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联乙炔

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The absorption spectra of the terpyridyl platinum acetylide complex containing monoazacrown moiety in the acetylide ligand was blue-shifted upon complexation with metal cations.

对位带有氮杂-15-冠-5冠醚的苯乙炔为辅助配体的三联吡啶Pt络合物TAC在金属离子的存在下吸收光谱的变化明显不同。

The energy of excited state depended on the nature of different cations. 3. 4-(4-tolyl)-6-phenyl-2, 2'-bipyridine platinum acetylide complex containing a monoazazcrown moiety in the acetylide ligand could signal Mg〓 specifically and displayed large changes both in color and in luminescence intensity upon complexation with Mg〓. The most striking result was that it could signal Mg〓 specifically even in the presence of alkali and alkaline earth metal ions in high concentrations.

对位带有氮杂-15-冠-5冠醚的苯乙炔为辅助配体的4-(4-甲基苯基)-6-苯基-2,2'-联吡啶Pt络合物AC,不仅在碱金属和碱土金属的存在下吸收光谱明显改变,更有意义的是,它只有在Mg〓离子存在时能够发光,因此可以通过发射光谱选择性的识别Mg〓,尤其可以在高浓度的其它金属离子存在下选择性的检出Mg〓离子。

A self-assembled monolayer film of tolane was fabricated in aqueous solution by using silane coupling agent.

用硅烷偶联剂3-氨丙基-三乙氧基硅烷,通过自组装反应在石英基板表面制备了含有二苯乙炔基的自组装单层膜。

In the second chapter, a rational synthetic route for enantiopure 2,2'-diethynyl-1,1 '-binaphthyl was established.

在论文的第二章,主要讨论了具有单一手性(R构型或构型的2,2'-二乙炔基-1,1'-联萘模板的合成。

EVA/LDPE/ CB conductive foam was made of EVA and LDPE as matrix,HG-1P CB and ACET CB as conductive filler,AC as foamer and DCP as crosslinker.

文章以乙烯-乙酸乙烯酯和低密度聚乙烯为主基体,特导炭黑(HG-1P)和乙炔炭黑为导电填料,偶氮二甲酰胺为发泡剂,过氧化二异丙苯为交联剂,制备了EVA/LDPE/炭黑导电泡沫复合材料。

The target molecules were synthesized through a Sonogashira coupling reaction of 1-trans-4-(trans-4-n-pentylcyclohexyl)cyclohexylacetylene and 4-iodo-2,3-difluoro- phenyl ether with total yields of 27%~28%.

目标化合物采用1-trans-4-(trans-4-正戊基环己基)环己基乙炔与4-碘-2,3-二氟苯基醚进行Sonogashira偶联反应制备,反应总产率27%~28%。

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