearance,uniform distribution,nonadherence and stability.The diameter,ebeding ratio and drug loading in GA-PBCA-NP produced by emulsification polymerization and interfacial polymerization methods were 90~600 nm and 200 nm,60.49% and 73.87%,18.15% and 22.23%,respectively.ConclusionIt is important to add dextran 70 in preparation.

结果未添加稳定剂的纳米球表面粘连团聚现象严重,难以成球;乳化聚合法制备的GA-PBCA-NP在透射电镜下观察表面圆整光滑,粒子之间不团聚,不黏连,粒径范围在90~600 nm,包封率为60.49%,载药量为18.15%;界面缩聚法制得的纳米粒表面圆整光滑,粒子之间不团聚,不黏连,粒径大小均匀,都在200 nm左右,包封率为73.87%,载药量为22.23%,两种方法制备的稳定性都较好。

Many previous observations of △131△ should be reinterpreted in terms of the self-association equilibrium.

以前在变性片段△131△观察到的许多现象需要用聚合平衡重新解释。

In compared with acceptor emitters, not only can the emission wavelength be tuned (up to 100 nm of red-shift) by H-bonds, but also much higher emission efficiencies of the H-bonded complexes were induced by reduced aggregation and energy transfer from the OXD donor dendrons.

另外,在使高分子形成高分枝结构之研究上、利用不同含量与不同官能基数目之carbazole单体与茀单体进行聚合,可得一系列高分枝状高分子,能使聚茀共轭高分子产生不同之分枝程度结构,这样方式有效改善分子间聚集之现象并且维持高分子主链良好共轭程度,使得产生之高分子具良好的萤光效率。

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