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The results show that the initial phase is non-homogeneous reaction,solid-liquid mass transfer coefficient is the main factor on the reaction rate,N-methyl-2-pyrrolidone can accelerate the dissolution of polyester film and prompte the alcoholysis reaction into homogeneous process.

结果表明,反应初始阶段为非均相阶段,固-液间传质系数是影响反应速率的主要因素,加入NMP可以加速PET的溶解,促使醇解反应快速进入均相阶段。

It is existed competitiveness inhibition of 6APA, non-competitiveness inhibition of PAA and substrate inhibition of Penicillin on the hydrolysis of benzylpenicillin to 6APA and PAA by an immobilized penicillin amidase. The heat conductive coefficients were determined on the vacuum elevation liquid membrane concentration. The thermodynamics and kinetics of PAA extraction were studied on the organic solvent extraction of the above solution.

研究证明固定化青霉素酰化酶裂解反应是典型的底物、产物抑制酶反应,其反应动力学数据表明,青霉素、苯乙酸以及6APA对反应分别存在底物抑制、非竞争性抑制和竞争性抑制;真空升膜浓缩适应热敏性以及粘度不大的物系,对于6APA水溶液的真空升膜浓缩过程研究得到了浓缩实验的传热系数;浓缩液萃取主要是提取出其中的苯乙酸,本文测定了不同温度以及溶剂条件下的苯乙酸溶解度,并观测了苯乙酸萃取动力学。

However, statement II does give a true statement of the relationship of coefficients in a balanced equation of gaseous chemical reaction.

因为。配平的反应方程式的各个反应物的系数表明了参加反应的气体之间量的关系

Following optimal operation conditions are found through orthogonal tests: the excess coefficient of added precipitator 1.2~1.3, the pH value at the reaction end 3~4, the reaction time 30min and the reaction temperature 50℃.

通过正交实验,找出了从提取草酸的优化操作工艺条件:沉淀剂的加入过量系数为1.2~1.3,反应终点pH值3~4,反应时间30min,反应温度50℃。

In the one half part, according to the strontium nature, thermodynamic calculation of correlative reaction and the principle of the vacuum aluminothermy reduction process, with the laboratory findings of preparation strontium by vacuum aluminothermy reduction compared and analyzed in different parameter conditions, a variety of factors which effect the decomposition rate of SrCO_3 and the percent reduction of strontia are gotten out. The factors include that the decomposition rate of SrCO_3 is influenced by different addition and pressure. They also include that the percent reduction of strontia is influenced by excess coefficient of reducing agent aluminium powder, the particle size of raw material or reducing agent, the pressure of barbecuing, temperature and reduction time. According to those, we can draw the conclusion as follows:(1) Decomposition temperature of SrCO_3 is decreased by adding carbon and alumina in different degree.(2) With quantitative carbon added under the vacuum condition, the decomposition temperature of SrCO_3 is decreased obviously, which can fall 150℃ compared with atmospheric pressure.(3) In keeping 1150℃ of 2.5h, under the 5Pa vacuum condition, the decomposition rate of SrCO_3 nearly keeps in 99% steadily.

在前半部分的真空铝热还原法中,根据锶的性质、相关反应的热力学计算及真空铝热还原法原理,通过对不同参数条件下的真空铝热还原法生产金属锶的实验结果的分析比较,得出了影响SrCO_3的分解率和氧化锶的还原率的种种因素,具体因素包括不同添加剂、不同气压对SrCO_3分解率的影响,还原剂铝粉的过量系数、原料与还原剂的粒度、制团压力、温度和还原时间等对氧化锶还原率的影响,得出具体结论如下:(1)添加碳和Al_2O_3能不同程度的降低SrCO_3的分解温度;(2)真空条件下加入一定量的碳可显著降低SrCO_3的分解温度,比之常压下可降低150℃之多;(3)在1150℃恒温2.5h、真空度达到5Pa的条件下,SrCO_3的分解率几乎保持稳定在99%;(4)氧化锶的还原率随还原剂过量系数的增大而增大,但是趋势越来越小,当过量系数超过25%后,氧化锶的还原率几乎不再增加;(5)氧化锶的还原率随原料与还原剂的粒度的变细而增加;(6)氧化锶的还原率随制团压力的增加而增加,但超过一定值后,氧化锶的还原率反而会下降;(7)氧化锶的还原率随还原温度的升高而增加;(8)氧化锶的还原率随还原时间延长而增加,在本实验条件下,超过2.5h趋于稳定。

Where k is the kinetic constant or rate coefficient and n is the order of the reaction with respect to A.

那里k是动力学常数或速率系数,而n是与A有关的反应级数,若n=1就表示A是一级反应,若n=2,就表示A是二级反应,如此类推。

Using the theory of radiative capture reaction and combining our department experiment, we investigate two nuclear reactions,〓 and 〓, and calculate the cross sections and astrophysical reaction rate of them.

我们对ANC系数的近似模型无关性给出了一个数学形式理论证明,并结合具体的核反应,利用数值计算验证了ANC系数的近似模型无关性;在E1跃迁情况下,我们给出了一个用ANC系数计算辐射俘获反应截面的计算公式。

In this method, the equivalent elastic and elastic-plastic response spectra are ensured considering of structural inelasticity, the explicit expression of response spectra including Newmark-Hall deformation reduction factors is achieved.

该方法首先考虑结构的非弹性反应确定等效弹性反应谱和弹塑性反应谱,并建立了使用Newmark-Hall变形折减系数的能力谱的明确表达式。

This article that focuses on the systematic and in-depth research in the current primal problem about abnormal burst pressure reservoir depress burst pressure has procured following main fruits:1 It forms the method which could obtain massive vertical static state mechanics parameters.2 In a foundation of acquisition of rock mechanics parameters,apply bent lamella that as mechanical model along with characteristic of actual geologic characteristics to analysis curvature for anticlinal strcture, get homologous tectonic stress value throug relation between the curvature and stress and different principal curvature in anticlinal structure,consequently set up laminational stress model for anticline reservoir. The block lamination for existed fracturing date has formed method of setting up mechanical model of lamination terrestrial stress by abtaining the block tectonic stress coefficients which are got by complex utilization test, laboratory test and fracturing date playback.3 Analysesing the main reason which lead to high burst pressure by considering the characteristic of reservoir geology,reservoir,and rock mechanics and reservoir damage,etc.Establishing burst pressure quantitative prediction model which provide gist for depressing construction risk and optimizing construction craft under the condition of open hole completion ,gun-perforated completion and damaged reservoir.4 Provding theoretical basis for interpreting acidification pretreatment which could depress busrt pressure by finding the relation between the influencing factors and rock machanics parameters and analysing the factors that have effect on rock mechanics parameters. Expounding the mechanism of reaction of mixed monomineral and acid from the angle of microcosmic element, evaluating quantitatively acid sensilility of different kinds of mineral effectively, and determing the first-order reaction dynamical equation of each mineral.5 Revealing rock mechanics property chage as a result of acid flooding in different condition by sandstone traumata experiment in different temperatures which combined with rock mechanics triaxial stress experiment.6 Associating damage mechanics with sandstone acidizing, established sandstone damage mechanics model in the foundation of the recognition on the rock mechanics parametric variation which is caused by acid-rock reaction in both macroscopic view and microscopic view ,also demonstrated those processes and quantitative estimated the acid busrt pressure to direct the site operation.

本文针对目前异常破裂压力储层降低破裂压力的主要问题展开较为系统和深入的研究,取得了以下主要成果:1形成了利用测井资料,结合室内岩芯测试结果,获取静动岩石力学参数的相关性特征,从而获得纵向上大量静态力学参数的方法。2在获取了岩石力学参数的此基础上,利用弯曲薄板作为力学模型,结合区块实际地质特征对背斜构造进行曲率分析,通过曲率与应力的关系,利用背斜构造不同部位的主曲率求得相应的构造应力值,从而建立起背斜储层的分层应力模型;对已有压裂资料的区块分层,形成了综合利用测试、室内实验、压裂资料反演获得该区块构造应力系数,建立起分层地应力的力学模型的方法。3综合考虑储层地质、油藏、岩石力学特性和储层伤害等因素,分析造成高破裂压力的主要原因,综合利用岩石力学、弹性力学等知识,建立了裸眼完井、射孔完井条件下以及储层受到伤害后的储层破裂压力定量预测模型,为降低施工风险和优化施工工艺提供了依据。4完成了物性、岩性影响岩石力学参数的因素分析,找出了各影响因素和岩石力学参数之间的关系,为从机理上解释酸化预处理降低破裂压力提供了理论基础;从微观元素的角度阐述了单矿物与酸反应的机理;并在此基础上,有效评价了各种矿物的酸敏感性,定量确定了岩石中各矿物的一级反应动力学方程。5完成了不同温度下的酸液类型、酸液浓度、注酸量等一系列砂岩损伤实验,结合岩石力学三轴应力实验,系统揭示了在不同条件下注酸而引起的岩石力学性质变化。6将损伤力学与砂岩酸化相结合,在宏观、微观两个方面认识酸岩反应引起岩石力学参数变化基础上,建立了砂岩损伤力学模型,并对其进行验证,在此基础上定量计算酸化后的破裂压力,有效指导现场施工

At first in the preliminary design this paper computes the linear damping coefficient of the viscous damper employed in this project using Composite Response Spectra approach, meantime, this paper proves that reducing the exponent of velocity of the piston can increase the magnitude of the dissipative energy, because of the viscous damper employed in the practical project character nonlinear behavior; next this chapter performs analysis and comparison between the building without and with the viscous dampers aforementioned when the building suffers from various Time Domain Response, from the angle of displacement, interstroy drift, velocity, interstory velocity, acceleration, energy, maximum axial force of the dampers and of the column etc., in order to prove that the incorporating the viscous dampers into the buildings has great superiority on enhancing its aseismic performance ; furthermore, this chapter also expatiates on diverse assembly form of the viscous dampers that results in the adverse impact on the internal force of the structural member in this building, on the ground of which this segment bring about the preference of the assembly form of the viscous damper; finally this chapter points out the sphere of application of the analysis and computation using Composite Response Spectra approach in design: it is available in well-proportioned stiffness structures and isn抰 available in the structures that contain weak story. It is recommendable, particularly, to incorporate the fluid viscous dampers into this structure that contain weak story to refrain earthquake and reinforce, such as the Central Hall of Shanghai Exhibition Hall.

首先使用了反应谱分析法设计出欲附设的粘滞阻尼器的线性阻尼系数,由于实际工程所用的粘滞阻尼器具有非线性的特性,故而笔者又证明了降低速度指数对提高粘滞阻尼器的耗能量的优势所在;接着分别从位移、层间位移、速度、层间速度、加速度、能量、最大阻尼出力和柱轴力等不同的角度对结构在附设粘滞阻尼器前后的时程反应进行了分析对比,籍此在实际工程中证明了附设粘滞阻尼器对于提高结构的抗震性能的优越性;再者,笔者还阐述了采用不同的粘滞阻尼器布置方式对结构中构件内力特别是柱轴力和基座竖向反力产生的不利影响,并在此基础上提出了布置方式的优选;最后,指出了反应谱法在设计中的适用范围:对于均匀结构反应谱法能够使用,而对于含有薄弱层的结构反应谱法并不适用;对于类似于上海展览馆中央大厅的含薄弱层的结构尤其值得使用粘滞阻尼器的方法进行抗震加固。

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