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In this thesis, a convenient and efficient synthesis of highly functionalizeddihydropyrido[2,3-d]pyrimidines via a double [5 + 1] annulation strategy startingfrom easily available α-alkenoyl-α-carbamoyl ketene--acetals 1 and cheapreagents (NH4OAc, DMF, and POCl3) has been developed.

本论文探索了一种简便有效的合成高度官能化的二氢吡啶并[2,3-d]嘧啶的方法,此方法由易得的α-乙酰基-α-氨基乙酰基二硫缩烯酮1和便宜的试剂(醋酸铵,二甲基甲酰胺和三氯氧磷)通过两步[5 + 1]加成而实现。

The photocycloaddition of 1-naphthonitrile (1-NpCN) and 2,3-dimethyl-2-butene in cyclohexane or benzene gave cyclobutane 3 primarily,but that of 2-NpCN gave azetine 6 asthe major and cyclobutane 5 as the minor product in low conversion photolysis.

在低转化光解情况下,1-萘甲腈(1-NpCN)和2,3-二甲基丁烯-2在环已烷或苯中的光环加成反应主要得到环丁烷3,但2-NpCN主要得到氮杂环丁烯6和少量的环丁烷5,三氟醋酸量增加抑制1-NpCN和DMB的光环加成反应,表明TFA与基态及单激发态1-NpCN生成非光反应的复合物,它也淬灭(1-NpCN-DMB)激基复合物。

The photocycloaddn. of 1-naphthonitrile (1-NpCN) and 2,3-dimethyl-2-butene in cyclohexane or benzene gave cyclobutane I primarily, but that of 2-NpCN gave azetine II as the major and cyclobutane III as the minor product in low conversion photolysis. The photocycloaddn. of 1-NpCN with DMB is retarded by increasing amts. of trifluoroacetic acid which is shown to form non-photoreactive complexes with ground state as well as with singlet excited state 1-NpCN. It also quenches the *(1-NpCN-DMB) exciplex.

在低转光解情况下,1-萘甲腈(1-NpCN)和2,3-二甲基丁烯-2在环已烷或苯中的光环加成反应主要得到环丁烷3,但2-NpCN主要得到氨杂环丁烯6和少量的环丁烷5,三氟醋酸量增加抑制1-NpCN和DMB的光环加成反应,表明TFA与基态及单激发态1-NpCN生成非光反应的复合物,它也淬灭^*(1-NpCN-DMB)激基复合物。

A second group includes those compositions, which include an organic polymeric binding material, eg, mixed cellulose esters of monobasic or dibasic acids such as cellulose acetate succinate; an addition-polymerizable ethylenically unsaturated compound, eg, vinylidene and vinyl monomers, preferably of the acrylic or alkacrylic ester type; eg, triethylene glycol diacrylate; and an addition-polymerization initiator which forms radicals under the influence of actinic radiation, eg, anthraquinone.

第二组包括那些作品,其中包括有机聚合物具有约束力的物质,例如,对一元或二元酸混合纤维素酯,如醋酸纤维素琥珀酸; 1此外,聚合ethylenically不饱和化合物,例如,偏和乙烯基单体,丙烯酸最好的或alkacrylic酯类型,如,三乙二醇二丙烯酸酯;和加成聚合引发剂的形式下光化辐射的影响自由基,例如,蒽醌。

A new heat storage material (CH3COONa·3H2O) with a phase change temperature of 55℃ and a sub-cooling temperature of less than 2℃ was developed. This sodium acetate trihydrate based material was obtained by a number of experiments for selecting proper nucleation catalysts and suspension mediums.

以三水醋酸钠(CH3COONa·3H2O)为蓄热基质,通过大量实验,遴选合适的抗沉淀剂和成核剂,配成相变温度约55℃、过冷度小于2℃的蓄热材料。

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