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For lack of direct quantitative diagnostic methods to evaluate the function of SO and unavailable objective standards judging whether to remove or to keep SO, more importance has been attached to anatomy, pathological characteristics of SO, and the development of appropriate means for the diagnosis and treatment of SO dysfunction. Little was known about the physiology, regulation mechanism and pathology of SO, neurobiological enervation and etiological mechanism of SOD.

由于目前临床上对SO运动功能障碍缺乏直接、量化的诊断方法和有效的治疗手段,对于保留或废除SO也缺乏客观的指标,因而对于SO的结构功能、病变特点、发病机制和诊断治疗方法的研究越来越得到重视。

In the experimental tectum, the expression of GFAP in the right SO was higher than the expression of GFAP in the left SO during 1d-60d after after optic nerve damage. The expression of GFAP in the right SO was familiar with the expression of GFAP in the left SO during 85d after optic nerve damage, but the expression of GFAP in SO in the experimental tectum was higher than that in the normal tectum. The result of GFAP expression in the experimental retina and tectum showed that AStrocyte took part in the optic nerve regeneration and it might play an important role in optic nerve regeneration accidents.

在损伤1d后视网膜的神经纤维层和外核层外缘可见较为深的GFAP染色,在损伤3d后视网膜从内网层经内核层至外网层出现稀疏的垂直于视网膜长轴分布的线条状GFAP染色,随时间推移,伤后5d、7d、14d、28d上述染色进一步加深密集,到伤后60d和85d上述染色减弱,阴性对照的视网膜各层未见GFAP阳性染色;(5)正常鲫鱼视顶盖中在SO层内有较浅的黄棕色线条状GFAP染色,在SFGC层

In this study, sulfate radical concentration from 4 drip water points (PL1, PL2, SH, JG) in the Shihua cave have been monitored for three years, and those from the drip water point was monitored for two years. Drip discharges show three types of response to surface precipitation variations: rapid response, response with associated time-lag and stable. The results show that:(1) SO(superscript 2- subscript 4) concentration in rapid response drip water increases sharply during rain period and has a exponential relationship with drip rate;(2) in the drip water of lag response, SO(superscript 2- subscript 4) concentration has no significant incrcase during rainfall, but they show a increasing trend during a long-term monitoring;(3) SO(superscript 2- subscript 4) concentration at the stable drip site is low and has no obvious change during wet weason.

本文通过对石花洞洞穴4个滴水点(JG, SH, PL1和PL2)硫酸根浓度近3个水文年的分析测定,结果表明:响应降雨快的滴水点滴水SO(上标 2-下标 4)浓度升高幅度最明显,且滴水SO(上标 2-下标 4)浓度与滴率成指数关系;滞后响应降雨的观测点滴水SO(上标 2-下标 4)浓度雨季升高幅度不明显,但在长期观测期间有明显增加的趋势;对降雨没有响应的滴水点,其SO(上标 2-下标 4)浓度低且雨季没有明显变化。

SO〓 injury caused a reduction of water, chlorophyll and anthocyanidin, and pH values of the grapes injured by SO〓 were decreased and the intracellular acidification of flesh could be found. SO〓 injury also inhibited activities of SOD, POD and CAT, and deceased ASA contents. Hence the membrane lipid per oxidation was accelerated and the content of MDA and relative electrical conductivity were increased. Treatment of toxic dose of SO〓 increased respiratory rate, lowered activities of PAL and PPO.

与不耐SO〓的品种&红地球&相比,耐SO〓品种&巨峰&具有较高的pH值和较大的缓冲容量,较高的超氧化物歧化酶和苯丙氨酸解氨酶活性;受SO〓刺激后,耐SO〓品种&巨峰&的超氧化物歧化酶及苯丙氨酸解氨酶活性和酚类物质含量上升幅度大于不耐SO〓的品种&红地球&;长期处于SO〓伤害环境时,耐SO〓品种&巨峰&的过氧化氢化酶活性下降幅度低于不耐SO〓的品种&红地球&。

SO〓〓/M〓O〓 solid superacid was applied to the photocatalytic oxidation of organic pollutants for the first time. Porous SO〓〓/TiO〓 solid superacid catalysts with high specific surface area were prepared by sol-gel method. The photocatalytic degradation of bromomethane was used as model reaction. The influence of impregnation with H〓SOsolution on the structure of catalysts and their photocatalytic performance was systematically studied by using X-ray diffraction, X-ray photoelectron spectroscopy, N〓 sorption analysis applying BET method, UV-Vis diffuse reflectance spectroscopy, FTIR spectroscopy, O〓-TPD and photocatalytic activity measurement. The acidity of TiO〓-based catalysts was investigated by Hammett indicator method, NH〓-TPD and IR spectra of pyridine adsorbtion. The mechanism of superacidifing effects on photocatalytic performances such as the photocatalytic degradation rate of bromomethane, apparent kinetic constant and apparent quantum efficiency was discussed.The results indicated that SO〓〓 is combined with metal ions of TiO〓 in a chelating bidentate mode.

本文首次将SO〓〓/MxOy型固体超强酸催化剂用于光催化氧化有机污染物研究,采用溶胶-凝胶法制备了具有多孔性和大比表面结构的二氧化钛基固体超强酸光催化剂SO〓〓/TiO〓,以光催化降解溴代甲烷为模型反应,系统地研究了H〓SO〓浸渍处理对催化剂表面酸性及其气相光催化性能的影响,结合XRD、BET、XPS、FTIR、Hammett指示剂法、吡啶吸附红外光谱、NH〓-TPD、O〓-TPD、紫外可见漫反射光谱等多种表征手段,深入地讨论了超强酸化对TiO〓的改性机理,阐明了引起SO〓〓/TiO〓超强酸催化剂光催化降解溴代甲烷的转化率、表观反应速率常数和表观量子效率变化的本质原因。

The structural and photocatalytic properties of TiO〓 as well as surface acidity were greatly improved by sulfation. SO〓〓/TiO〓 solid superacid with Hammett constant Ho less than -12.14 was prepared by treating the TiO〓 with 1.0mol. L〓 sulfuric acid solution and then calcining at 450℃ for 3h. When compared to unmodified TiO〓, the SO〓〓/TiO〓 superacid catalyst exhibited higher anatase content, smaller crystal size, higher specific surface area, centralized pore size distribution, and the blue-shifted band edge of uv-vis adsorption spectra. Furthermore, the SO〓〓/TiO〓 superacid also showed excellent reaction activity and stability for CH〓Br photocatalytic decomposition even under the moist reaction conditions. The apparent quantum efficiency of SO〓〓/TiO〓 was 10 times of that of TiO〓 catalyst for the photocatalytic degradation of bromomethane. Therefore, the SO〓〓/TiO〓 superacid catalyst is promising for practical application in environmental remediation.It was found that both L and B acid sites exist on SO〓〓/TiO〓 photocatalyst while only L acid sites on TiO〓 photocatalyst. On the basis of experimental results, the synergistic model of superacidic centers was proposed for SO〓〓/TiO〓 photocatalyst to explain the photocatalytic behavior and the mechanism of superacidifing effects, assuming that the adjacent L and B acid sites induced by SO〓〓 comprise cooperatively the superacidic center on superacid photocatalyst. The group cooperation of the superacidic center could strengthen the surface acidity, increase surface acid sites and the adsorbtion of O〓, promote separation of photogenerated electron-hole pair, enhance the interfacial transfer of charges and reversibility of water adsorption. Consequently the excellent photocatalytic activity, reaction stability and resistibility to humidity of SO〓〓/TiO〓 superacid photocatalyst may attributed to the group cooperated effect of the superacidic center on the photocatalyst.

研究结果表明:SO〓〓与TiO〓表面的结合为螯合式双配位结构;TiO〓光催化剂表面经H〓SO〓浸渍处理后,提高了表面酸性,改善了催化剂结构和光催化性能,当H〓SO〓浸渍浓度为1.0mol.L〓、烧结温度为450℃时,可制得SO〓〓/TiO〓超强酸催化剂(H〓<-12.14),其结构和光催化活性得到明显改善,与TiO〓相比,SO〓〓/TiO〓光催化剂的锐钛矿含量高、晶粒小、BET比表面积大、孔径分布集中、光谱吸收边蓝移,具有优异的光催化氧化活性、稳定性及抗湿性能,光催化降解溴代甲烷的表观量子效率比TiO〓催化剂提高了一个数量级,是一种有实际应用前景的高效光催化剂;由此提出了SO〓〓/TiO〓超强酸催化剂表面集团协同作用的超强酸中心模型,认为在SO〓〓/TiO〓超强酸催化剂表面,由SO〓〓诱导的相邻L酸中心和B酸中心组成了集团协同作用的超强酸中心,其集团协同作用显著地增强了催化剂表面酸性、增大了表面酸量及O〓吸附量、促进了光生电子和空穴的分离及界面电荷转移,具有可逆吸附水的性能,是SO〓〓/TiO〓超强酸催化剂具有优异的光催化氧化活性、很好的活性稳定性及抗湿性能的重要原因。

The apparent quantum efficiency of SO〓〓/TiO〓 was 10 times of that of TiO〓 catalyst for the photocatalytic degradation of bromomethane. Therefore, the SO〓〓/TiO〓 superacid catalyst is promising for practical application in environmental remediation.It was found that both L and B acid sites exist on SO〓〓/TiO〓 photocatalyst while only L acid sites on TiO〓 photocatalyst. On the basis of experimental results, the synergistic model of superacidic centers was proposed for SO〓〓/TiO〓 photocatalyst to explain the photocatalytic behavior and the mechanism of superacidifing effects, assuming that the adjacent L and B acid sites induced by SO〓〓 comprise cooperatively the superacidic center on superacid photocatalyst. The group cooperation of the superacidic center could strengthen the surface acidity, increase surface acid sites and the adsorbtion of O〓, promote separation of photogenerated electron-hole pair, enhance the interfacial transfer of charges and reversibility of water adsorption. Consequently the excellent photocatalytic activity, reaction stability and resistibility to humidity of SO〓〓/TiO〓 superacid photocatalyst may attributed to the group cooperated effect of the superacidic center on the photocatalyst.

研究结果表明:SO〓〓与TiO〓表面的结合为螯合式双配位结构;TiO〓光催化剂表面经H〓SO〓浸渍处理后,提高了表面酸性,改善了催化剂结构和光催化性能,当H〓SO〓浸渍浓度为1.0mol.L〓、烧结温度为450℃时,可制得SO〓〓/TiO〓超强酸催化剂(H〓<-12.14),其结构和光催化活性得到明显改善,与TiO〓相比,SO〓〓/TiO〓光催化剂的锐钛矿含量高、晶粒小、BET比表面积大、孔径分布集中、光谱吸收边蓝移,具有优异的光催化氧化活性、稳定性及抗湿性能,光催化降解溴代甲烷的表观量子效率比TiO〓催化剂提高了一个数量级,是一种有实际应用前景的高效光催化剂;由此提出了SO〓〓/TiO〓超强酸催化剂表面集团协同作用的超强酸中心模型,认为在SO〓〓/TiO〓超强酸催化剂表面,由SO〓〓诱导的相邻L酸中心和B酸中心组成了集团协同作用的超强酸中心,其集团协同作用显著地增强了催化剂表面酸性、增大了表面酸量及O〓吸附量、促进了光生电子和空穴的分离及界面电荷转移,具有可逆吸附水的性能,是SO〓〓/TiO〓超强酸催化剂具有优异的光催化氧化活性、很好的活性稳定性及抗湿性能的重要原因。

I think I should have told you that I'm still yours so goodbye my love So Goodbye. I here the birds singing It's time to go so Goodbye my friends I thought, You would do but I was wrong Now, I see myself still left alone Now, I think I know where I belong Now, I don't want to let this life go on No more, no more So Goodbye Those bittersweet memories once so lovely So Goodbye, I'm gone So Goodbye Those pretty stary eyes once just for me So Goodbye, i'm gone

so good bye》再见\我想我应该告诉你,我仍属于你\别了,我的爱\再见吧\我听见鸟儿在歌唱\但是离别的时间已经来临\那么,别了我的朋友\我本以为我们能永远在一起,但,我错了\现在,我发现自己又被孤单的留下\现在,我想我知道自己归属何方\现在,我希望时间的小河停止流淌\永远、永远地停止\那么,再会吧,我必须得走了\别了,那双曾只属于我的水漾明眸\再会吧,我必须得走了

In range of 300℃~900℃, all the transition metal oxide catalysts could get high ammonia conversion, during the initial stages of the reaction, the SO〓 conversion is relatively low since the catalysts have not been sulfureted, but it increases gradually and attain constant with rising temperature and time continuance,〓 is better than other catalysts in reactivity and elemental sulfur selectivity; XRD indicates that, in the SO〓-SCR process, stable transition metal sulfide is generated which is very important to SO〓 reduction and transition metal sulfide probably is the active phase of catalyst, further the reduction of SO〓 by H〓 to H〓S is the limiting step of all process, then the activity is somewhat related to its lattice oxygen yet not so notable; XPS indicates that little sulfur on surface exists as S〓 in sulfate, showing that TiO〓 could restrain the generation of sulfate.

对于过渡金属氧化物催化剂的研究发现,在300℃~900℃范围内,不同的催化剂均可获得很高的NH〓转化率,反应初期由于催化剂还未硫化,所以SO〓的转化率较低,随着温度升高和反应时间的延续,SO〓的转化率逐渐升高并达到了稳定值;七种过渡金属氧化物中,以〓对于NH〓还原SO〓反应的活性和选择性最好;XRD结果表明在NH〓-SO〓反应后生成了稳定的硫化物相,硫化物对SO〓的还原过程具有重要作用,催化剂的活性相可能是过渡金属硫化物,而且在硫化物催化剂上进行的H〓还原SO〓生成H〓S的反应是整个过程的速率控制步骤,所以催化剂的活性与其自身的晶格氧的氧化还原能力有一定的联系,但关系不明显;XPS结果表明催化剂表面的硫大部分以过渡金属硫化物的形式存在,只生成少量的S〓,说明TiO〓催化剂能够较好的抑制硫酸盐的生成。

They Told Him Don't You Ever Come Around Here Don't Wanna See Your Face, You Better Disappear The Fire's In Their Eyes And Their Words Are Really Clear So Beat It, Just Beat It You Better Run, You Better Do What You Can Don't Wanna See No Blood, Don't Be A Macho Man You Wanna Be Tough, Better Do What You Can So Beat It, But You Wanna Be Bad Just Beat It, Beat It, Beat It, Beat It No One Wants To Be Defeated Showin' How Funky Strong Is Your Fighter It Doesn't Matter Who's Wrong Or Right Just Beat It, Beat It Just Beat It, Beat It Just Beat It, Beat It Just Beat It, Beat It They're Out To Get You, Better Leave While You Can Don't Wanna Be A Boy, You Wanna Be A Man You Wanna Stay Alive, Better Do What You Can So Beat It, Just Beat It You Have To Show Them That You're Really Not Scared You're Playin' With Your Life, This Ain't No Truth Or Dare They'll Kick You, Then They Beat You, Then They'll Tell You It's Fair So Beat It, But You Wanna Be Bad Just Beat It, Beat It, Beat It, Beat It No One Wants To Be Defeated Showin' How Funky Strong Is Your Fighter It Doesn't Matter Who's Wrong Or Right Just Beat It, Beat It, Beat It, Beat It No One Wants To Be Defeated Showin' How Funky Strong Is Your Fighter It Doesn't Matter Who's Wrong Or Right Just Beat It, Beat It, Beat It, Beat It, Beat It Beat It, Beat It, Beat It, Beat It No One Wants To Be Defeated Showin' How Funky Strong Is Your Fighter It Doesn't Matter Who's Wrong Or Right Just Beat It, Beat It, Beat It, Beat It No One Wants To Be Defeated Showin' How Funky Strong Is Your Fighter It Doesn't Matter Who's Wrong Or Who's Right Just Beat It, Beat It, Beat It, Beat It No One Wants To Be Defeated Showin' How Funky Strong Is Your Fighter It Doesn't Matter Who's Wrong Or Right Just Beat It, Beat It, Beat It, Beat It No One Wants To Be Defeated Showin' How Funky Strong Is Your Fighter It Doesn't Matter Who's Wrong Or Right Just Beat It, Beat It Beat It, Beat It, Beat It

They告诉他不您来周围 Do不想要看您的面孔,您更好消失在他们的眼睛的The火的和他们的词是真正地清楚 So敲打它,打了它 You改善奔跑,您改善做什么您能 Do不想要看血液,不是一强壮男子的人 You想要是坚韧的,更好做什么您能 So敲打它,但是您想要是坏的 Just敲打它,打了它,打了它,打了它没人想要被击败 Showin质朴强怎么是您的战斗机 It不重要谁是错误或不错 Just敲打它,打了它 Just敲打它,打了它 Just敲打它,打了它 Just敲打它,打了它 They是得到您,更好的事假,当您能时Do不想要是男孩,您想要是一个人 You想要停留活,更好做什么您能 So敲打它,打了它 You必须表示他们,您真正地不是害怕的 You是与您的生活的Playin,这不是没有真相或胆敢 They将踢您,然后他们打您, Then他们将告诉您它是公平的 So敲打它,但是您想要是坏的 Just敲打它,打了它,打了它,打了它没人想要被击败 Showin质朴强怎么是您的战斗机 It不重要谁是错误或不错 Just敲打它,打了它,打了它,打了它没人想要被击败 Showin质朴强怎么是您的战斗机 It不重要谁是错误或不错 Just敲打它,打了它,打了它,打了它,打了它 Beat它,打了它,打了它,打了它没人想要被击败 Showin质朴强怎么是您的战斗机 It不重要谁是错误或不错 Just敲打它,打了它,打了它,打了它没人想要被击败 Showin质朴强怎么是您的战斗机 It不重要谁是错误的或谁是不错 Just敲打它,打了它,打了它,打了它没人想要被击败 Showin质朴强怎么是您的战斗机 It不重要谁是错误或不错 Just敲打它,打了它,打了它,打了它没人想要被击败 Showin质朴强怎么是您的战斗机 It不重要谁是错误或不错 Just敲打它,打了它 Beat它,打了它,打了它

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