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凝胶

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Polyethersulfone with cardo was a developed engineering thermoplastic and membrane material with high glass transition temperature,PES-C ultrafiltration membranes were prepared by phase inversion method using dimethylacetamide as solvent and oxalic acid and polyethylene glycol as additives.The membrane morphology forming and evolution could be observed by the experimental system and method.The effect of additive and polymer concentration on cast solution and the gelation kinetics of polyethersulfone with cardo asymmetric membrane were studied.

采用耐高温工程塑料——含酚酞侧基的聚芳醚砜为膜材料,草酸和聚乙二醇为添加剂, N,N -二甲基乙酰胺为溶剂,并利用改进的凝胶动力学实验装置和方法,使之能真实地再现不同膜孔结构生长及发展演化的过程,借助相关软件对图像进行处理,考察了添加剂、聚合物浓度对铸膜液凝胶速度的影响,对酚酞基聚芳醚砜非对称膜的凝胶过程的动力学进行研究。

The result showed that intensity of CMG decreased evidently,and its hardness,springiness and chewiness increased significantly under the pressure of 200 MPa or above.

研究结果表明:200 MPa以上的高静压可导致鸡肉凝胶亮度的显著下降、以及凝胶硬度、弹性和咀嚼性的显著增加;300 MPa以上的高静压可引起鸡肉凝胶pH值和黏结性的显著升高P。

Transmission Electron Microscope and other properties testing results show that the complex emulsifier system is the crucial influence factor of the polymerization process and the properties of products. It may influence the coagulum content and reaction rate of the polymerization process, the performance, particle diameter,viscosity, electrolyte stability and storage stability of the emulsion products and the contact angle of the film.The initiator mainly influences the coagulum content and reaction rate.The acrylic monomers mainly influence the solid content, Minimum Film Formation Temperature of the emulsion and the Glass Transition Temperature of the film.The organic silicone monomer mainly influences the water absorption of the film.The reaction temperature mainly influences the reaction rate and conversion.The stirring intensity mainly influences the coagulum content of the polymerization process.

透射电镜等性能测试结果显示:复合乳化剂体系是硅丙共聚乳液的聚合过程及产品性能的主要影响因素,它可以对聚合过程的凝胶率、反应速率以及乳液的外观、粒径、粘度、耐电解质稳定性及贮存稳定性,还有乳液涂膜的接触角等造成不同程度的影响;引发剂主要影响反应速率和凝胶率;丙烯酸酯单体主要影响到乳液的固含量、最低成膜温度以及涂膜的玻璃化转变温度,有机硅单体主要影响涂膜的吸水率等;聚合反应温度主要影响乳液的反应速率和转化率等;搅拌强度主要是影响到聚合过程的凝胶率。

The performances of Ceramic-wood composite such as decay resistance, dimensional stability and effloresce resistance were improved owing to the introduction of the cymene, which reducing the inner stress of gel net, meliorating the brittleness and reducing the absorbility of gel.

CH3可以降低凝胶网络内应力,改善凝胶的脆性,同时憎水基团-CH3还可以降低凝胶的吸水性,因而材料的尺寸稳定性、耐风化和耐腐朽性能都得到提高。

The hydrophobic association in heating process is not the same as the disassociation in cooling. Thermal gelation behavior is strongly influenced by the degree of substitution.

HPMC的两个取代基团对热凝胶过程的影响效果是相反的,羟丙基和水分子之间的氢键作用对预凝胶阶段的开始起着阻碍作用,而甲氧基则对凝胶阶段的大分子的疏水结合起促进作用。

Methods Gelators of N-lauroyl-l-alanine methyl esterand N-lauroyl-l-alanine ethyl esterwere synthesized with l-alanine methyl ester,l-alanine ethyl ester and lauroyl chloride as materials.

方法以l-丙氨酸甲酯盐酸盐、l-丙氨酸乙酯盐酸盐和月桂酰氯为原料,合成月桂酰-丙氨酸甲酯凝胶因子及月桂酰-丙氨酸乙酯凝胶因子,采用IR、1H-NMR、MS对其结构进行表征,并对其熔点、热稳定性、在各种植物油中的最小胶凝质量浓度、相转变温度等基本性质进行了研究。

To simplify Hu Ying and coworker's mixing model according to the gel's characteristics, and to revise the Flory's physical entanglment elasticity model, a concept of non-gaussian-short chains and interlooping chains is introduced which results, in a super-short and interlooping chains fraction Ψ and the number of effective segment N.

含离子凝胶分子热力学模型则在上述工作的基础上,进一步考虑了大分子网链中离子氛之间的静电排斥作用,并假设凝胶内活动离子的扩散作用服从唐南平衡,导出了新的含离子凝胶的分子热力学模型。

It is revealed that a certain amount of excessive formamide is favorable for preparation of the aerogel with high porosity, while more excessive glycol can deteriorate the formation of nano-porous SiO2 aerogel network. Additionally, the pH value of the reaction system has a strong impact on the microstructure and properties of prepared SiO2 aerogel.

研究发现:微过量的甲酰胺,有利于高孔隙率气凝胶的合成;过量的乙二醇的引入不利于低密度气凝胶的形成;pH值对合成气凝胶的性质也有较大的影响。

Of, relating to, or containing gelatin.

凝胶的,与凝胶有关的,或包含凝胶

In thispaper, the characteristics of protein gelation formation were introduced by physical and chemical aspects.

从物理和化学方面阐述了蛋白形成凝胶的特点,蛋白凝胶的内在因素和外部因素,主要介绍蛋白的热诱导、酸诱导和酶诱导凝胶的形成及其影响因素。

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