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The spectroscopic and electrochemical studies suggest the energy structure of this class complex can be easily controlled by modification. With the introduction of electron-donating arylamino groups, the obtained complexes show intense and continuous absorption bands in the region of 250-550nm with strong metal-to-ligand charge transfer dπ(Pt →π* transitions (ε~ 2×104 dm3 · mol-1 · cm-1). Complexes involving the construction of D-π-A type systems also display continuous absorption bands in the region of 400-750nm, rising from the overlapping effect of MLCT and LL'CT bands.

其中,芳胺及其二聚体类修饰基团的引入,使其配合物MLCT吸收谱带的摩尔吸光系数增加,并在250~550nm范围内形成了强的连续吸收;具有D-π-A结构的配合物,由于MLCT吸收谱带和LL'CT吸收谱带的协同效应,导致在400~750nm范围内形成连续吸收;得到了从绿光到深红光的磷光发射系列配合物,并采用真空蒸镀的方法获到了外量子效率分别为5.7%和5.0%的橙光和橙红光多层电致发光器件。

Because the solubility of the complex monomers is very important for polymerization, the bidentate ancillary ligand of the bicycloiridium complexes also has an effect on the luminous properties of the chelating polymer.

实验证明了在这类电磷光聚合物中配合物单元辅助配体合理的分子设计,可以提高配合物单体的溶解度,提高聚合物的分子量和发光性能。

The characters of powder are connected with the inside structure and synthesize-technics of materials. In this paper, we want to search a optimize technics of materials synthesizing, and prepare a kind of nanosize powder which shape like ball and have good dispersed character. At the same time, we want to obtain a bridge structure of Zn-O-Tb through dopping of Tb, which can achieve efficient energy transfer from ZnO hosts to excited states of dopants, The doped powder can eradiate blazing green light because of efficient emission buildup from dopants and ZnO hosts, and the powder can emission a pure light. And we want to research the structure in doped ZnO for the further research of low-tension fluorescence of ZnO.

粉体的这些特性无不与其内部结构特征和制备工艺有关,基于这些,本文的实验目的是希望能寻找一种合适的制备方法和优化工艺,制备分散性好的球形纳米颗粒,希望改善其表面形貌,同时,通过铽掺杂,希望得到一种Zn-O-Tb桥联结构,实现氧化锌基体向铽发光中心的能量传递,希望铽中心特征发射和氧化锌绿光发射能有效叠加增强,改善粉体的单色性,制备出好的复合粉体,分析清楚其结构,从而为后续低压荧光特性研究作准备。

Associated minerals are primary glauberite, halite and terrigenous mud; while calcite is absent or rare. The X-ray diffraction analysis shows that the mud-sized crystalline dolostone has an average CaCO3 mole content of 57.30% and an average degree of order of 0.40, revealing the characteristics of higher calcium content and lower degree of order. It is closely intergrown with glauberite, indicating that the aqueous medium in the depositional environment of mud-sized crystallinedolostone was hypersaline water or dilute brine. The temperature of water in the depositional environment calculated according to the oxygen isotope data averaged 30.5℃ and the minimum homogenization temperature of inclusions in primary glauberite crystals associated with mud-sized crystalline dolomite was 44℃. The two groups of temperature data are close, indicating that the temperature of the water in the paleolake environment during the deposition of mud-sized crystalline dolostone ranged from 30.5℃ to 44℃.

泥晶白云石在阴极发光下呈红色、橙红色,与其伴生的矿物除原生钙芒硝、石盐、陆源泥质外,方解石没有或极少;X衍射分析结果表明,泥晶白云石的CaCO3摩尔含量平均为57.30%,有序度平均为0.40,具高富钙、低有序的特征;与钙芒硝岩的紧密共生,说明泥晶白云岩沉积环境的水介质为高盐度的咸水或淡卤水;根据氧同位素数据计算的沉积环境的水体温度平均为30.5℃,与泥晶白云石伴生的原生钙芒硝晶体中的包裹体均-温度最低值为44℃,这两组温度数据基本接近,表明泥晶白云石沉淀时环境水体的温度大致在30.5-44℃之间。

The as synthesized MCM 41 hosted Eu 3 mesophase was confirmed to possess hexagonally ordered mesostructure and a uniform ranosize of 30 nm with XRD and HRTEM techniques.

稀土配合物,尤其是含Eu3+和Tb3+的配合物,由于有机配体的强吸光能力和分子内高效的能量传递,一般都表现出良好的发光性能。

Varieties of Diopside include "Russian Diopside"(a chromium-rich Diopside known for its deep green color),"Violan"(a rare blue variety found in Italy ),"Cat's Eye Diopside"(green with the effect due to inclusions of rutile needles),"Malacolite","Salaite","Dekalbite" and "Star Diopside".

透辉石的品种包括&俄透辉石&、&青辉石&、&猫眼透辉石&(因含有金红石会状包体而产生绿猫眼发光效果)、&白透辉石&、&次透辉石&、&纯透浑石&以及&星芒透辉石&。

The alkali metal complexes containing oxadiazole ligand were synthesized and we found that the emission color was dependent on the central ion.

合成了含有噁二唑配体的碱金属配合物MOXD。我们发现配合物的发光颜色取决于中心金属离子,LiOXD是一个优良的蓝光材料,半峰宽是65nm,发射峰位在478nm,它也可以作为界面材料使用,起到和LiF相同的作用,即改善电子注入。

Phenanthroline ligand was tuned by incorporating triphenylamine group with hole-transporting nature and oxadiazole groups with electron-transporting nature into phenanthroline, which can help their europium complexes to have improved carrier-transporting property and increased luminous efficiency.

研究的主要内容有: 1通过引入三芳胺空穴传输单元和噁二唑电子传输单元,对邻菲罗啉中性配体进行分子修饰,从而改善它的铕配合物的载流子传输性能,提高铕配合物的发光效率。

However, the reason that LCD can't fully take the place of the tube is mainly on the performance of color and motion image. Though LCD can greatly improve the Color Saturation up to NTSC 105%, LCD is limited on reaction time and continue LCD light source, which create image shape shadows while the image moves due to photogene.

而液晶显示器目前无法完全取代映像管的地方就在於色彩及动态影像的表现,虽然发光二极体已可大大改善色彩饱和度到达NTSC 105%,但液晶显示器受限於液晶的反应时间及液晶显示光源表现为持续方式,使在动态影像表现上因人眼的视觉停留的因素导致影像移动的边界上产生阴影。

The photophysical properties of Py-Am under high pressure In PMMA film, Py-Am showed two emission states.

三。Py-Am的高压光物理性质:在PMMA固溶体膜中,Py-Am显示两种形态的发光。

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In this paper, the requirement analysis, design and implementation of the system are introduced in detail.

此论文详细介绍了系统的需求分析,系统设计和具体实现。

In the context of economic globalization is increasingly deepening, China's economy can not be spared.

在经济全球化日益加深的背景下,中国经济不可能做到独善其身。

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结果:(1)体外培养的内皮细胞缺氧后ICAM-1表达上调,随复氧时间的延长ICAM-1呈增强趋势。