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And has very high thermal and hydrothermal stability. When it is used to prepare catalyst, under catalytic cracking condition, the output rates of ethylene and from ethylene to butylene can reach more than 18% and more than 50% respectively.

该分子筛的结构和活性中心具有很高的热和水热稳定性,它的最显著的特点是,用其制成的催化剂在催化热裂解条件下,乙烯产率可达18%以上,乙烯~丁烯产率可达50%以上。

Thermal simulation experiments has carried out on mudstone,marlite and limestone,three kinds of typical Ordovician source rock samples,from foreland basin of western Ordos,not only revealed the evolve process and characteristics of hydrocarbon generation indoors but also provided important parameter for calculation the amount of hydrocarbon generation in this region.

通过对鄂尔多斯盆地西缘奥陶系3类代表性的烃源岩即泥岩、泥灰岩和灰岩进行热模拟试验,不仅在室内再现了各类岩样的生烃演化过程及特点,而且为该地区生烃量计算提供了重要依据。试验结果表明,泥岩的生烃能力最强,最终产气率达527 m3/tTOC,泥灰岩次之,最终产气率为512m3/tTOC,纯灰岩最差,最终产气率仅267 m3/tTOC;气态烃的产出与热成熟度密切相关,较高的热演化程度对气态烃的生成是有利的。

The temperature effect on the oil yield was discussed at first. Then, analytical work was carried out as follows: the ultimate analysis and physi-chemical analysis of the pyrolytic oil comprised a sketch of the fuel properties of the oil; Then, through the distillation analysis of the oil, the fraction composition of the "unrefined"oil was known. After that, a general knowledge of the aromaticity and saturation of the hydrocarbons in the oil was provided by the outcome of the FT-IR functional group analysis. Also, from the analysis, the form of the polar functional groups and their distribution in different fractions of the oil were learned.

文中首先对不同热解温度下热解油产率进行分析讨论,然后,针对热解油品质进行了一系列分析:通过元素组成和理化特性的分析,对热解油作为燃料特性有了一个大致了解;通过实沸点蒸馏分析,得到热解油作为一种未提炼油的馏分分布,并为后续热解油馏分的细入分析提供了前提;通过对热解全油和各窄馏分的FT-IR官能团分析,对热解油的芳香性、不饱和性有了整体的了解,并且清楚了热解油中的极性官能团存在型式及其在热解油不同馏分中的分布。

The results show that: the functional groups in coal are the function of coal rank , and the yields of CO 2, H 2O and CO are related to the content of carboxyl, hydroxyl and other oxygen containing groups such as ether groups in coal, and Tar and CH 4 are related to the aliphatic CH, the char yields to the aromatic CH.

借助化学分析和FTIR光谱分析对我国煤化程度不同的18 种煤中官能团的研究表明:煤中官能团含量与煤化程度有关;煤中羧基、羟基及醚键等其他含氧官能团的含量与热解生成物CO2、H2O 和CO 的产率有关,脂肪—CH 的含量与甲烷和焦油的产率相关联,芳香—CH 的含量与热解半焦产率有关。

Amino-6-nitrobenzodifuroxan was prepared through a three-step reaction from starting material 3, 5-dinitrobenzoic acid:(1)3, 5-dinitroaniline (1) was synthesized from the reaction of DNBA and hydrazoic acid in inert solvent 1, 2-dichioroethane through Schmidt rearrangement with yield of 89.6%;(2) 1 was subjected to nitration to prepare pentanitroaniline (2) with yield of 51.1%;(3) The title compound was prepared from 2 and sodium azide in acetic acid through denitrogenation and then Schmidt rearrangement with yield of 86.8%, m.p.204℃~206℃.

以3,5-二硝基苯甲酸为原料经过3步反应合成了7-氨基6-硝基苯并二氧化吠咱:第1步反应,在二氯乙烷惰性溶剂中,DNBA与叠氮酸反应并发生Schmidt重排反应生成3,5-二硝基苯胺(1),产率89.6%;第2步反应,1在含100%硫酸的硝硫混酸中硝化生成五硝基苯胺(2),产率51.1%;第3步反应,2与叠氮酸反应,不经分离直接进行热解脱氮、Schmidt重排反应,得到目标化合物, m.p.204℃~ 206℃,产率86.8%。

The thermal property studies indicate that the mass loss of compound B was 54.39% at 242.2~750℃, and when the temperature was 1000℃, there was 25.11% char residue left, which showed that the title compound has a good thermal stability and char forming capability. Using acetonitrile as the solvent instead of trichloromethane or 1, 2-dichloethane gave higher yield. During the synthesis, the yield was very low when triethylamine was used as acid acceptor alone, and when a little amount of 4-dimethylaminopyridine was added at the same time, the yield could be 81%.

结果表明,所合成的化合物B的结构与预期的结构一致;热性能研究表明,化合物B在242.2~750℃质量损失为54.39%,1000℃时仍有25.11%的炭残渣,显示出优异的热稳定性和成炭性;在相同反应条件下,用乙腈作为溶剂的反应产率比使用氯仿和二氯乙烷为溶剂的高,并且在合成过程中,单独使用三乙胺作为缚酸剂时产率很低,而当同时加入少量4-二甲氨基吡啶时,产率可达81%。

The mechanism of thermal decomposition mechanism of nickel benzoate trihydrate in N 2 was studied by using TG,DTA,IR,MS and XRD.

用流变相反应法合成了苯甲酸镍,通过元素分析、红外光谱确定了组成,用热重分析和差热分析研究了它在氮气气氛中的热分解过程,并用红外光谱、质谱、X 射线衍射表征了热分解产

The Xiaoxinancha copper-gold deposit occurs in the upwarped zone rimming the Mesozoic volcanic basin, being of porphyry type; the Naozhi gold deposit occurs in the lifted block within the Mesozoic volcanic basin, belonging to porphyry epithermal transitional type; the Wufeng and the Ciweigou gold deposit, which are two epithermal deposits, exist in the fault zone within the Mesozoic volcanic basin.

小西南岔金铜矿床产于中生代火山岩盆地边缘的隆起带,属于斑岩型矿床;闹枝金矿床产于中生代火山岩盆地内的断隆块,属于斑岩-浅成热液过渡型矿床;五凤和刺猬沟金矿床产于中生代火山岩盆地内断裂带,属于浅成热液型矿床。

The yield of combustible gas increasesand the yield of tar as well as residue decreases with the increasing of pyrolysistemperature.

随着热解终温的提高,可燃气体产率增长,焦油产率和残渣产率则减少。

Then quality upgrading scheme was explored in order to solve the high content of sulphur and nitrogen in pyrolytic oil, low flash point as well. Yields of pyrolysis of scrap tires in a pilot-scale rotary kiln under 550℃were firstly summarized. Then elemental composition and physiochemical properties were analyzed on both pyrolytic crude oil and its fractions. Based on these researches, the feasibility that pyrolytic oil is used as fuel was discussed. From FT-IR spectra the functional group compounds were generally acquainted, and by column chromatography analysis chemical compositions were clearly known. Then through GC analysis the absolute content of BTX in pyrolytic crude oil was defined.

本文首先考察了中试回转窑550℃下的废轮胎热解产率及热解原油的元素组成和理化特性,对其作为燃料使用的可行性进行了分析;通过实沸点蒸馏研究了轻质、中质馏分热解油的基本特性:红外分析得出了有代表性馏分热解油的大致官能团组成形式,对热解油的强芳香性和部分不饱和性有了整体了解;化学族组成分析进一步了解了热解油内在化学族组成和含量,对热解油的内在性质有了更为深入理解;气相色谱分析对热解油中富含的苯、甲苯和二甲苯进行绝对定量,为热解油提取BTX化工原料的经济性提供了参考。

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