化

By way of sulfonation on emeraldine base polyaniline, sulfonated polyaniline was prepared. Effect of reaction conditions on conductivity and sulfonation degree of SPAN was discussed in detail. The relationship of sulfonation degree and solublility was also discussed.

通过磺化的方法，对本征态聚苯胺进行了磺化改性研究，讨论了磺化条件对磺化聚苯胺电导率、磺化度的影响以及磺化度与溶解度的关系。

The results indicate that the heteronuclear bond energies are greater than homonuclear bond energies.

用示差扫描量计、X光衍射以及透射电镜研究了非晶铝合金的晶化行为，结果表明，非晶铝合金的晶化经历了初晶型晶化和剩余非晶的多重型晶化，整个晶化过程可相应地分为第一和第二晶化阶段。

The invention discloses a LCD panel, colorful filter piece and making method, which comprises the following steps: providing a base; forming a buffer material layer on the base; forming patterned lightproof layer on the buffer material layer; adopting patterned lightproof layer as lid to pattern the buffer material layer to form a patterned buffer layer; forming a separating piece through patterned lightproof layer and patterned buffer layer; making the separating piece form multiple pixel areas on the base; forming a colorful filter layer in each pixel area.

本发明公开了一种液晶显示面板、彩色滤光片及其制作方法，其中彩色滤光片的制作方法包括下列步骤：首先，提供一基板，并在基板上形成一缓冲材料层。接着在缓冲材料层上形成一图案化遮光层。以图案化遮光层为罩幕来图案化缓冲材料层而形成一图案化缓冲层，使得该图案化遮光层与图案化缓冲层共同形成一隔离件，且隔离件在基板上形成多个像素区域。然后在每一像素区域内分别形成一彩色滤光层。

The decisive influencing factor of viscosity in carboxyl-methylation was cross-linking reaction. Carboxyl-methylation was the main influencing factor of solubility and swelling capacity in modification of high content amylose starch. The structure and gelatinization property of different amylose content were analyzed with an Olympus Vanox BHS-2 multi-function optic microscope, and the results were as follows. The structure of ordinary cornstarch was different from the high amylose; gelatinization temperature and pH value of starch were affected deeply by amylose content, but had little difference between the gelatinization of high content amylose starch contained 50% and 70% amylose; pH value had much more effect than temperature on the gelatinization of high content amylose cross-linked starch. Monochloroacetic acid consumption, alcohol concentration and pH value influenced the starch carboxyl-methylation. When alcohol concentration was 60%, pH value 10, monochloroacetic acid/starch mass ratio 55%, the carboxyl-methylation of high amylose cross-linked cornstarch had the best result. With the In-Vitro digestibility model and biodegradation experiment, the digestibility and biodegradability of high amylose cornstarch and its modified starch were detected.

采用Brabande粘度测定仪和Olympus Vanox BHS-2型多功能光学显微镜等分析手段对链淀粉含量50％和70％的高链玉米淀粉及其交联和交联羧甲基化淀粉的结构和性质进行了表征和分析，结果表明，普通玉米淀粉结构与含链淀粉50％和70％高链玉米淀粉结构不同；高链淀粉比普通淀粉难糊化，高链改性淀粉糊化受pH值影响较大，受温度影响较小；淀粉的冻融稳定性、透光率、溶解度、膨胀度和粘度受链淀粉的含量和改性的影响，但是，链淀粉含量超过50％时，则链淀粉含量对淀粉的膨胀度和溶解度影响不大；改性淀粉性质的影响因素中，影响粘度主要因素是交联反应，影响透明度、溶解度和膨胀度主要因素是羧甲基化改性；一氯乙酸用量、反应时乙醇浓度及碱性条件都会影响高链淀粉及其交联淀粉的羧甲基化改性效果，制备羧甲基化改性淀粉的最佳工艺是在pH值为10的60％的乙醇浓度介质中按一氯乙酸/淀粉质量比为55％进行取代反应。

The microstructure evolution and composition distribution of the 7A55 cast and homogenized alloy were studied by optical microscopy, scanning electron microcopy, energy dispersive spectrometer, transmission electron microscopy and X-ray diffractometry. The homogenizing and overburnt temperatures of the alloy were determined. Meanwhile, the diffusion kinetics of the alloy elements during homogenizing treatment was investigated and the homogenizing kinetic equation was deduced according to Fick's First Law of diffusion. The diffusion of alloy elements, precipitation of Al3Zr particles and the conglomeration and globe of the insoluble phases were explained by the equation during homogenization.

摘 要：采用光学显微镜、扫描电镜、能谱分析、透射电镜和X射线衍射分析等研究了7A55合金铸态与均匀化显微组织演化与成分分布，确定了该合金的均匀化处理温度与过烧温度，研究了铸锭均匀化动力学过程，利用菲克定理导出了均匀化动力学方程，利用动力学方程对均匀化过程中合金元素的扩散、 Al3Zr的析出、难熔相的聚集和球化现象进行了解释。

In solid phase process, the polyiodides, which include triiodide, pentaiodide, heptaiodide, nonaiodide and undecaiodide tetra-n-butyl ammonium iodide, tetrabutyl ammonium bromide and tetramethyl ammonium iodide poly-compounds, were synthesized by the low-heat solid phase reaction between iodine and tetra-n-butyl ammonium iodide, tetrabutyl ammonium bromide or tetramethyl ammonium iodide; In complexation process, solution polyiodides were synthesized by complexing action of different agents; In resinifying process, triiodide, pentaiodide, heptaiodide resinic polyiodides were synthesized by ion-exchange when the strong basicity styrene anion exchange resin, potassium iodide and iodine were used as raw materials.

固相法是用正四丁基碘化铵、四丁基溴化铵或四甲基碘化铵分别与碘作用，通过低热固相反应，合成出碘三、碘五、碘七、碘九和碘十一形式的正四丁基碘化铵、四丁基溴化铵或四甲基碘化铵的系列高聚碘化合物；在络合法合成溶液高聚碘的实验中，选用几种络合剂通过络合作用首次合成了溶液高聚碘；树脂法合成高聚碘的实验是采用强碱性苯乙烯系阴离子交换树脂、碘化钾和碘为原料，通过离子交换，合成了碘三、碘五和碘七形式的树脂高聚碘。

The innovation of this article is the perspective of "columnized survival". On the one hand, it carries out the summary the course of development of more than 10 years of columnized documentary, positively affirmed the trend of plebification with on-the-spot report concept and the trend of story expressed with entertainment concept; on the other hand, the article carries out meticulous analysis on the existing character of columnized documentary and the differences of non-columnized documentary of tradition. After having analyzed a mass media objectively getting involved in documentary, the article carries out the change coming into being in aspects of documentary such as making idea, production process, aesthetic attributes, narrative technique and social function. It carries out the calm thinking on the appearing problem, and seeks new export to the documentary with columnized survival.

这篇论文的创新之处在于从&栏目化生存&这一角度切入分析纪录片，一方面对纪录片栏目化十余年的发展历程进行概括总结，积极肯定了栏目体制下运作的纪录片所体现出的平民化与纪实观念、故事化与娱乐观念；另一方面，对栏目化生存下纪录片的本体特征、与非栏目化生存的传统纪录片进行细致分析，客观剖析阐述大众媒介介入纪录片创作后，纪录片在制作理念、生产方式、审美属性、叙事手法、社会功能等方面产生的变化，并对其出现的问题进行冷静思考，以期结合当下的生存语境，为目前纪录片栏目化生存的发展探寻新的出口。

Therefore, the future landscape design should attach greater importance to the humanity, ecology, frugality, spatiotemporality, poeticness and personality, while the expression of design result should be clear and standardized, the most important basic requirements.

因此，认为今后的园林设计应进一步重视人性化、生态化、节俭化、时空化、诗意化、个性化和表述明晰化7方面内容，而设计成果的表达必须规范和明晰化，这是最重要的基本要求。

In this paper, firstly using natural fatty acids including lauric acid, myristic acid, palmitic acid etc. and disproportionated rosin as starting materials, the acyl reaction of starting materials with SOCl_2 respectively, and then using Schotten-Baumann condensation: on the reaction conditions of alkalescence, condensation of acylchloride with amino acid (sarcosine, glycine, alanine etc.), and then acidification, saltation. A series of anionic surfactants of N-acyl amino: sodium N-fatty acyl sarcosinate (SFS-12, SFS-14, SFS-16); sodiun N-fatty acyl glycinate(SFG-12, SFG-14, SFG-16); sodium N-fatty acyl alaninate(SFA-12, SFA-14, SFA-16)and sodium N-disproportionated rosinoyl aminatewere prepared. During the preparation of N-acylamino acid, the reaction conditions of acylchloride with amino acid condensation were identified by optimizing the synthetic conditions of N-lauroyl sarcosine: mol ratio of amino acid to acylchloride 2:1, reaction taken place in a solvent composed by acetone/water 2:1, acylchloride and 20% NaOH were slowly added to the reaction mixture at the same time while maintaining the pH at 9~10, after completion of adding maintaining reacting for 2.5h at 25℃.

首先以月桂酸、肉豆蔻酸、棕榈酸等天然脂肪酸和歧化松香为原料，与氯化亚砜反应制得酰氯，然后采用Schotten-Baumann 缩合法路线，即在碱性条件下，酰氯和氨基酸(肌氨酸、甘氨酸、丙氨酸等)缩合，经过酸化、成盐，合成一系列氨基酸型阴离子表面活性剂：脂肪酰肌氨酸钠，即月桂酰肌氨酸钠(SFS-12)、肉豆蔻酰肌氨酸钠(SFS-14)、棕榈酰肌氨酸钠(SFS-16)；脂肪酰甘氨酸钠，即月桂酰甘氨酸钠(SFG-12)、肉豆蔻酰甘氨酸钠(SFG-14)、棕榈酰甘氨酸钠(SFG-16)；脂肪酰丙氨酸钠，即月桂酰丙氨酸钠(SFA-12)、肉豆蔻酰丙氨酸钠(SFA-14)、棕榈酰丙氨酸钠(SFA-16)；N-歧化松香酰基氨基酸钠(sodium N-disproportionated rosinoyl aminate)，即N-歧化松香酰基肌氨酸钠(sodium N-disproportionated rosinoyl sarcosinate ，简称SDRS)、N-歧化松香酰基甘氨酸钠(sodium N-disproportionated rosinoyl glycinate，简称SDRG)、N-歧化松香酰基丙氨酸钠(sodium N-disproportionated rosinoyl alaninate，简称SDRA)。

Sulfuric acid was sulphonation reagent, add the sulfuric acidquantity was 8%, reaction temperature was 60~65℃.The reaction occursbetween the feed oil and sulfuric acid,then add 30% of sodium hydroxidesolution conducted neutralization in the Pyrex standard react kettle,when the reactionfinished ,draw out the products by funnel,then the products react with 8%clay to refine received the sulphonation refining oil so as to review property andreceive rate of the shallow sulphonation refining oil .By the using the sulphonationrefining oil to blend lubricant,its quality is on-specification .

为验证其可行性，首先在实验室进行浅度磺化小试，原料油采用新疆原油经常压蒸馏、减压蒸馏、溶剂精制、溶剂脱蜡后的减压二、三线脱蜡油，发烟硫酸作为磺化剂，发烟硫酸加入量8%，反应温度60～65℃，用三口圆底耐热玻璃标准反应釜对原料进行发烟硫酸磺化，加入量30%氢氧化钠中和，分液漏斗抽提，在烧杯内加入量8%白土进行精制得到磺化抽余油，考察浅度磺化抽余油性质和收率，用磺化抽余油调合润滑油质量合格。

Do not gum up the work by telling mother what we are going to do .

别告诉母亲我们要干的事，那会把事情搞糟的。

In recent years, application of the partial prestressed concrete beam s is developed.

近年来，随着部分预应力砼梁应用的推广，发现我国规范所采用的名义拉应力法的计算结果不稳定。