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Both catalytic activity and selectivity of Ru(PPh_3)_3Cl_2 were improved in ionic liquid BMImPF_6/DME medium.The conversion of hexene and selectivity ofβ-adduct for the hydrosilylation reaction of 1-hexene with triethoxysilane catalyzed by Ru(PPh_3)_3Cl_2 in ionic liquid BMImPF_6DME (V/V=1/4) medium at 90℃were 100% and 89.0%,respectively.

实验结果表明,在乙二醇二甲醚/离子液体1-丁基-3-甲基咪唑六氟磷酸盐(BMImBF_6)(V/V =1/4)介质中,于90℃下,己烯与三乙氧基硅烷反应的转化率为100%,β加成物的选择性可达89.0%,而用Rh(PPh_3)_3Cl作为反应的催化剂,在纯离子液体BMImPF_6中,就可以高效催化烯烃与三乙氧基氢硅烷的加成反应,过渡金属Rh(PPh_3)_3Cl,Ru(PPh_3)_3Cl_2催化剂/离子液体BMImPF_6催化体系,不仅解决了产物与催化剂分离困难这一难题,同时,离子液体BMImPF_6的存在提高了过渡金属Rh(PPh_3)_3Cl,Ru(PPh_3)_3Cl_2催化硅氢加成反应的活性,特别是β加成物的选择性。

The correlation between liquid fragility of alloys and micro/maro -properties in liquids or their corresponding solids, as well as the correlation between liquid fragility and potential energy landscape, is of great significance for understanding the nature of liquid fragility and the relationship between thermodynamics and dynamics,.

研究金属液体的脆性性质与液体中微观或固体中宏观性质的联系以及研究其液体的脆性与能量图谱的联系,对于揭示液体脆性的本质、热力学与动力学性质相关性问题以及能量图谱的量化工作具有深远的意义。

Considerable attention has really been focused on ionic liquids as "green" alternatives to classical environmentally damaging organic solvents in many fields such as in organosynthesis, material, catalysis, electrochemistry, biochemistry, physicochemistry, separation and so on. However, there have been only a few examples of chiral ILs have been reported so far, and ILs possessing chirality are having been synthesized aimed at application in asymmetric catalytic reaction.

离子液体在许多领域如电化学、有机合成、催化、生物化学、物理化学、材料及分离等的绿色替代溶剂技术引起了人们的重视,然而,有关手性离子液体的合成与应用的报道比较少,含有手性片段的离子液体不断被合成出来并期望在不对称催化反应中得到应用,但是成功的例子不多,使用手性离子液体在不对称催化反应中还在初始的探索阶段。

Three kinds of ionic liquid were used to support the acetylacetone at the C3 position directly according to the method indicated above. These synthesized ionic liquid supported acetylacetone catalysts include imidazolium salts ionic liquid supported acetylacetone catalysts, pyridinium salts ionic liquid supported acetylacetone catalysts and ammonium salts ionic liquid supported acetylacetone catalysts. All these catalysts were characterized by ~1H-NMR,~(13)C-NMR, IR and elementary analysis.

采用设计过程中预期能够提高乙酰丙酮金属催化剂催化氧化活性的修饰方式,合成了三类离子液体支载的乙酰丙酮金属催化剂:咪唑型离子液体支载乙酰丙酮金属催化剂、吡啶型离子液体支载乙酰丙酮金属催化剂、胺型离子液体支载乙酰丙酮金属催化剂,并采用核磁共振氢谱、碳谱,红外光谱及元素分析来对这些新型的催化剂进行了表征。

When pump starts, the lower impeller lifts the solution up step by step. And the extreme centrifugal force from the enlarged higher impeller stops the solution as it entering the higher impellr. At the same time, the full solution in the chamber stops the air mixed with the solution in the chamber to go down. This way masterly eliminates both big problems of vertical sealless pump, overflow at high pressure and bubbles at big flow.

塑宝SV泵剖面结构SV Super Series Analytical cross section SV泵剖面结构泵开始运转时,底部叶轮将液体逐步上推,待液体进入上部叶轮时,即受加大之背叶的强大阻力而无法上升,但上部叶轮所卷入液体中的空气,却受阻於水室中贮满的液体而无法下降,如此巧妙地排除了立式无轴封泵高压时溢流,或大流量时吸入空气的两大难题。

The methods for acetic acid bacteria preservation,including slant pre servation,liquid wax preservation and liquid preservation,were compared with t he modified slant-suspension preservation experiments on preservation duration and acid yield were also studied in this paper.

对醋酸菌保藏的斜面保藏法、液体石蜡保藏法、液体保藏法和经过改进的斜面液体保藏法进行了比较,并进行了保藏期限和产酸能力的实验,结果表明:斜面液体保藏法保藏的菌种保藏期限可达2年,产酸能力优于其它3种方法。

A conclusion has been drawn through analyses of the evaporation inner tank liquid, which is the evaporation of liquid occurred at and near surface during storage and boil-off gas and up liquid gets equilibrium during storage.

分析了LNG储存过程中罐内液体蒸发,经过分析得出储存过程中液体的蒸发发生在液体表面及其附近,而蒸发气相空间可认为与上层液体近似地达到了气—液两相平衡。

vanced a new approach to measure the coefficient of viscosity with the method of falling balls , and explained the movements of falling balls of the same diamters in viscose fluid in tubes of different diameters and falling bahs of different diameters in viscose fluid, as well as the whole process of movements of falling balls in viscose fluid.

文摘:给出了一种落球法测液体粘滞系数的改进方法;并对小球在不同管径内的粘滞液体中的下落运动、不同直径的小球在粘滞液体中的下落运动以及小球在粘滞液体中的整体运动过程等进行研究。

Such formulas could not only be used to calculate the volume or weight of the remaining liquid based on its height, but also be used to draw height staff gauge to illustrate the volume or weight of the remaining liquid in the petrochemical container.

介绍了石油化工容器内存留液体体积与液位高度函数关系的 1 6个基本公式,可以根据存留液体的液位高度计算出容器内液体的体积或质量,也可以用于绘制表示容器内存留液体体积或质量的高度标

A cappuccino as such differs from a caffè latte in that it is prepared with much less steamed or textured milk than the caffè latte, with the total of espresso and milk/foam making up between approximately 150 ml (5 imp fl oz; 5 US fl oz) and 180 ml (6 imp fl oz; 6 US fl oz).

阿卡布奇诺等有别於拿铁咖啡因为它是少得多准备蒸,材质比牛奶拿铁咖啡,总的咖啡和牛奶/泡沫占大约是150毫升(5进出口液体盎司;美国液体盎司5)和180毫升(6进出口液体盎司; 6美国液体盎司)。

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Results showed that 0.01g/mL extract of Oxalis corniculata L. had obvious antimicrobial effect on S. aureus, but all extract of Oxalis corniculata L has not any antimicrobial effect on E.

结果表明,0.01g/ml的提取物对摇床培养的金黄色葡萄球菌生长具有明显的抑制作用;但各种浓度的提取物对摇床培养的大肠杆菌生长均无抑制作用。

This will be totally different from Zaro's texture mod, it will be desaturated, dirty etc.

这会和Zaro的那个材质补丁有很大不同,这边是更多的不饱和色,整个都灰扑扑的。

This will be a major step forward for our country's aerospace technology.

这将是国家航空科技的一个重大的进步。