加成产物

The reaction process in methanol solvent can be deduced from the computational results with CPCM solvent model and the supermolecular handling, namely the reaction involves four steps in the methanol solvent. The nucleophilic addition of trimethylamine to acraldehyde generates an enolate. Nucleophilic attack of the enolate on the aldehyde forms the carbon-carbon bond, followed by the proton-transfer process and the further elimination generating the product and liberating the trimethylamine catalyst.

对于CH3OH对反应体系的影响，可以综合考虑CPCM溶剂模型及超分子模型下的研究结果，即CH3OH溶剂中反应按四步进行，催化剂三甲胺首先与丙烯醛发生亲核加成，生成的两性离子中间体与甲醛发生类似于Aldol的醛醇缩合，形成碳-碳键，之后发生分子内质子转移，最后经E1cb消除得到产物，并释放催化剂三甲胺。

The copolymerization of cycloolefin and α-olefin, and structure of the obtained polymer are significantly affected by the structure and symmetry of metallocene catalysts, electronic effect and steric hindrance of ligands.

着重介绍了加成聚合法中茂金属催化剂的结构对称性、配体的电子和体积效应、反应条件等对聚合活性、产物组成与序列分布及相关热性能的影响。

The copolymerization of cycloolefin and α-olefin,and the structure of the obtained polymer are significantly affected by the structure and symmetry of metallocene catalysts ,electronic effect and steric hindrance of ligands.

着重介绍了加成聚合法中茂金属催化剂的结构对称性、配体的电子和体积效应、反应条件等对聚合活性、产物组成与序列分布及相关热性能的影响。

In our research on study chemical reaction of active methylene compounds and brom-acetophenone. Because of brom-acetophenone is compound that contain carbonyl and halogen ,which will take place electrophilic substitution and nucleophilic addition. When active methylene compounds are ethyl acetoacetate and β-diketone, controlling reaction condition, we have found that mono-substitution's production and di-substitution's. production is isolated; active methylene compounds are acetoacetanilide and acetoacetanilide derivate, pyrrolidin-2-one derivants were obtained by substitution and close-ring reaction .but there is no report about it.

本文是让活泼亚甲基类化合物与溴代苯乙酮发生化学反应，由于溴代苯乙酮是含有羰基的卤代烃结构，它可以发生亲电取代和亲核加成反应，当活泼亚甲基类化合物为乙酰乙酸乙酯和β-二酮时，控制反应条件可以发生单取代和双取代两种产物；当活泼亚甲基类化合物为乙酰乙酰芳胺类化合物来反应时，溴代苯乙酮中的羰基与氨基会发生分子内的关环反应生成吡咯烷-2-酮衍生物，这在以前的研究中是没有发现的。

The mechanism was supposed as follows: polyfluoroalkyl iodides were initiated by sodium dithionite to give R〓 which was added to one double bond of diallylacetic acid, after the sequential radical cyclization and nucleophilic substitution to form bicyclo-lactones.

这是因为：多氟烷基碘化物在连二亚硫酸钠的引发下，得到自由基R〓，后者加成到二烯丙基乙酸中的一个—C=C—双键上，然后在碱性介质中进行分子内亲核反应得到双环内酯类产物。

Polyfluoroalkyl iodides could react with unsaturated olefin acids in the presence of sodium dithionite by radical addition to give adducts. It was found that these adducts could form polyfluoroalkyl substituted γ or δ-lactones due to intramolecular nucleophilic substitution in the alkali solution.

研究发现：多氟烷基碘化物在连二亚硫酸钠存在下与不饱和烯酸经自由基加成得到的产物，能在碱性条件下进行分子内亲核取代反应形成五元或六元环的含氟内酯类化合物。

Depending upon reaction conditions, the product may be a polyketone formed b y addition polymerization of the ketene double bond

随着反应条件的不同，产物可以是由烯酮的双键加成聚合得到的聚酮。

From the reaction mechanism, which involved formation of benzodiazepinium ethoxycarbonylmethylate, the reaction mechanism, which involved formation of benzodiazepinium ethoxycarbonyl- methylate followed by cycloaddition reaction, was tentatively proposed.

通过研究反应过程中分离出的副产物反丁烯酸二乙酯III和4，5-二氢吡唑-3，4，5-三羧酸乙酯IV，初步提出了反应经过乙氧羰基甲基化苯并二氮杂卓翁中间体V再发生环加成反应的机制。

In chapter 4 an abnormal reaction that the nitro group of 1-aryl-2-nitroethenescan be easily replaced by the organic moity of FG-RZnI using Ni〓 and tertiaryamine as catalyst was first given. The experimental results show that in the presenceof catalytic amount of Ni〓 and tertiary amines, the reaction of FG-RZnI andl-aryl-2-nitroethenes give the substitution products l-aryl-l-alkene, instead ofMichael addition products.

通过实验发现，在催化量的Ni〓及叔胺催化下， l-硝基-2-芳基乙烯与烷基碘化锌并不进行Michael加成反应，而是发生1-硝基-2-芳基乙烯中硝基被取代的反应，生成了高产率的1-芳基-l-烯烃，由于此反应的原料易得、反应条件温和、产物的产率高，因而是合成l-芳基-1-烯烃的有效方法。

In this thesis, we developed a new method to construct 2, 3, 6-trisubstituted piperidines using enantiopure -amino acid derivatives as the starting material and applied them to the synthesis of some piperidine alkaloids which showed interesting physiological activities.

本论文中，我们从非手性原料出发，通过手性胺对、(-不饱和酯的Michael加成来获得光学纯的-氨基酸酯，发展了一种构建2、3、6-三取代哌啶环的方法，并利用这种方法合成了一些具有重要生理活性的生物碱类天然产物。

Further more, the simplified analysis method on stressed-skin effect of corrugated steel sheet is also discussed in detail.

此外还比较详细地探讨了蒙皮效应的简化分析方法。

If I had known her telephone number,I would have called her.

要是我知道她的电话号码，我就打电话给她了。