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Different aspects associating the DMAE-NHS-based CLIA were studied in this thesis,including synthesis of acridinium ester,chemiluminescent characteristics of DMAE-NHS,labelling antibody or streptavidin with DMAE-NHS,two-site sandwich chemiluminescent immunoassay for TSH,two-site sandwich chemiluminescent immunoassay involved biotin-streptavidin system for TSH,and competitive chemiluminescent immunoassay using biotin-streptavidin system for TLVThe desired acridinium ester,DMAE-NHS,was synthesized according to the reference method with some modifications.

目前国内尚未见有关DMAE·NHS的合成及其应用于CLIA的研究报导,本论文研究了吖啶酯DMAE·NHS的有机合成方法,DMAE·NHS的发光性能,DMAE·NHS及其与抗体偶联物的热稳定性,DMAE·NHS标记TSH单克隆抗体和链亲和素,TSH CLIA,TSH BAS-CLIA和TT_4 BAS-CLIA。

In this paper, the main work has been focused on the rare reported arsenomolybdates, and nine novel compounds have been synthesized. Sandwich arsenomolybdates:(NH_4)_(12)[Cr_2AsMo_7O_(27_2]·11H_2O (1)(NH_4)_(14)[Cu_2AsMo_7O_(27_2]·13H_2O (2) Double sandwich arsenomolybdates:(NH_4)_(12)Cu(H_2O)_4[As_2Fe_6Mo_(22)O_(85)(H_2O)]·19H_2O (3)(NH_4)_(15)[As_2CoFe_5Mo_(22)O_(85)(H_2O)]·16H_2O(4)(NH_4)_(14)Mn_(0.5)[As_2Fe_5MnMo_(22)O_(85)(H_2O)]·22H_2O(5) Cagelike arsenomolybdate:(NH_4)_(11)[AgAs_2Mo_(16)O_(54)]·9H_2O (6) Organic-inorganic molybdenum arsenate complexes:CuAs_6Mo_6O_(30{[Cu_4]_3[CuAs_6Mo_6O_(30)]}_2·6H_2O (7),[Cu_2]_3[As_3Mo_3O_(15)]_2·2H_2O (8)(NH_4)_(10){Cu(H_2O)_4}[AsMo_6O_(21)(O_2CCH_3)_3]_2·12H_2O (9)All of the above polyoxomolybdates were characterized by IR spectroscopy, TG-DSC, elemental analysis, and single-crystal X-ray analysis to identify their structures and chemical compositions.

本文选择目前报道尚少的砷钼杂多化合物为研究重点,合成了不同结构类型的九个新的杂多化合物:单夹心化合物:(NH_4)_(12)[Cr_2AsMo_7O_(27_2]·11H_2O(1)(NH_4)_(14)[Cu_2AsMo-7O_(27_2]·13H_2O(2)双夹心化合物:(NH_4)_(12)Cu(H_2O)_4[As_2Fe_6Mo_(22)O_(85)(H_2O)]·19H_2O(3)(NH_4)_(15)[As_2CoFe_5Mo_(22)O_(85)(H_2O)]·16H_2O(4)(NH_4)_(14)Mn_(0.5)[As_2Fe_5MnMo_22_O_(85(来源:AbcccBC论文网www.abclunwen.comH_2O]·22H_2O(5)笼状结构化合物:(NH_4)_(11)[AgAs_2Mo_(15)O_(54)]·9H_2O(6)有机配体修饰的化合物:CuAs_6Mo_6O_(30{[Cu_4]_3[CuAs_6Mo_6O_(30)]}_2·6H_2O(7) [Cu_2]_3[As_3Mo_3O_(15)]_2·2H_2O(8)(NH_4)_(10){Cu(H_2O)_4}[AsMo_6O_(21)(O_2CCH_3)_3]_2·12H_2O(9)对上述新化合物进行了瓜光谱分析、元素分析、热分析和X-射线单晶衍射测试,确定了它们的组成和结构,对部分化合物还进行了UV-vis及荧光光谱分析和循环伏安表征。

The main mechanical properties in warp and weft direction of the hollow integrated core sandwich composites were obtained by flatwise tensile, flatwise compression, double lap shear, four point bending experiments, and then the properties were compared with the honeycomb sandwich composites.

对整体中空夹层复合材料经、纬向的平拉、平压、双层剪切和四点弯曲等性能进行了实验研究,获得了该种材料的主要力学性能参数,并与类似的蜂窝夹层材料进行了性能对比。

The main mechanical properties in warp and weft direction of the hollow integrated core sandwich composites are obtained by edgewise tensile, edgewise compression, flatwise tensile, flatwise compression, double lap shear, and four point bending experiments. Some properties are compared with the honeycomb sandwich composites.

对整体中空夹层复合材料经、纬向的侧拉、侧压、平拉、平压、双层剪切和4点弯曲等性能进行了实验研究,获得了该种材料的主要力学性能参数,并与类似的蜂窝夹层材料部分力学性能进行了对比。

The similar formula of bending stiffness was given about the wooding sandwich construction and the formula can forecast the stiffness of sandwich construction.

结果表明:木质蜂窝夹芯材料的抗弯性能较原蜂窝纸板大大提高,给出的木质蜂窝夹芯材料抗弯刚度的近似公式可以预测夹芯结构的刚度。

The author made induction and arrangement and offer to the two sides of the Taiwan Straits civil engineering scientific and technical workers, in order to obtain "break the ice","adopt sb.'s strong points while overcoming one's weak points", prosperous both banks economic development, promote the common progress of science and technology from the "open-web truss structure" at the 80 middle decade last century, and "open-web sandwich plate structure" at the 90 middle decade last century, and "cast-in-place concrete hollow plate structures" at the beginning of the century, to "the reinforced concrete open-web sandwich reticulated barrel arch structures" recently.

从上世纪80年代中期开发的&空腹网架结构&、上世纪90年代中期的&空腹夹层板结构&到本世纪初期的&现浇混凝土圆孔空心楼盖结构&和近期(2006年)开发应用的&钢筋混凝土空腹夹层曲面网壳与筒拱结构&,进行归纳整理,奉献给海峡两岸土木工程科技工作者,以求&抛砖引玉&、&取长补短&,繁荣两岸经济建设,促进两岸科学技术共同进步。

Double-antibody sandwich method for determination of 2 price or value of more than two macromolecular antigen, but not for the determination of haptens and small molecules unit antigens, because of two points can not form the sandwich.

双抗体夹心法适用于测定二价或二价以上的大分子抗原,但不适用于测定半抗原及小分子单价抗原,因其不能形成两位点夹心。

But the airborne radomes mostly are sandwich shells, the finite element analyses of them deal with various knowledge such as thin shell、 sandwich shell、buckling、free vibration and random vibration theories.

而机载雷达罩多数是夹层壳结构,对它们进行有限元分析涉及到薄壳、夹层壳、稳定性、自由振动和随机振动等多方面理论。

The second part is about the modeling of the wing structure using the Finite Element Software ANSYS. The theory of sandwich plate is adopted to analyze the sandwich wing-shaped structure.

第二部份针对制作出的三明治翼型结构,使用复合材料三明治梁板的理论来分析,建立ANSYS有限元素分析模型。

The results indicate that, using the PCMTS cores as the actuators, an ideal deflection of the sandwich beam is generated and the vibration of the sandwich beam is suppressed effectively.

结果表明,利用PCMTS作为驱动元件,夹芯梁获得了比较理想的变形量,其振动也能得到较为有效的控制,因此是一种很有应用前途的驱动方式。

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