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环乙烯

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Propyleneoxide is produced with chlorohydrin method or Halcon method which gives rise toenvironmental pollution or a large amount of co-product.

是最洁净、廉价的氧源,但工业上除乙烯外,其它环氧化合物还不能通过〓直接高选择性环氧化相应的烯烃制得。

Gerbera plantlets in 125 ml flask received 0, 2.5, 5, 10, 20 ppm Ethrel and 0.01, 0.1, 1 mM 1-aminocyclopropane-1-carboxylic acid to study the effect of ethylene and ethylene biosynthesis through cultured in vitro. The good quality plantlets which had more adventitious roots, no overgown stem, no etiolated plantlets by the addition of 5, 10 ppm Ethrel.

非洲菊(Gerbera jamesonii, Bolus)幼苗於试管内处理以0, 2.5, 10, 20 ppm的益收素及0.01, 0.1, 1 mM的环丙烷氨基羧酸(1-aminocyclopropane-1-carboxylic acid, ACC)以研究乙烯对试管苗之影响及乙烯生合成,结果以5及10 ppm的益收素处理能得到良好品质的苗,为多侧根不徒长,不白化的幼苗。

The first step in the degradation is most probably the classical ester scission reaction to give a carboxylic acid and olefinic end groups. Further ester scission on the adjacent ester groups of carboxylic acid and olefinic molecular chains can then lead to the formation of lower weight pyrolytic products, such as: CH〓=CHOCOPhCOOCH=CH〓、CH〓=CHOCOPhCOOH and HOOCPhCOOH, and they can pyrolyze continually to produce substrate pyrolytic compounds, such as: HOOCPhCOCH〓、PhCOOH、PhH、PhCOCH〓 and CO、CO〓. At the same time, a corsslinking cyclization reaction occurred of the formation of the gas products during the degradation of PET.

断裂大分子链端邻近羰基和乙烯基的酯键持续断裂,不断地形成小分子裂解产物,如:CH〓=CHOCOPhCOOCH=CH〓、CH〓=CHOCOPhCOOH以及HOOCPhCOOH,这些产物还会进一步裂解成分子量更低的小分子裂解产物,如:HOOCPhCOCH〓、PhCOOH、PhH、PhCOCH〓以及CO、CO〓等,与此同时,一部分乙烯基酯端基的大分子链碎片会发生支化而相互连接,再经&链脱离&和环化反应形成难燃的交联产物。

Waste oil category: Waste oil, waste hydraulic oil, waste oil, waste oil injection, waste kerosene, waste of white mineral oil, white waste oil, waste oil sparks, the repeal of toluene, waste cutting oil, gear oil, lubricants, batteries oil, spindle oil, zorra, oil, turpentine oil, solvent oil, gear oil, oil rails; waste chemical categories: one, the repeal of toluene, xylene waste, spent 2 pure benzene, acetone waste, waste Ding ketone, cyclohexanone 3 waste, waste dichloromethane, dichloroethane waste, waste Dichloropropane 4, solvent categories: soluble oil 6 #, 120 # dissolving agents, dissolving agents 200 # 5, trichloro ethylene, dichloromethane, trichloroethane; tetrachlorethylene, trichloromethane 6, the repeal of methanol, ethanol, waste, waste alcohol, isopropyl alcohol waste 7, the repeal of ethylene glycol, diethylene glycol waste, spent three 8 glycol, waste butyl acetate, ethyl acetate wastewater, waste acetate 9, the repeal of ethyl ether, acetonitrile waste, waste petroleum ether 10, cleaning categories: cleaning agent, washing machine water, days that water; wash board water,×oil wastewater liquid 11, the supply of tires category: special supply of fuel oil, non-standard oil, burner oil, waste oil and other refined crude oil.

废油类:废机油,废液压油,废柴油,废注塑机油,废煤油,废白矿油,废白电油,废火花机油,废甲苯,废切削油,齿轮油,润滑油,废电池机油,锭子油,索拉油,松节油,溶剂油,齿轮油,导轨油等;废化工类:1、废甲苯、废二甲苯、废纯苯2、废丙酮、废丁酮、废环已酮3、废二氯甲烷、废二氯乙烷、废二氯丙烷4、溶剂类: 6#溶油剂, 120#溶油剂, 200#溶油剂5、三氯乙烯,二氯甲烷,三氯乙烷;四氯乙烯,三氯甲烷6、废甲醇、废乙醇、废丁醇、废异丙醇7、废乙二醇、废二甘醇、废三甘醇8、废醋酸丁酯、废醋酸乙酯、废醋酸甲酯9、废乙醚、废乙腈、废石油醚10、清洗类:清洗剂,洗机水,天那水;洗板水,去渍油等废液废水11、废轮胎类供应:特价供应燃料油,非标油,烧火油,废油提练的原油等。

The synthetic route is concise and convenient. In chapter four, a serial of dithienylethene derivatives containing substituted triphenylamine groups was synthesized with a concise route.

第四章通过Suzuki反应,制备了在噻吩环的5-位上有单三苯胺取代的二噻吩乙烯,和5-,5'-位双三苯胺取代二噻吩乙烯光致变色化合物。

Japanese Komatsu, Hitachi, Kato, Sumitomo, Carter, the United States and South Korea's Hyundai, Daewoo, Samsung, various kinds of imported excavator seal the fuel tank, the center seal, crankshaft oil seals before and after, and services for major projects in the fuel tank of the domestic plants, for provide users with a variety of piston oil seal (SPGO, SPGW, SPG portfolio, such as seals), piston rod seal (SPNO, IDI, HBY, etc.), a variety of materials to support Central (A phenolic cloth, filled PTFE composites, POM, etc.), V-type combination of seals, all kinds of O-ring, PTFE block films, a variety of automotive oil seals.

提供日本小松、日立、加藤、住友、美国卡特及韩国现代、大宇、三星、各种进口挖掘机油缸密封件、中心油封、曲轴前后油封,并服务于国内各大工程油缸厂,为用户提供各种活塞油封(SPGO、SPGW、SPG等组合密封)、活塞杆密封(SPNO、IDI、HBY等)、各种材料支撑环(酚醛甲布、填充复合聚四氟乙烯、聚甲醛等),V型组合密封圈,各种O型圈、聚四氟乙烯挡片、各种汽车用油封。

In this dissertation, preparation of polysubstituted ethene and heterocyclic compounds based on 2-hydroxyalkyl phenyl selenides andα-phenylselenopropionic acid reagents were further investigated as follow: Firstly, O-ethyl-O-vinyl phosphonates were prepared in a one-pot, two-step transformation by Mitsunobu reaction of 2-hydroxyalkyl phenyl selenides with monoethyl esters of phosphonic acid in the presence of diethyl azodicarboxylate and triphenyl phosphine (PPh3) followed by oxidation-eliminatio...

中文摘要:本文主要进一步探索了2-羟基烷基苯基硒醚、α-苯硒基丙酸试剂在制备多取代乙烯和杂环化合物反应中的应用,具体研究内容和结果如下:一、在偶氮二羧酸乙酯和三苯膦(PPh3)存在下,苯基-2-羟基烷基硒醚和O-乙基膦酸单酯发生Mitsunobu反应,无需分离和纯化反应中间体,直接使用30 %的双氧水进行氧化-消除反应,提供了&两步、一锅&合成O-乙基-O-乙烯基膦酸酯的新方法,该方法反应条件温和,操作简便,产物收率良好(76-82 %)。

Tris-(1-aziridinyl)- phosphine oxide and 2-[bis-(2-chloroethyl)-amino]-tetrahydro-1, 3, 2-oxazaphospholidine-2-oxide(Ⅲ, B-518) possess inhibitory action against a variety of animal tumours and have been used clinically. Recently, bis-(1-aziridinyl)-phosphinyl carbamic acid ethyl ester(Ⅱ, AB-100) was found to possess significant activity with low toxicity on experimental animal tumours.

双(2-氯乙基)氨基磷酰二氯与乙烯亚胺在脱水苯或对氧六环中并在三乙胺的存在下进行缩合,生成N,N-双(2-氯乙基)-N′,N-二乙烯基-磷酰胺;与双巯基或双氨基化合物作用,则生成相应的环状磷酰胺、磷酰胺酯以及磷酰胺硫代酯氮芥类化合物。

The main products are SF-1 (as the base plate of the middle sintering Copper Balls powder, surface modified PTFE); SF-2 (plate as the base of the middle sintering Copper Balls powder, surface modified POM); JDB (For brass, bronze, iron-based body, inlaid solid lubricant); dual-metal (steel as the base for the various models of the surface of copper); production of various enterprises have also filled with PTFE, the curve of bearings, bearing powder metallurgy, by Chun-for the Pistons, Piston Ring, ethylene tetrafluoroethylene ring, ring.

主要产品有SF-1(钢板为基体中间烧结铜球粉,表面为改性聚四氟乙烯);SF-2(钢板为基体中间烧结铜球粉,表面为改性聚甲醛);JDB(为黄铜、锡青铜、铸铁为基体,镶嵌固体润滑剂);双金属(钢板为基体表面为各种型号铜);企业还生产各种填充四氟带、曲线轴承、粉末冶金轴承、减震器活塞、活塞环、四氟乙烯密封圈、环。

Objective] The research aimed to improve the comprehensive surface performance of lauryl polyoxyethylene ether (AEO3) by means of modification.[Method] AEO3 was synthesized from lauryl alcohol and epoxy ethane, which reacted with liquid chloroacetic acid to produce modified AEC.

[目的]对月桂醇聚氧乙烯醚(AEO3)进行改性来提高它的综合表面性能[方法]用月桂醇、环氧乙烷合成月桂醇聚氧乙烯醚(AEO3),再用AEO3与液体氯乙酸反应改性合成AEC。

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