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This dissertation involves the study of the growth dynamics of colloidal particles under unequilibrium and irreversibility condition. Firstly, it is of interest to investigate whether the ideal diffusion or reaction-limited aggregation universal behavior can be observed for the initially polydisperse practical system of basic yttrium carbonate as well. The fractal structure of basic yttrium carbonate aggregate cluster was observed using transmission eletron microscopy. The aggregation kinetics of basic yttrium carbonate colloids was studed using dynamic 1ight-scattering techniques. At 1.00mol/l NaCl solution the fast diffusion-limited aggregation behavior was observed with an increase in the aggregate size over time described by a power law. The aggregates are characterized by a fractal dimension D=1.82. The disordered and ramified cluster is consisted of primary colloidal particles and tenuous and more open. These are in good agreement with those observed for other colloidal system such as colloidal gold (1.86), silica (1.85) and polystyrene latex (1.82) in diffusion-limited aggregation from the static and dynamic light scattering by Lin. Therefore ideal diffusion-limited aggregation behavior can be observed in practical polydisperse system as well. Smoluchwski and fractal theories were used to obtain the aggregation rate constant for initially polydisperse system for the first time.

本论文研究胶粒的非平衡不可逆聚集动态学,分为两个部分,第一部分是通过实验研究一个新的初始多分散的碱式碳酸钇胶粒实际体系中,聚集标度性质的普适性,即使用透射电子显微技术观测聚集粒子簇的分形结构,使用动态激光光散射研究碱式碳酸钇胶粒的聚集动力学,胶粒带电而产生静电排斥作用使得碱式碳酸钇胶粒处于稳定状态,当加入电解质NaCl溶液时,碱式碳酸钇胶粒间的Debye-Hückel屏蔽距离缩短,从而降低静电排斥能垒,引起胶粒发生不可逆聚集,加入电解质NaCl的浓度为1.00mol/l时,碱式碳酸钇胶粒进行快速聚集,经历扩散控制聚集机理,形成结构疏松、更为开放的分形聚集粒子簇,其分形维数为1.82,碱式碳酸钇胶粒聚集增长动力学遵循幂函数增长规律,与Lin等使用静态激光光散射和动态激光光散射测量硅胶(1.85)、金胶(1.86)和聚苯乙烯胶乳(1.82)在扩散控制聚集状态形成聚集粒子簇的分形维数值以及粒子簇聚集增长的动力学规律相一致,表明胶粒聚集标度性质的普适性质在初始多分散的实际体系中也是存在的,首次由动态激光光散射的实验数据得到初始多分散胶粒分形粒子簇的聚集速率常数,并且其值与Smoluchowski聚集速率理论预期相符。

There are exponential functions between the reaction rate constants and electrode potential, NaCl concentration respectively, while the rate constant and initial dye concentration are related with the reciprocal function. Furthermore, the decoloration rate was reduced obviously by high temperature.

脱色反应符合一级动力学,反应速率常数分别与阳极电位、氯化钠浓度存在指数函数关系,与染料初始浓度存在倒数函数关系;高温明显降低脱色降解反应速率。

A novel finite-difference time-domainmethod,called shift operator FDTDmethod is developed for anisotropic magnetized dispersive media.The recursive relation between operators is used.In this paper,some expressions containing the dielectric constants of magnetized dispersive media are written as rational polynomial function.

给出了一种新的计算各向异性磁化色散介质的有限差分算法,称为移位算子FDTD算法,它利用算子之间的移位递推关系,将一类色散介质的包含介电常数的表达式写成有理分式函数形式,进而导出FDTD中一系列相关量之间的关系。

By the use of the obtained relationship between reflectively and frequency, the effects of thickness, material coefficients and viscoelastic damping of outer shell on the scattering characteristics of the structure were calculated and analyzed.

利用已得到的散射率函数,计算并分析了外层壳的厚度、材料常数、粘性阻尼等对双层球壳散射特徵的影响。

First, it is compared with the usual formal theory of scattering, for example, that developed by Moeller.

第一,我们将它与寻常的散射形式理论作一比较,证明了二个理论的波函数除去一个常数倍外,完全相同。

For the parameters of physical interest, the self-consistency also diminishes the continuum part of the spectral functions.

对于π-ω模型,自洽效应对耦合常数有很大的依赖性,随着〓的减小自洽后的重子谱函数先增大后减小。

Moreover, it gives a condition of self-induced velocity with stability for helical vortex with arbitrary vorticity distributing.

首次提出了对于具有任意涡分布的螺旋涡管,其自诱导速度等于常数时,涡分布函数必须满足的条件。

In this paper,for some Orlicz sequence space we obtain the representation of nonsquare constants by N-function.

本文对某类具体的Orlicz 空间用N-函数对非方常数给出表示和估计。

The stability of system equilibrium point and the existence condition of 3-D Hopf bifurcation as well as the stability of hence generated periodic solution were analyzed, so that the existence of limit cycles on the two-dimensional stable manifold of one microbial species and its nutrition was verified when other one had the disadvantage in the competition so as to become extinct.

研究当营养消耗率δ1=δ1为一般的非减连续函数和δ2=常数的三维Chemostat模型,分析系统平衡点的稳定性,三维系统经历Hopf分支的条件和由此产生的周期解的德定性,证明系统中某一微生物物种处于竞争劣势而趋于灭绝时另一微生物物种和营养的二维稳定流形上极限环的存在性。

The stability of system equilibrium point and the existence condition of 3-D Hopf bifurcation as well as the stability of hence generated periodic solution were analyzed,so that the existence of limit cycles on the two-dimensional stable manifold of one microbial species and its nutrition was verified when other one had the disadvantage in the competiti.

研究当营养消耗率1δ=1δ为一般的非减连续函数和2δ=常数的三维Chemostat模型,分析系统平衡点的稳定性,三维系统经历Hopf分支的条件和由此产生的周期解的稳定性,证明系统中某一微生物物种处于竞争劣势而趋于灭绝时另一微生物物种和营养的二维稳定流形上极限环的存在性。

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