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Mono-calcium phosphate, sulfuric acid and urea were used for simulating the crystallization of calcium sulfate in the reaction of phosphate rock and urea-sulfuric acid.

结果表明,与无尿素的结晶过程相比,尿素使出现结晶的时间延长了150%,但悬浮液密度增加50%,结晶在长度和宽度上均有所增加,特别是宽度上的增长超过50%。

The comonomer in the copolymer by cat247 is trend to isolated. A few amount of comonomer could make the melting point remarkably decreased and maintain the crystalline at a relative high level. This catalyst can be use to produce the material with low melting point and high intensity such as packing film with low hotsealing temperature. The copolymer by cat24 is characteristic of uniform comonomer distribution and low melting temperature and crystallinity. Therefore, this catalyst could be used to produce LLDPE and POE according the comonomer content; cat246 has a strong copolymerization ability, and the resultant polymer has relatively high blockiness. If this trend is strengthened by adjustment of polymerization condition, the polymer can be used as thermal plastic elastomer with random and crystalline blocks.

由于各个催化剂所产生的聚合物各具特点,所以其潜在的工业用途不同。cat247的产物中共单体趋于孤立分布,极少的共单体即可使熔点明显降低而结晶度仍保持较高水平,有利于制备低熔点、高强度的材料(如低热封温度的包装膜等)。cat24的催化聚合产物无规程度比较高,对降低熔点和结晶度都十分有效,通过控制产物中共单体含量的多少,可以生产LLDPE和POE;cat246共聚合能力强,且产物有嵌段倾向,通过调整聚合条件强化这一倾向后,可以用来生产具有无规-结晶嵌段结构的热塑性弹性体。

Then,the tradition manner of crystallization was evaporating and crystalline,but this paper made the other method . The salt-mixture solution of the disodium hydrogen phosphate and the monometallic odium orthophosphate was put in ethanol.

传统的结晶方法是通过加热蒸发结晶,而本文则采用了一种新的结晶方法,在精调后的正磷酸盐混合溶液中加入乙醇,由于正磷酸盐不溶于乙醇,就会使正磷酸盐溶液达到过饱和,再通过搅拌,析出晶体。

Primary crystal melting broadly overlapped with the melting of recrystallized species and contributed to the broad highest endotherm, which is the high endothermic peak.

对于结晶1h和3h的样品,二次结晶和主结晶的片晶尺寸分布都随老化时间向高尺寸区域移动,说明老化过程可以使片晶更加完善。

After the deformation will enlarge the fine grains of the mylonite and at the same time will produce some new minerals. Thus, this will turn the mylonite into various crystallined schist.

随着片形后重结晶的增高,糜棱岩中的细小颗粒因重结晶而增大,并有一些新生矿物出现,使糜棱岩转变形成各种结晶片岩。

The experimental results indicate that when introducing XT-β nucleator into PP, the size of spherulite of the specimen obviously reduces and there appear typical characteristic diffraction peaks of β crystal form in the wide-angle X-ray diffraction pattern....

结果表明:在PP中引入XT-β晶型成核剂后,试样的球晶尺寸明显减小,广角X射线衍射谱图出现了典型的β晶型特征衍射峰;试样的结晶速率、结晶温度明显提高,差示扫描量热法谱图出现α晶型、β晶型2个熔融峰,β晶型含量达到总结晶量的50%~80%;XT-β晶型成核剂可使体系保持较好的力学性能,PP负荷下热变形温度提高15~40℃。

Avrami and Ozawa equations were used to analyze the experiment data in this study. Because the melting point of PBS is high and the mechanical properties are worse. In addition, the PTS is uncrystallized. Therefore, PBS and PTS were mixed to improve their properties. PBS containing 5wt% PTS can be able to reduce the crystallization performance, and make the polymer strength to enhance. Furthermore, the brittle fracture situation of PBS is also improved simultaneously.

本研究运用等温结晶分析使用的Avrami 方程式以及Ozawa 方程式,分析实验所得的数据,因为PBS 的熔点较高,机械性能较差,加上PTS 几乎不结晶的特性,因此将PBS 及PTS 以不同比例混掺的方式,对PBS 进行分析研究,结果发现,加入5wt% PTS的共聚酯能够明显的降低结晶性能,进而使聚合物的拉伸强度提高,同时脆性断裂的情况也得到改善。

Results of DSC determinations show that an adequate content of atactic polystyrene is favourable of the crystallization of isotactic polystyrene,but the addition of more aPS linearly decreases the crystallinity of iPS because of the dilution effect.

DSC测定表明,产物中的无规物有利于等规聚苯乙烯结晶,但对结晶的熔点有降低作用。向产物加入更多的aPS则由于稀释效应而使iPS的结晶度线性下降。

It is shown that deformation temperature is the main factor that influences the static recrystallization behavior. Carbonitride precipitation inhibits recrystallization and causes a plateau in the softening ratio curve. The static recrystallization activation energy of X80 pipeline steel was regressed and calculated to be 380 kJmol^(-1), and its rationality was also discussed according to previous references and investigations.

结果表明:变形温度是影响奥氏体静态再结晶行为的主要因素;微合金碳氮化物的析出抑制了再结晶的进行,使软化率曲线出现了平台;利用实验结果回归计算出了X80管线钢的静态再结晶激活能为380kJmol^(-1),并根据文献研究讨论了结果的合理性。

Experience shows that the introduced magnetic field can give an effective intervention to the transition of droplet, flowing of molten bath metal, crystalline and nucleation of molten bath and the process of crystalline growth. The magnetic field promotes the refining degree of primary crystallization structure , decreases the chemistry non-homogeneity, So it can strengthen hardness and wearing resistance of weld metal overlay and improve quality of surfacing deposit.

实践表明,利用外加磁场对焊接中熔滴的过渡、熔池金属的流动、熔池的结晶形核及结晶生长等过程有显著作用,使堆焊层的一次结晶组织细化,控制硬质相的分布,减小化学不均匀性,从而提高了堆焊层金属的硬度和耐磨性,全面改善堆焊层的性能。

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