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Synthesis and application of 1, 1'-ferrocene P, N -ligands in enatio- and regio-selective palladium-catalyzed allylic substitution reactions

1， 1'-二茂铁膦氮配体的合成及其在不对称区域选择性钯催化烯丙基取代反应中的应用

This thesis focused mainly on studying the role of planar chirality in asymmetric catalysis, synthesizing novel ferrocene ligands and applying them to palladium-catalyzed allylic substitution reactions.

本论文主要是研究二茂铁平面手性在不对称催化反应中的作用，设计合成新型二茂铁配体及其在钯催化烯丙基取代反应中的应用。

A series of crosslinkable alternating polys containing pendant phenylethynyl groups were synthesized via aromatic nucleophilic substitution reaction. The resultant polymers show good solubility in ordinary organic solvents.

以耐高温高性能树脂-聚芳醚酮作为研究对象，从改善材料的加工工艺性及提高材料的使用温度出发，对含有苯乙炔基的交替共聚物进行了系统研究。

Then Doripenem came into the market in the July ,2005. We studied the synthesis of Doripemen.Firstly, we synthesized the chemical 2 from the starting material------o-hydroxylphenylacylamine through Reformastky reaction, alkylation, Diekmann reaction, enolization, esterification and etc. Secondly, we synthesized the chemical 3 from L — hydroxylproline through the protection of carboxyl, amidogen and hydroxyl group, reduction by NaBr, SN_2 substitution and Mitsumobu reaction.

我们以水杨酰胺为起始原料，经Reformatsky反应、烷基化、Diekmann环合、烯醇化、酯化等反应合成双环母核2；再从L-羟基脯氨酸出发，经酯化保护羧基、保护氨基、保护羟基、硼氢化还原酯得醇、Sn2取代和Mitsumobu反应等合成巯基侧链3；最后由化合物3经脱保护、水解得硫醇，和化合物2在二异丙基乙基胺的作用下缩合，最后Pd／C催化脱保护，历经16步反应最终得到产物多尼培南。

However, this amino acid substitution could have an effect on intramolecular interactions.

然而，这种氨基酸的替换却对分子内相互作用有影响。

In this paper,3-methoxy-5,6-diamino-2-nitropyridine was synthesized from 3,5-dichloropyridine by substitution,oxidation,nitration and ammoniation .

研究了以3-氯-5-甲氧基-2，6-二硝基吡啶为原料，通过甲氧化、硝化、氨化合成3-甲氧基-5，6-二氨基-2-硝基吡啶，该化合物的结构通过IR，1H NMR，MS和元素分析进行了表征，确认为目标化合物。

Through wide hybridization between wheat and Thinopyrum species, a lot of amphidiploid, addition, substitution and translocation lines were produced and many wheat cultivars were selected.

通过小麦与偃麦草的远缘杂交，创造了大批小麦一偃麦草双二倍体、异附加系、异代换系和易位系材料，选育了许多小麦新品种。

Using SDS-PAGE technique, HMW-GS of Thinopyrum were detected by analyzing Thinopyrum accessions, wheat-Th. elongatum 1E〓 substitution lines and wheat-Th. intermediam partial amphidiploid Zhong2. It was showed that the composition of HMW-GSs of Thinopyrum were distinctly different from which in wheat.

对偃麦草、二倍体长穗偃麦草1E中国春代换系、小麦—中间偃麦草部分双二倍体中〓高分子量谷蛋白亚基进行了SDS-PAGE分析，发现在偃麦草材料中存在不同于小麦的特异HMW-GS类型。

A pair of specific primers was designed from the sequenceand was used to amplify the genomic DNAs of Yangmai 5,6VS/6AL line,substitution line of 6V and amphidiploid of Triticum durum-Haynaldiavillosa.

根据该序列设计了一对特异引物，分别以感病对照扬麦5号，抗病6VS/6AL易位系，6V代换系，硬粒小麦-簇毛麦双二倍体及簇毛麦的基因组DNA为模板进行特异性扩增。

Blessed substitution for it was the Andalusian who produced the goods, levelling the score 69 minutes into the clash.

这是个幸运的换人，安达卢西亚人在第六十九分钟时扳平了比分。

I had a lovely dog named PiPi, he was one of my best friends.

我曾经有过一只小狗，它的名字叫皮皮，它很善良，它是我最忠实的朋友。

Newly ovulated mouse oocytes were cultured in the CZB medium supplemented with different concentrations of pyruvate before treated for activation or assayed for MPF activity.

我们猜测卵母细胞在不含丙酮酸的条件下老化的更快，并且卵丘细胞可能通过消耗不含葡萄糖的CZB中的丙酮酸从而促进卵母细胞老化。