反应

The first part consists of three experiments:(1) The rings were incubated in KH, 20, 50 mmol/L 〓 for 1 house, relaxation in response to the EDHF stimuli A23187 in 30nmol/L U46619-induced preconrtaction in the presence of 7 μ mol/L indomethacin, a cyclooxygenase inhibitor, 300μmol/L LNNA, a nitric oxide biosyhnthesis inhibitor, and 1mmol/L tetraethylammonium , a 〓 blocker, or 3 μmol/L glibenclamide , a 〓 blocker, was compared with the control;(2) After the arteries were incubated in KH, UW solution or HTK solution at 4℃ for 4 hours, endothelium-derived relaxation (percentage of 30nmol/L U46619 precontraction) was induced by A23187 in the present of 7 μmol/L indomethacir and 300μmol/L LNNA;(3) After incubation with KH, UW solution and STH (either at 37℃ in oxygenated organ chamber or at 4℃ in a refrigerator for 4 hours), endothelium-derived relaxation (percentage of 30nmol/L U46619 precontraction) was induced by A23187 in the present of 7 μ mol/L indomethacin and 300 μmol/L LNNA.

第一部分研究结果：（1）单纯浸泡于KH的冠状动脉A23187能引发66.67％的血管舒张反应，经TEA及20mmol／L、50mmol／L钾离子作用后，血管舒张反应程度显著降低，但经GBM作用后改变不明显；（2）与保存于KH的冠状动脉相比，A23187引发的血管舒张反应程度，保存于UW液的明显下降，保存于HTK液的无明显变化；（3）在37℃条件下，血管环浸泡于STH出现缓慢轻微的舒张反应，浸泡于UW液初期出现短暂收缩反应，但此后主要以舒张为主：在37℃条件下，血管经UW液保存后，U46619引发的收缩反应程度降低；不论在37℃或4℃条件下，A23187引发的血管舒张反应，经UW液保存后明显下降，但用STH保存后变化不明显。

And the optimum pH was 4-6 for the dechlorination reaction of 2,4-D, and pH between 2 and 8 were all suited for the reaction in Pd/Fe systems. Intermediate and final products of 2,4-D, HCH and chlordane with Pd/Fe were determined by GC/MS, and the possible dechlorination pathways were concluded: 2,4-D can be converted to phenoxyacetic acid through gradual hydrogenolysis, and HCH can be transformed to cyclohexatriene through dichloroelimination or dehydrochlorination.

通过GC/MS定性定量分析了三种目标污染物在Pd/Fe体系中发生还原脱氯反应过程中的反应物及最终产物，并根据反应产物推测分析了这三种有机污染物在催化还原反应体系中可能的反应途径：2，4-D主要通过逐级氢解最终生成彻底脱氯产物苯氧乙酸；而六六六则可能通过逐步双氯消除反应或脱氯化氢反应，最后生成环己三烯。

Reductive conversion of geraniol to citronellol is adopted as a model reaction, and several factors in the reaction are discussed using gas chromatography method. The influence of n-hexane and butyl acetate, as organic solvents, on biocompatibility was studied; the influence of methanol, ethanol, glycol, n-butanol and 1-hexanol, as energy substance, on the transformation efficiency was compared, respectively; the catalysis capabilities of Baker's yeast, XST-KO yeast, LP yeast, alcohol yeast, dry yeast, Saccharomyces cerevisiae, Angel yeast and Meishan yeast were discussed. It has been proved that biocompatibility of n-hexane are much better than that of butyl acetate, and the hexane has been demonstrated the most effective in terms of the influence on biotransformation, Baker's yeast has shown the highest tranformation efficiency among the eight yeast strains.

以香叶醇转化为香茅醇作为模型反应，通过气相色谱法进行定性和定量分析研究了影响该有机相生物转化反应的几个基本因素，考察了两种有机溶剂正己烷和乙酸丁酯对生物相容性的影响，选用甲醇、乙醇、乙二醇、正丁醇和l-己醇分别作为能量物质进行实验，比较其对转化的影响并探讨了Baker's酵母、XST-KO酵母、LP酵母、酒精酵母、假丝酵母、干酵母、安琪酵母和梅山酵母八种不同酵母作为生物催化剂对模型反应的催化能力，结果表明，正己烷作为有机溶剂，其生物相容性明显好于乙酸丁酯，更加有利于该生物转化反应进行；乙二醇作为能量物质，该模型反应转化率最高；而 Baker's酵母作为生物催化剂，对该模型反应的催化能力最强，最适合作为该模型反应的催化剂。

The optimum reaction conditions are obtained by orthogonal exptl. design; ring-opening reaction:n:n = 1:1.3, Hexamethylenetetramine catalyst 0.7%,reaction temp. is 80℃, reaction time is 7 h, and concentration of inhibitor is 0.3%. ring-closing reaction : n:n=1:0.9, reaction temp. is 40℃, reaction time is 5 h.

通过正交设计确定了最佳工艺条件为：开环反应：六次甲基四胺用量0.7%(占反应物总量的质量百分比)，阻聚剂用量0.3%(占反应物总量的质量百分比)，ECH：MAA的摩尔比为1.3：1，温度80℃，反应时间7h ；闭环反应：氯醇酯： NaOH的摩尔比为1：0.9，反应温度40℃，反应时间5h。

The main content of this paper as follows: The acidic strength, reaction temperature, reaction time of Chlorine-aluminate Ionic Liquids with different structure of cation on the activity of transalkylation of MN with TeMB and the selectivity of 2,6-DMN were studied. The optimum reaction condition was obtained: the molar fraction of AlCl_3 is 0.71, molar ratio of 2-MN and TeMB is 1, the amount of ionic liquid is 32wt%, reaction temperature is 20℃and reaction time is 8h using X-xAlCl_3 and X-xAlCl_3 as catalysts; the optimum reaction time is shortened 6h using Et_3NHCl-xAlCl_3 as catalyst.

本文主要研究了以下内容：分别考察了不同阳离子结构的氯铝酸盐类离子液体的酸强度、反应温度、反应时间等因素对MN和TeMB转移烷基化的催化反应活性和2，6-DMN选择性的影响，优化得到适宜的反应条件为：以X-xAlCl_3和X-xAlCl_3为催化剂时，AlCl_3的摩尔分数x=0.71，2-MN和TeMB摩尔比为1∶1，离子液体用量为32wt％，反应温度为20℃，反应时间为8h；以Et_3NHCl-xAlCl_3为催化剂时，反应时间缩短到6h。

Through mechanism analyzing on the process of producing HMT , it was known that because the resistance of isobutylene was small ,the yield of outgrowth in such a reaction system was little and the yield of reaction was as high as 86%. 2,3-dimethyI-butene-2 had the biggest resistance and lowest yield of reaction of 18%. 2,3-dimethyl-butene-l had bigger resistance than isobutylene and more outgrowth than isobutyles but its yield of reaction could reach 70%.

通过对上述三种烯烃合成HMT的研究可知，由于新己烯位阻小，反应中副反应少，收率高达86％：而2，3—二甲基—丁烯—2的位阻最大，反应中副反应最多，反应收率最高仅为18％；2，3—二甲基—丁烯—1的位阻比新己烯大，反应副产物比新己烯多，但反应收率仍可达70％。

In this study, the UV-spectra of AITC and its thioureas , and kinetic properties of piperidine, morpholine and diethyl amine reacted with AITC were investigated.

AITC与胺反应转化为硫脲后，最大吸收峰强度有了极大的提高，摩尔吸光系数增加了十余倍；利用我们的发现，我们以光度法研究了该反应的动力学，证明该反应为二级反应，并求得了反应速率常数和反应活化能等参数；同时，讨论了反应机理。

In this paper,investigation has been made on the process for the synthesis of salicylaldehyde by esterification-oxidation with phenol,paraformaldehyde,boric acid as initial materials.

探索了以苯酚、硼酸和多聚甲醛为原料的酯化氧化法合成水杨醛的工艺路线，根据反应特点，改进了酯化反应方式，采用了多聚甲醛气态解聚法作为羟甲基化反应的进料方式，探讨了羟甲基化反应温度、多聚甲醛原料含水量、催化氧化反应催化剂用量对反应收率的影响并得到最佳反应条件，水杨醛收率为60.5%，纯度达98%以上。

The paper reviews the advanced progress in the application of ionic liquids as reaction medium as well as catalysts to organic synthesis, mainly including coupling reaction, Michael addition, Baylis-Hillman reaction, Diels-Alder reaction, Aldol reaction, Knoevenagel condensation, cyclorization reaction, alkylation and acylation, oxidation and reduction etc.

综述了离子液体作为反应介质或催化剂在有机合成传统反应类型中的最新研究成果，主要包括：偶联反应、Michael加成、Baylis-Hillman反应、Diels-Alder反应、Aldol缩合、Knoevenagel缩合、环化反应、烷基化及酰基化反应和氧化还原反应。

objective the aim of this study is to investigate the expression and the distribution of the nerve growth factor during the period of neural tube development of human embryo.method early development of neural tube was studied in human embryos about 35 gestational days by using immunocytochemical abc technique.result there were ngf immuno-positive substances in the cytoplasm and nuclei of neuroepithelial cells in the ventricular zones of neural tube.in the intermediate zone of neural tube,ngf immunoreactivity was detected in the nuclei of some neurons,or the processes of other neurons which contained no ngf-immunoreactive substances in their nuclei;the expression pattern of ngf in the marginal zone of neural tube was similar to that of the intermediate zone.the density of ngf-immunorecative particles was higher on the rostrum side of neural tube than on the caudal side.the ngf immuno-positive cells were also observed among the somites of embryo under the neural tube.conclusion these results suggest that ngf was an important signal molecule to induce neural tube differentiation,and that ngf may play a significant role in regulation of the biological function of neurons in developing neural tube.

目的 研究捷安肽素的抗真菌作用机理。方法采用形态学方法和同位素标记法。显微形态观察经捷安肽素处理后的供试真菌的形态学变化。进一步采用14c同位素标记的特异底物&尿苷二磷酸-（14c）-葡萄糖&示踪，研究捷安肽素对真菌(1，3)-β-d-葡聚糖合成酶活性反应的影响。结果研究神经生长因子在早期人胚神经管发育过程中的定位表达。方法采用免疫细胞化学 abc法染色，研究35天人胚的发育情况。结果在人胚神经管的室管带中，神经元的细胞质和细胞核ngf免疫反应阳性；在中间带，一部分神经元的细胞核ngf免疫反应阳性，另外一部分神经元的细胞核ngf免疫反应阴性，而其突起ngf免疫反应阳性；在边缘带ngf的表达与中间带相似。在神经管的头侧ngf阳性反应较强，神经管的尾侧ngf阳性反应较弱。结论 ngf在人胚神经管免疫反应阳性，表明ngf可能是诱导神经管分化发育的重要信号分子，提示ngf可能在人胚神经管的发育中具有十分重要的作用。神经生长因子；人胚；神经管；发育

Objective To investigate the effects of interleukin-1 β converting enzyme gene on the biologic characteristics of ovarian cancer cells.

目的 探讨白细胞介素-1 β转换酶的表达，对卵巢癌细胞生物学特性的影响。

Campylobacter: This illness is the most commonly identified cause of diarrheal illness in the world.

弯曲：这种病是最常见的原因查明腹泻病，在世界上。