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The application results from fluorination showed microwave heating could accelerate chemical reactions markedly. The reaction time could be shortened 50% at least than that of conventional heating. The relationship between fluorinating agents\' structure and their activity was studied systematically. In addition, an anhydrous KF with higher activity was prepared by using expansion effect of microwave heating. As we known, solvents were very important to reaction. The comprehensive study showed some less polar aromatic solvents could be used as dipolar solvents. In addition, they had better effect than dipolar solvents in some occasions, such as fluorination of chlorobenzaldehydes and chlorinated diphenyl ketones etc. The primary applications of ionic liquids were also studied which indicated reactions with ionic liquids as solvents were more efficient and simple.

研究表明,微波是一种节能高效的加热方式,在微波作用下的卤素交换氟化反应具有反应速度快、转化率高、选择性好的优点,其反应时间可较常规加热缩短50%以上;同时也系统地研究了氟化剂种类及制备方式对其反应活性的影响,并利用微波加热的膨化作用制备出了一种活性较高的KF,其活性与喷雾干燥KF相差不大;溶剂对反应具有重要的作用,在此系统地研究了强极性非质子溶剂和中等极性非质子溶剂的应用情况,发现一些中等极性的非质子溶剂如硝基芳烃和氯代芳烃类溶剂在氯代苯甲醛类化合物的氟化反应中具有比强极性非质子溶剂更好的使用效果。

Centralized the iformation flow in detecting should satisfy afore-mentioned requirements, the haemal information network that builds a stability besides the requirement is exchanged with satisfying the real time of data outside, still should use the haemal information that accords with uniform standard to run software in order to assure centralized detect the unity of flow and can accuse, in addition, still should build regional integrated database on this foundation in order to assure the normative sex of data and consistency.

集中化检测中的信息流要满足上述要求,除了要求建立一个稳定的血液信息网络以满足数据的实时交换外,还应使用符合统一标准的血液信息管理软件以保证集中化检测流程的统一和可控,此外,在此基础上还应建立起区域性的综合数据库以保证数据的规范性和一致性。1.2国外信息保障方面的经验欧盟、美国、日本等发达国家都对信息技术给予了充分重视和大量投入,如美国采供血机构中的红十字会系统为实现全美地区的集中化检测,于1991—19。。。

Sythesis and application of chlorostyrene-DVB strongly acidic cation exchange resin ;2. For this study,a series of poly( p -amino styrenes) with various amounts of supported hydrogen chloride,and a series of strongly acidic cation exchange resin s with various exchange capacity were synthesized,and their catalytic property for ketalization of cyclohexanone and glycol were investigated.

通过测定固载了不同量的氯化氢的聚和不同交换量的强酸性阳离子交换树脂催化的环己酮与乙二醇的缩酮化反应缩酮的收率,研究了聚合物固体酸催化剂的疏水性对其催化缩酮化反应性能的影响;发现在一定范围内增加催化剂的疏水性,可提高缩酮化反应的收率。

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