查询词典 red shift

The results showed that a red-shift of the maximum absorption took place when the delocalization of the π electrons in the organic molecules increases.

计算结果表明，随着有机分子的π电子离域结构的增大，最大吸收峰红移。

The red shift is produced not only by the Doppler Effect, but also by the gravitational field .

除了多普勒效应产生的红移外，在引力场的影响下也会产生红移。

Under the wind fairing is a large tachometer with red shift point light.

在风展览会之下是有赤字的变化一个大的转速计点光。

The complex has a maxmium absorption at 480 nm with 9 nm of red shift compared to fluorescein itself.

研究了在生理条件下，荧光素与牛血清白蛋白相互作用形成复合物，最大吸收峰的波长480nm ，比荧光素红移9nm。

The FTIR of the C03O4 nanopowder exhibits red shift and wider, the reason is also discussed from the bond length and the hydrogenous bond.

纳米Co_3O_4晶体的红外吸收谱存在红移和宽化现象，定性地解释了红外吸收谱存在红移和宽化的原因。

The conclusions were as follows: theνO-H andνC=O IR absorption maxima shifted towards higher wave numbers after imprinting 17β-estradiol on TFMAA-co-TRIM copolymer with the red shift of theνO-H groups being apparent after precipitation polymerization for 16h while that forνC=O groups being observed after polymerization for 24h. A strong interaction between TFMAA and 17β-estradiol was confirmed by the high selectivity for 17β-estradiol, as indicted by the values of the separation factor of isomers of 17β-estradiol/17α-estradiol (2.28) and the imprinted factor (3.01). Particle diameter of TFMAA-co-TRIM polymer was between 300 nm and 1.5μm, which suited well for solid phase sorbent throughout at low column pressure. The recognition of imprinting TFMAA-co-TRIM polymer for sterol molecules was driven by enthalpy eluted with acetronitile, and low temperature was in favor of the separation of sterol structure analogues on imprinting column. TFMAA-co-TRIM polymer possessed of determinate anti-heat stability, with melting point beginning at 255.84℃, Tp=257.40℃, control TFMAA-co-TRIM polymer and imprinting TFMAA-co-TRIM polymer were respectively decompounded at 267.79℃and 343.11℃, and solid micro-extraction noddle prepared by the special polymerization also showed definite recognition for 17β-estradiol by GC/MS detecting at 270℃. By selection of various washing and elution solvents, elution reagents of close polymerization system were of more advantage in template molecules retention and recognition on molecularly imprinted solid phase extraction column. At a certain extent, progesterone, 17α-estradiol, 17β-estradiol and 4-androstene-3, 17-dione could be intercepted on the MISPE column. Especially, MISPE had high selectivity for progesterone, and imprinting TFMAA-co-TRIM polymer could achieve adsorption balance within 50 min by absorption kinetics test for 17β-estradiol. However, MISPE column showed better selectivity and enrichment property for 17β-estradiol than C18 and CSPE columns according to the data from HPLC and GC/MS analyses. Recovery of 17β-estradiol on MISPE column was up to 85.5% while when prime extracting solution of milk powder was sampled, the recovery of CSPE and C18 columns were 43.7% and 30.7%, respectively.

通过研究阐明：紫外聚合产物TFMAA-co-TRIM中的νO-H振动吸收峰在聚合16h后红移，νC=O振动吸收峰在聚合24h后红移；TFMAA-co-TRIM对雌二醇异构体的印迹因子达到了3.01，α为2.28，优于其它功能单体参与得到的聚合物识别特性；TFMAA-co-TRIM聚合物粒径介于300 nm至1.5μm之间，作为色谱固定相具有良好的通量和低的柱压；在乙腈流动相中，TFMAA-co-TRIM分子印迹固定相的分离过程主要被焓驱动，低温有利于分子印迹固定相分离甾醇结构类似物；TFMAA-co-TRIM分子印迹聚合物在255.84℃时开始熔融，Tp=257.40℃，聚合物CP的降解温度在267.79℃，MIP降解温度在343.11℃，制备的固相微萃取头初步经GC/MS 270℃的耐热性测定；不同的洗提溶剂筛选证明了选择接近聚合溶剂的洗脱体系更有利于MISPE发挥识别效应；分子印迹固相萃取柱对孕酮、17α-雌二醇、17β-雌二醇和雄烯二酮都具有不同程度的保留特性，可作为此类化合物的吸附材料，特别对孕酮强保留的富集特性，可作为孕酮的选择性识别吸附剂，其分子印迹聚合物对17β-雌二醇的吸附动力学测定显示在50 min内基本达到吸附平衡，具有作为传感器核心敏感材料的潜力；对比萃取奶粉中17β-雌二醇性能，MISPE柱比非分子印迹固相萃取柱和C18柱具有更高的保留，回收率依次为85.5%，43.7%和30.7%。

From comparison with poly(2,7-fluorenylene), the 1,2-bis( p -phenylene)-1-cyanovi- nylene unit was found to be a good electron-withdrawing moiety for electronic materials and the incorporation of 1,2-bis( p - phenylene)-1-cyanovinylene resulted in a narrow band gap and a red shift of both the absorption and photoluminescence emission peaks.

通过与聚芴对比，发现对于电致发光材料来说，由于氰基的强吸电子能力使得氰基亚乙烯基成为一个很好的吸电子基团，与之结合使得能隙变窄，吸收和发射光谱发生红移。

The main results are as follows.1. The UV-visible absorption spectra, the spin-trapping EPR measurements, and the DPA (9,10-diphenylanthracene) bleaching experiments showed that (1) HB-Net exhibits much improved light harvesting efficiency in the phototherapeutic window (600-900 nm) as the result of its remarkable absorption red shift with respect to HB;(2) HB-Net remains the generation abilities of semiquinone anion radical, superoxide anion radical, hydroxyl radical, and singlet oxygen, but with much lower efficiencies than that of HB, most likely due to its very short triplet excited state lifetime.

设计合成了寡聚吡咯酰胺修饰的竹红菌乙素衍生物HB-Net，利用紫外-可见吸收光谱、自旋捕获技术和DPA光漂白法详尽比较了HB-Net与HB的光动力性质，发现：(1) HB-Net的吸收光谱较HB有显著红移，在光疗窗口的吸光能力明显提高；(2) HB-Net能够产生半醌负离子自由基、超氧负离子自由基、羟基自由基和单重态氧，但由于其短的三重态寿命，这些活性物种的产生能力均弱于HB.2。

It was also found that the absorption wavelength s of porphyrin and magnesium porphyrin had the general red shift.

计算结果表明溶剂环境中氢卟啉和镁卟啉分子的电子吸收光谱发生了普遍的红移，结合分子轨道理论对这种变化给出了可能的解释。

So it is obvious substituent of large conjugation will lead to red shift of the corresponding absorption wavelength.

显然最大吸收峰会随着侧链共轭程度的增大而红移。

But Severus escaped the hands of those that Julianus had sent to murder him and sent a letter to the praetorian guard, giving them the signal either to desert Julianus or to kill him.

赛维鲁总算逃过了尤利阿努斯派来的杀手，并写了一封信给罗马的禁卫军，向他们发出信号，要么抛弃尤利阿努斯，要么干掉他。他们立即服从了。

This text is in terms of this of " human nature ", it is under the influence of western literature human nature thought to probe into, awakening in human nature of novel works and all sorts of limitations that affectionate The school of Mandarin Duck and butterfly.

本文便是从"人性"这一角度，探讨在西方文学人性思想的影响下，清末民初鸳鸯蝴蝶派的言情、哀情小说作品在人性方面的觉醒与种种局限。