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Simultaneously, how the gum acacia affects the hydrolysis rate constants of fatty acid esters in 38.6% ethanol solution, and the combination behavior between gum acacia and fatty acid esters have been found. And the way to determine the combination costants between them quantitatively is also found. In addition, the validated quantitative mathematic expression between hydrolysis rate constants of ester and the concentration of gum acacia: k=k'/(1+AM) is verified.

同时研究了38%乙醇溶液中阿拉伯胶与脂肪酸酯之间的缔合行为,并建立了定量确定缔合常数的方法,推导并验证了定量表达酯水解速率常数k与GA浓度关系的数学表达式:k'=k/(1+AM),得出了GA对脂肪酸酯水解起禁阻作用的结论。

Furthermore, the difference of δ-x curve trend between methanol+DMF system and methanol+ hexane system is discussed.

讨论了醇与DMF体系和醇与正己烷体系核磁共振化学位移随醇的浓度变化趋势的差异,认为醇与DMF形成比醇的自缔更强的交叉缔合是造成这种变化趋势不同的主要原因。

The experimental results show that hydrophobic association increases obviously with increasing polymer concentration, hydrophobe content, hydrophobic side chain length and temperature. The Critical aggregate concentration of P(AM/NaAA/C_8AM) with different hydrophobic content is 1.5-3g/L. Strong ass...

结果表明,随聚合物浓度、疏水单体摩尔分数、疏水侧链长和温度的增加,疏水缔合作用增强;不同疏水单体含量的P(AM/NaAA/C8AM)的临界缔合浓度为1.5~3.0 g/L;表面活性剂十二烷基硫酸钠与P(AM/NaAA/C8AM)发生了强烈的疏水相互作用,形成混合胶束,得到SDS的临界胶束浓度为8×10-3 mol/L;由于聚合物链上羧基的存在,使其具有良好的 pH敏感性,随 pH值的增大,P(AM/NaAA/C8AM)的疏水缔合作用呈现先减弱后恒定再增强的变化。

The experimental results show that hydrophobic association increases obviously with increasing polymer concentration, hydrophobe content, hydrophobic side chain length and temperature. The Critical aggregate concentration of P (AM/NaAA/C8AM) with different hydrophobic content is 1.5~3g/L. Strong association between surfactant sodium dodecyl sulfate and P (AM/NaAA/C8AM) occurs through the formation of mixed micelles. The CMC of SDS is 8×10^(-3)mol/L. Moreover, because of the presence of-COOH group, the terpolymers have pH-responsive characterization. The hydrophobical association changes greatly with increasing pH.

结果表明,随聚合物浓度、疏水单体摩尔分数、疏水侧链长和温度的增加,疏水缔合作用增强;不同疏水单体含量的P(AM/NaAA/C8AM)的临界缔合浓度为1.5~3.0g/L;表面活性剂十二烷基硫酸钠与P(AM/NaAA/C8AM)发生了强烈的疏水相互作用,形成混合胶束,得到SDS的临界胶束浓度为8×l0^(-3)mol/L;由于聚合物链上羟基的存在,使其具有良好的pH敏感性,随pH值的增大,P(AM/NaAA/C8AM)的疏水缔合作用呈现先减弱后恒定再增强的变化。

The mechanism of the synergic effect of CNTs and PVA was discussed in this work.The ion association complex of Hep and EV noncovalented with CNTs through π-stacking, the hydrophilic property of which was improved in the presence of PYA.

在此缔合物显色体系中,含芳香环大分子的EV通过π~π作用于CNTs的管壁上,增大了有色物质的吸光面积;PVA的加入提高了CNTs及离子缔合物的分散性。

The optimum conditions and the influence factors were investigated, and the composition of ion-association complexes and the reaction mechanism were also discussed. The effects of foreign substances were tested and it is shown that the method has a good selectivity. Based on HgCl2 and basic triphenylmethane dye, the sensitive, simple and rapid method for the determination of trace CTRX was developed.

研究了适宜的反应条件和影响因素,对离子缔合物的组成和离子缔合反应机理进行了探讨,考察了共存物质的影响,表明方法有良好的选择性,据此发展了用HgCl2和碱性三苯甲烷类染料的灵敏、简便、快速测定痕量头孢噻肟钠的新方法。

In pH 5.3-6.8 Britton-Robinson buffer medium, Cefotaxime sodium can react with HgCl2 to form 1:1 anionic chelate, which can further react with basic triphenylmethane dye such as crystal violet, methyl violet, ethyl violet, brilliant green, iodine green, methyl green and malachite green to form ternary ion-association complexes. As a result, the resonance Rayleigh scattering spectrum was enhanced greatly.

在pH为5.3~6.8的Britton-Robinson缓冲溶液中,头孢噻肟钠与HgCl2形成摩尔比为1:1的螯合阴离子,它能进一步与结晶紫、甲基紫、乙基紫、亮绿、碘绿、甲基绿和孔雀石绿等碱性三苯甲烷类染料反应形成三元离子缔合物,导致共振瑞利散射的显著增强。

The results can be expressed as follows:(1) With the increase of water phase content, the amine salt aggregated orderly in different forms such as W/O micro-emulsion, nodus-knot catenulate aggregates, layer liquid crystal and O/W micro-emulsion.(2) In layer liquid crystal, SO〓 mainly combined with amine salt cation by two oxygen atoms in bridge.(3) In UV-VIS spectrum of layer L. C., there is an absorption about 500 nm and "light short circuit"appeared about 430 nm. These phenomena may be very important for measuring the distance between the layers of the L.

研究发现该体系随水相含量的增加,胺盐发生不同形式的有序缔合,分别形成了W/O型微乳液、&节-结&型链状缔合体、层状液晶和O/W型微乳液:在层状液晶中,SO〓主要以桥式双齿配位形式存在,中性胺分子有利于体系中液晶的形成;层状液晶于500nm波长处有一吸收峰,在430nm附近发生&光短路&现象,该现象可能对测定层状液晶的层间距有重要意义。

The hydrophobic association thickening behaviors are also remarkably dependent on the number and length of the hydrophobic block in polymer chain, Rheological properties were further studied as a function of polymer concentration, salinity, temperature and shear rate.

这种由分子间的疏水缔合作用而产生的疏水缔合增黏能力与疏水嵌段的数量和长度密切相关。同时进一步研究了聚合物浓度、盐浓度、温度和剪切速率对溶液黏度的影响。

By using quantum statistics,this paper obtains the calculation formula of entropy of phonons and initial results,and points out that the entropy of phonons plays an important role in the associated reaction of two kinds of anion structural groups in silicate melts.

熔体阴离子结构团缔合过程中声子熵的研究何安明李秉新石焕文(西安地质学院,西安710054)关键词熔体阴离子结构团缔合声子熵近年来,中外学者已经开始重视对岩浆熔体的物理过程和机制(如利用喇曼光谱直接测定硅酸盐熔浆的结构等)的研究工作,并取得了重要进展。

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