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碱土金属

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The mechanism, thermodynamics and kinetics of ion-exchange reactions between alkali, alkaline-earth and transition metal ions and zirconium phosphate and its derivatives are reviewed, progress in ion-exchange reaction between luminescent metal complex and zirconium phosphate is also discussed.

本文综述了碱金属、碱土金属、过渡金属离子等与磷酸锆及其衍生物的离子交换反应机理、热力学和动力学特性,另外也讨论了发光金属配合物与磷酸锆的离子交换反应研究进展。

The reaction performance that the soda acid sex of carrier and the size of the area that compare a list affect activator directly, of the compound carrier surface that decorates via alkaline-earth metal alkalescent increase, rose to leave capacity to the adsorptive solution of CO2, activation agent is shown in reforming reaction better fight carbon deposit ability.

载体的酸碱性和比表面积的大小直接影响到催化剂的反应性能,经碱土金属修饰的复合载体表面的碱性增强,提高了对CO2的吸附解离能力,使催化剂在重整反应中表现出较好的抗积炭能力。

The invention relates to a method for making oligomeric isocyanates by reacting diisocyanates in the presence of a catalyst, wherein the catalyst comprises a saline compound prepared from an anion selected from 1,2,3- or 1,2,4-triazole, a substituted species of 1,2,3- or 1,2,4-triazole and carbocyclically and/or heterocyclically annellated species of 1,2,3- or 1,2,4-triazole and the cation selected from an alkali metal, alkaline-earth metal and/or monovalent ammonium cation and/or phosphonium cation of formula (5), wherein the E, R1, R2, R3, R4 are as defined in the descriotion.

本发明涉及一种制备低聚异氰酸酯的方法,包括二异氰酸酯在催化剂的存在下进行反应,其中所述催化剂由盐化合物组成,该盐化合物由选自1,2,3-或1,2,4-三唑、1,2,3-或1,2,4-三唑的取代系列者、1,2,4-三唑的碳环稠合系列者、1,2,3-或1,2,4-三唑的杂环稠合系列者的化合物及其混合物的阴离子和选自碱金属、碱土金属和/或通式(5)的一价铵阳离子和/或磷友衾胱拥难衾胱又票福其中E、R 1 、R 2 、R 3 和R 4 如说明书中所定义。

The effects of the type and concentration of alkaline-earth metal ions are systemically investigated on removing OH groups of erbium-doped phosphate glasses, by using fluoresent lifetime of erbium-doped phosphate glasses varying with OH concentration.

以掺铒磷酸盐玻璃中铒离子寿命随OH含量变化为依据,系统研究了碱土金属离子类型和含量对磷酸盐铒玻璃除水性质的影响。

The raw materials used by the method are green chemicals dimethyl carbonate and p-nitrophenol, and the catalyst is NaY molecular sieve, activated aluminum oxide or activated carbon which is impregnated by alkali metals or alkaline-earth metal compounds.

本发明涉及到一种合成对硝基苯甲醚的方法,该方法所用的原料为绿色化学品碳酸二甲酯和对硝基苯酚,催化剂是经碱金属或碱土金属化合物浸渍过的NaY分子筛、活性氧化铝或活性碳。

Alkalescence a flux, such as alkali metals and alkaline-earth metal, zinc oxide and most stain oxide or chromophores components are gender neutral, the principal is alumian oxide, sometimes hemaite and electrolyic, and so on are also included in this composition; acidic components of oxide for silica, phosphoric acid, zirconia, etc.

碱性成分为熔剂,如碱金属、碱土金属、氧化锌及多数的着色氧化物或发色基团;中性成分为两性氧化物,主体为氧化铝,有时将氧化铁和氧化锰等也列入此成分中;酸性成分中有代表性的氧化物为氧化硅、磷酸、氧化锆等

Transition probabilities, oscillator strengths, and lifetimes of configurations, multiplets, and individual lines for many-electron atoms and ions are studied employing the WBEPM theory. Transition probabilities and oscillator strengths for alkali metal atoms, alkaline-earth elements Be, Mg, Be , and Mg , carbon atoms and its ions , nitrogen atom and its ions , oxygen atoms and its ions , fluorine atom, Ne , and IB elements are calculated. Lifetimes of C, N, and O atoms are evaluated as well.

运用WBEPM理论对多电子原子和离子的组态、谱项和能级间的跃迁几率、振子强度以及辐射寿命进行系统地研究,计算了碱金属原子、碱土金属的Be、Mg原子及其一价离子、C原子及其离子、N原子及其离子、O原子及其离子、F原子、Ne离子和重金属IB族原子的跃迁几率和振子强度以及C、N、O原子的辐射寿命。

Alkali metal; Alkaline-earth metal; ionic salvation; ionic association ; quantum chemistry

碱金属;碱土金属;离子溶剂化;离子缔合;量子化学

The invention relates to a method for the extraction of keratin from dead animal skins, characterised in the treatment of dead animal skins with a substance of general formula, or at least one corresponding alkali metal, earth alkali metal, ammonium, or phosphonium salt, the variables having the following definitions: R, R = together or independently, H, C6-C14 aryl, C1-C12 alkyl, unsubstituted or substituted with one or several SH or OH groups, R, R = together or independently, H, C6-C14 aryl, C1-C12 alkyl, unsubstituted or substituted with one or several SH or OH groups, whereby at least one of R or R is not H, or R and R are not H and two vicinal groups of R to R together may be C3-C10 alkylene, R = H, C1-C12 alkyl, H-C=O or C1-C4-Alkyl-C=O, X, X, X and X = OH, SH or NHR, whereby where Rto R contains at least one sulphur atom, at least one of X to X = SH and where R to R contains no sulphur atom, at least two of X to X= SH.

本发明涉及一种从死亡动物原皮中除去角质的方法,其特征在于用通式I的物质或至少一种对应的碱金属盐、碱土金属盐、铵盐或∴盐处理死亡动物原皮,式I中各变量定义如下:R 1 和R 4 相同或不同且选自氢、C 6 -C 14 芳基和C 1 -C 12 烷基,其未被取代或被一个或多个SH或OH基团取代;R 2 和R 3 相同或不同且选自氢、C 6 -C 14 芳基和C 1 -C 12 烷基,其未被取代或被一个或多个SH或OH基团取代,其中至少一个基团R 2 或R 3 不为氢,或R 1 和R 4 不为氢,且两个相邻基团R 1 -R 4 可以一起为C 3 -C 10 亚烷基;R 5 选自氢、C 1 -C 12 烷基、H-C=O或C 1 -C 4 烷基-C=O;X 1 、X 2 、X 3 和X 4 选自OH、SH和NHR 5 ,其中若R 1 -R 4 含有至少一个硫原子,则至少一个基团X 1 -X 4 为SH,以及若R 1 -R 4 不含硫原子,则至少两个基团X 1 -X 4 为SH。

Said mineralizing agent is the fluoric alkali-earth metal salts or alkali metal salts (potassium fluoride or calcium fluoride).

其特征是在磷酸钙盐与碳酸钙盐以2∶1比混合物中,加入0.5~3wt%的含氟离子碱土金属或碱金属盐矿化剂,例如氟化钾、氟化钙等。

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