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响应曲线

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Experiments were carried out to verify the static model. Experimental results show that the experimental curve matched well with the simulated curve, and there was certain error between them (maximal static error is 0.035 rad). The error cause was analyzed. Then the experiments were carried out to measure the dynamic performances of the side-sway joint. Experimental results show that the step response time of the joint was about 2 s steady value's tolerance zone ?

完成了侧摆关节静态特性试验,试验结果与仿真曲线基本吻合,验证了静态模型的正确性,但存在一定误差(最大静态误差为0.035 rad),分析了误差原因;对侧摆关节进行了动态特性试验,试验结果表明对于不同的期望值角度阶跃信号,侧摆关节开环阶跃响应时间大约是2 s

The time-history velocity response signal of pile can be decomposed by Sym wavelet. The power spectrum value can be extracted from some specified spectrum range. These values from one signal makes up the characteristic vector representing this signal. The relationship between characteristic vector of pile and pile defect type can he established by using BP artificial neural network. Abundant time-history velocity response signals of pile can be acquired by numerical simulation method.

利用Sym小波对基桩速度响应时程曲线进行小波分解,对指定频带上的信号分量进行特征值提取,提取的特征值为反映各频带范围内体现能量分布的功率谱均值,提取的特征值可构成反映信号特征的特征向量,同时利用BP人工神经网络的非线性映射特性建立特征向量和基桩缺陷类别之间的一种对应关系。

The main research work of this dissertation is as follows: Based on the chemical reaction engineering theory and the nitrobenzene electroreduction mechanism, the plate and frame electrolyzer was designed and applied to the process of electroreduction nitrobenzene to p-aminophenol. This dissertation measured the residence time distribution data of the electrolyzer by means of the pulse response method and studied the rule of flow pattern along with the current capacity change. Under different conditions ,this dissertation studied the cyclic voltammetry properties of nitrobenzene on different electrodes by means of the dynamic cyclic voltammetry method and the electrode materials applied to the NB electroreduction have been selected primarily.Baseed on the results of cyclic voltammetry tests, this dissertation used p-electrode systems to measure the steady-state- polarization curves of nitrobenzene on different electrodes in H-type diaphragm cell, and obtained each primary factor s influence rule and the exchange current density value of each electrode.And then on the basis of the conclusions of fundamental researchs upword, the effects of influence factors on the the yield of p-aminophenol and the current efficiency,such as electrode material, current density, quantity of electricity circulated, nitrobenzene concentration . sulpuric acid concentration and so on, have been studied in detail in the systems of hign temperature , strong acidity and oxygen-poorthrough a series of electrolysis experiments in this paper.After all using Pb as anode Monel metal as cathode Dupont Nafion 417 cation-exchange membrane as membrane, this dissertation obtained the optimum technological condition: reaction temperature about 85C, current density 500A m-2, sulphuric acid concentration 20%wt.

论文的主要研究工作为:运用化学反应工程理论,结合硝基苯的电还原机理,设计出用于硝基苯直接电还原合成对氨基苯酚实验的板框式电解槽,并利用脉冲响应法测定了该板框式电解槽的停留时间分布数据,研究了流型随流量变化的规律;通过动态循环伏安法研究了硝基苯在不同电极上、不同条件下的循环伏安特性,初步评选出了用于硝基苯电还原的电极材料;结合循环伏安的测定结果,在H型隔膜电解槽中采用三电极体系测定了硝基苯在不同电极上、不同条件下的稳态极化曲线,得到了各主要因素的影响规律及硝基苯在各个电极上电还原的交换电流密度数值;在基础研究结论指导下,采用板框式电解槽,在高温、强酸、贫氧系统中,进行了一系列的电解实验,分别考察了电极材料、电流密度、通电量、硝基苯浓度、硫酸浓度等因素对收率及电流效率的影响,最终选择以蒙乃尔合金电极作为阴极、铅合金为阳极、Dupont Nofion 417阳离子交换膜为隔膜,得到由硝基苯直接电还原制对氨基苯酚的最佳电解工艺条件:反应温度85℃,电流密度500A·m~(-2),硫酸浓度20%wt。

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