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硫酸镁石

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This paper presents the experimental data of metastable phase equilibrium of Na+, K+, Mg2+∥Cl-, SO2-4-H2O quinary system at 35 ℃, from which the metastable phase diagram is drawn. It consists of nine regions of crystallization saturated with sodium chloride, potassium chloride, glasserite(3K2SO4*Na2SO4), leonite(K2SO4*MgSO4*4H2O), kainite(KCl*MgSO4*2.75H2O), thenardite(Na2SO4), astrankit(MgSO4*Na2SO4*4H2O), carnallite(KCl* MgCl2*6H2O), magnesium sulfate hexahydrite(MgSO4*6H2O) and bischofit(MgCl2*6H2O).

研究得出(Na+, K+, Mg2+∥Cl-, SO2-4-H2O)五元体系35 ℃时的介稳溶解度数据,绘制了该体系35 ℃的介稳相图,共有9个为氯化钠所饱和的结晶区域:氯化钾、钾芒硝(3K2SO4*Na2SO4)、钾镁矾(K2SO4*MgSO4*4H2O)、钾盐镁矾(KCl*MgSO4*2.75H2O)、光卤石(KCl*MgCl2*6H2O)、白钠镁矾(Na2SO4*MgSO4*4H2O)、硫酸钠、六水硫酸镁(MgSO4*6H2O)和水氯镁石(MgCl2*6H2O)。

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