形成

In this thesis, a series of complexes based on aromatic multicarboxylic acids have been successfully synthesized in solutions or under hydrothermal conditions. Their structure and properties are investigated.(1) Eight complex compounds have been synthesized and characterized by X-ray single crystal diffractive technology: The eight complexes are listed as following: [Cu242] complex 1 [Cd22(H2O)4]·4H2O complex 2 [Co(H2btc)(H2O)3] complex 3 [Co2(H2O)2]·H2O complex 4 [Ni22(H2O)4] complex 5 [Cu22(H2O)4] complex 6 [Co(H2biim)2(H2O)2](H2btc) complex 7 [Zn(H2biim)2(H2O)2](H2btc) complex 8 The structure of complex 1 is dinuclear complex resulted from weak interactions（0-D chain）; complex 2 is 1-D chain stucture result from interactions of water molecules; complex 3、4、5、6 are coordination polymers using hydrothermal synthses, where the first kind ligand is H4btc, the second kind ligand is phen and Co2+、Ni2+、Cu2+ as center ions, respectively. While the coordination enviroment of Co2+ is the same in complex 3, the coordination geometries around the Co atoms in complex 4 are obviously different because of the different reaction conditions. In complex 4, the 1-D chains are connected into 2-D layer through carboxy groups of ligand H4btc. The structures of complex 5、6 are 1-D chain stucture result from interactions of carboxy groups in ligand H4btc. Complex 7、8 are homeomorphy compounds. Either of them are linked to the 3-D chains through intermolecular hydrogen bonds. Each H4btc lose two protons and H2btc2- acts as negative electron balance.

合成了8个结构新颖的配合物，并用X-射线单晶结构分析方法确定了晶体结构，分别为： [Cu242] 配合物1 [Cd22(H2O)4]·4H2O 配合物2 [Co(H2btc)(H2O)3] 配合物3 [Co2(H2O)2]·H2O 配合物4 [Ni22(H2O)4] 配合物5 [Cu22(H2O)4] 配合物6 [Co(H2biim)2(H2O)2](H2btc)配合物7 [Zn(H2biim)2(H2O)2](H2btc)配合物8 配合物1是一个依靠弱作用连接的双核铜结构；配合物2借助水分子形成一维链状结构；配合物3、4、5、6是以H4btc为第一配体、phen为第二配体，通过水热法合成的配合物，其中，Co2+、Ni2+、Cu2+为中心离子；配合物3中的二价钴离子具有相同的配位环境，不同反应条件下得到的配合物4中的二价钴离子存在不同的配位环境，在配合物4中，一维链通过H4btc上的羧基形成一个二维层结构；配合物5、6是借助H4btc上的羧基形成的一维链状结构；配合物7、8属于异质同晶结构，它们的分子通过分子间氢键形成三维网状结构，H4btc上的羧基失去2个质子，作为一个二价负离子起到电荷平衡作用。

Histological examination demonstrated bone formed in accordance with intramembranous ossification in distraction zone and bony connection between the transport disc and mesial mandible on right side; On the left side, there was a big defect at the area of both distraction and defect zone because of dislocated bone transport disc, and no obvious new bone regeneration was found.

组织学检查：见9周后右侧牵张区形成新生骨质，符合膜内成骨，传送盘与近中牵张区形成骨性连接；左侧由于骨传松盘离开缺损区，牵张区与缺损区形成一较大的凹陷，未见明显新骨形成。

Lall indicated that developing countries enterprises can pose theyself special advantage and then become MNEs through making self-determination technological innovation according to local condition.

上述理论对发展中国家跨国企业的形成条件、优势特点和发展过程的分析，均没有联系发展中国家经济发展背景和发展过程的特点，忽视了管理能力积累和创新所形成的特有优势对跨国企业形成的重要性，因此不能对发展中国家跨国企业形成的超前性作出解释。

Results One case with transverse mesocolon pore hernia, one with obturator hernia and one with paracecal hernia were confirmed by exploratory laparotomy. There were six cases whose hernias resulted from the fall of export jejuna into import jejuna after Billroth II anastomoses in front of colons, five from the pelvic bottoms' peritoneal fissure and four from the fissure appearing between descending colon and lateral abdominal wall after Miles' operation, one from greater omental adhesion to sigmoidal wall after sigmoidostomy, and one from inflammatory adhesion on the basis of Meckel's diverticulum. The other 17 cases' hernias (48.7%) were caused by the fissure among celiac adhesive bands, peritonea, celiac organs, enteric walls and intestines.

结果 剖腹探查手术证实为横结肠系膜裂孔疝1例；闭孔疝1例；盲肠旁疝1例；毕Ⅱ式结肠前吻合术后输出段空肠疝入输入段空肠与横结肠系膜间隙6例；Miles术后盆底腹膜裂开所致内疝5例；Miles术后降结肠与侧腹壁形成的间隙致内疝4例；大网膜与乙状结肠造口肠壁粘连形成内疝1 例；1例在梅克尔憩室基础上发生炎性粘连形成腹内疝；因腹腔粘连带与腹膜、腹腔脏器、肠壁、肠与肠之间的孔隙改变形成内疝17例（48.7%）。

Skin keratinocytes and epithelial cells from hair follicle organized into epidermoid cyst-like spheroids when cultured on nubby dermal papilla cells gel and epidermoid layer-like structure was formed when they were cultured on free dermal papilla cells and skin fibroblasts gel.

团块状的毛乳头细胞诱导毛囊上皮细胞和皮肤角质形成细胞形成球形结构；而游离分散的毛乳头细胞和皮肤成纤维细胞诱导毛囊上皮细胞和皮肤角质形成细胞形成表皮样层化结构。

The analyses of the meterological and oceanographical data from seriel observations aboard R/V Xiangyanghong 5 during the voyage of joint AMEX experiment by Australia,China and the United States show that (1) there is high level of humidity within middle and low layers of troposphere at the initial stage of a typhoon's formation,and once a typhoon has fully developed,the highest level of humidity remains within middle layer of tropisphere;(2) although small vertical wind shear is a requisition for a t...

对中、美、澳三国AMEX试验期间&向阳红5号&定点观测到的气象和海洋资料分析得出：①台风形成前，大气整个中、低层空气湿度较大，台风一旦形成，大气湿度最大层主要集中在中空；②风速垂直切变小，对形成台风是一个必要条件，但并非整个对流层风速切变都小，而且不同地区形成的台风，风速切变状况是不同的；③厄尔尼诺年南半球与北半球对应位置同期的θ_G、θ_8、Q_b相差不大，但是南半球的θ_c较北半球的大。

Scanning electron microscopy,transmission electron microscopy,circular dichroism and small-angle X-ray diffraction were used to analyze the aggregation mode of CSG in the organogel phase.A hierarchical self-assembly model was proposed to explain the transition from molecular to primary and secondary structure.It is shown from our results that CSG can aggregate into a micellar fibril nanostructure with high length-to-width ratio which is bundled and entangled to form a three-dimensional(3D) network that immobilize the fluid component probably by surface tension.Moreover,sol-gel polymerization of tetraethoxysilane was carried out using CSG in the gel phase.

通过扫描电镜(ScanningElectron Microscopy，SEM)、透射电镜(Transmission Electron Microscopy，TEM)、圆二色谱(Circular Dichroism，CD)和小角X—射线衍射仪(Small-angle X-rayDiffraction，SAXRD)考察CSG分子自组装行为结果表明，CSG形成的聚集体具有多级结构：首先CSG通过手性堆叠自组装形成直径在9—10nm的细纳米纤维，这些细的纳米纤维再以不规则的六方堆积的方式进行排列，构成直径在40—100nm的粗纳米纤维(即细纳米纤维的&捆束&)，最后粗纳米纤维互相粘连形成三维网络状结构，使有机溶剂&固定&，从而形成凝胶；以CSG有机凝胶为模板，四乙氧基硅烷为前体，通过溶胶—凝胶聚合的方法制备了直径大约为100nm的二氧化硅纳米管。3。

The method includes the steps of forming a peelable resin layer on a silicon substrate, forming the wiring substrate on the peelable resin layer, mounting semiconductor chips on the wiring substrate, forming semiconductor devices by sealing the plurality of semiconductor chips by a sealing resin, individualizing the semiconductor devices by dicing the semiconductor devices from the sealing resin side but leaving the silicon substrate, peeling each of the individualized semiconductor devices from the silicon substrate between the silicon substrate and the peelable resin layer, and exposing terminals on the wiring substrate by forming openings through the peelable resin layer or by removing the peelable resin layer.

该方法包括以下步骤：在硅衬底上形成可剥离树脂层；在所述可剥离树脂层上形成布线衬底；将半导体芯片安装在所述布线衬底上；通过用密封树脂密封所述多个半导体芯片来形成半导体器件；通过从密封树脂侧将这些半导体器件切分但是保留硅衬底来使这些半导体器件个体化；将每个个体化半导体器件在所述硅衬底和可剥离树脂层之间从硅衬底上剥离；并且通过形成穿过可剥离树脂层的孔或者通过除去可剥离树脂层来使布线衬底上的端子暴露。

The reseach on activity changes of SOD, POD and CAT during the somatic embryogenesis of Y35 showed:(1) The activty of SOD was from 52.98 to 133.20 U·g-1·h-1, and remained a rising trend after early single embryo forming, this revealed that SOD might be positively correlated to the differentiation of embryogenic cell and the development of somatic embryo.(2) The activty of POD was from 0.05 to 0.50 U·mg-1·min-1, ascended firstly and desceded later, and was highest in embryogenic callus and lowest in late single embryo , this revealed that POD might be positively correlated to the division and differentiation of proembryo mass, while negatively correlated to the development of PEMⅢto late single embryo.(3) The activty of CAT was from 0.86 to 2.81 U·mg-1·min-1, showed an up-down-up trend, reaching to the highest peak at the time of early embryo formating and decreasing to the lowest at the time of early cotyledonary embryo formating, this revealed that CAT might be positively correlated to the development of early single embryo, while negatively correlated to the formation of middle single embryo and early cotyledonary embryo.The changes in activty of SOD, POD and CAT indicated these three antioxidant enzymes coregulated the differentiation and development of embryogenic cells during Larix somatic embryogenesis.4. Differentially expressed cDNA libraries of the stages of proembryo mass and somatic embryo maturation were successfully constructed by suppression subtractive hybridization.

对Y35体细胞胚胎发生过程中抗氧化酶活性变化的研究显示：(1)SOD活性在52.98~133.20 U·g-1·h-1之间，并在早期单胚形成后一直保持上升的趋势，表明其与胚性细胞的分化及体细胞胚的发育均具呈正相关；(2)POD活性在0.05~0.50 U·mg-1·min-1之间，呈现出先下降后升高的趋势，在胚性愈伤组织中最高，而在后期单胚形成时降至最低，表明其与原胚团的分裂和分化呈正相关，但与PEMⅢ向后期单胚的发育呈负相关；(3)CAT活性在0.86~2.81 U·mg-1·min-1之间，表现出升-降-升的变化趋势，在早期单胚形成时升至最高，在早期子叶胚形成时降至最低，表明其与早期单胚的发育呈正相关，而与中期单胚和早期子叶胚的发育呈负相关。

The study of the forming condition and mechanism of immature oil in eastern Linqing depression reveals that brackish water-brine, abundant sulfur bacteria and sulfocompounds provided favorable conch-lions for the formation of the immature oil. Immature oil was the result of hydrogen-rich sapropel of lower activation energy degraded by sulfur bacteria. T and R of the early hydrocarbon generation of organic matter were 400~435℃ and 0.2%~0.5% respectively, and their values for peak hydrocarbon generaion are 420℃ and 0.35%.

通过对渤海湾盆地临清坳陷东部未熟－低熟油的形成条件及形成机制探讨，总结出沙一段和沙三段的微咸水－咸水介质环境、丰富硫细菌和含硫化合物为临清坳陷东部未熟－低熟油气形成提供了有利条件，证实该区未熟－低熟油气形成是低活化能的富氢腐泥组分受到硫细菌早期低温降解作用的结果，明确该区未熟－低熟烃源岩硫细菌降解的有机质早期生烃阶段的T值为400~435℃，R值为0.2%~0.5%，生油高峰T值为420℃，R值为0.35%左右。

Since historical times,England ,where the early inhabitants were Celts, has been conquered three times .

从有历史以来，英国，在此地早期居住的是凯尔特人，已经被征服了三次。

Bluetooth OBEX File Transfer Enables the sending and receiving of files on your phone via Bluetooth.

蓝牙OBEX文件移动允许经过蓝牙传送和接受文件。。。。