查询词典 radical function

The investigation also showed that, the antioxidants with same action mechanism, for example, as both radical scavengers, phenol and amine antioxidants are synergistic; but the synergistic effects between two antioxidants with different action mechanism, such as radical scavenging phenol and amine antioxidants, and hydroperoxide decomposing ashless dithiocarbamate, are much stronger, and the heterosynergism between dithiocarbamate and alkylated diphenylamine is outstanding, which can serve as high temperature ashless high performance antioxidant combination; the heterosynergism among three antioxidants with three different action mechanisms, for example, the tri-component combination of alkylated diphenylamine, zinc dithiocarbamate and organic molybdate ester, can achieve excellent antioxidation performance.

研究还表明，具有相同抗氧机理的不同抗氧剂，如酚类和胺类抗氧剂，具有协同作用；不同作用机理的两抗氧剂之间，如自由基清除剂和氢过氧化物分解剂，具有更好的抗氧化协同效果，其中，无灰氨基甲酸酯与烷基化二苯胺抗氧剂具有最佳的抗氧协同效能，可成为高温无灰抗氧剂应用的一个很好选择；不同抗氧机理的三种抗氧剂复合，如烷基化二苯胺，氨基甲酸锌和有机钼酸酯组成的三元复合抗氧剂，具有更为优秀的抗氧化性能。

Part 7 is the conclusion of this paper.The main research in this paper includes:1 The 22 mixed ligand complexes were synthesized in which bipyridine-, phenanthroline 5-nitrophenanthroline , phenanthroline- 5,6-dikentone and biquinoline are the first ligand and chlorine ion phenylalanine, tyosine asparagic radical 2.6-diaminocaproic radical tryptophan , histidine malonate(mal2-) benzyl malonate (bmal2-) phenethtyl malonate (pmal2-) are the second ligand.

本文具体研究内容包括四部分：一、合成了以联吡啶、邻菲啰啉、5—硝基邻菲啰啉、邻菲啰啉-5，6-二酮、联喹啉为第一配体，以Cl~-、苯丙氨酸根、酪氨酸根、天冬氨酸根asp~(2-、赖氨酸根、色氨酸根、组氨酸根、丙二酸根mal~(2-、苄基丙二酸根bmal~(2-和苯乙基丙二酸根pmal~(2-为第二配体的共22个混配配合物，制备了其中6个混配配合物和1个单配体配合物单晶，用X-射线单晶衍射法测定了晶体结构。

Next HOMO or HOMO-1 for the radical cations calculated by the ab initio 3-21+G^* method, and the atom-pair interaction energy determined by NMDO calculation, it is shown that when n is equal to or largey than 3 in the bridge chain (CH2)n for bicyclo diamine radical cations, the bridgehead nitrogen atoms form a weak N, N'-three-electron σ-bond through space.

通过比较这些阳离子几何构型，HOMO和NHOMO(即NextHOMO和HOMO-1)，和由MNDO计算确定的原子对作用能，表明当二氮双环游离基阳离子的桥链(CH2)n的n≥3时，桥头氮原子通过空间相互用用形成了一个弱的N，N'-三电子σ键。

The total contents of phenol compounds of fresh Boehmeria nivea root was 200.24± 0.93 mg/g, which is 4.5 times higher than ethanol extracts of fresh Boehmeria nivea leaf, and its ability to remove ABTS free radical is 7.4 times higher than that of fresh Boehmeria nivea leaf, which is one third of Trolox's ability to remove free radical. Antioxidant components of hot water extracts of Boehmeria nivea leaf exhibited 55 and 67% lower than that of fresh leaf respectively.

sulfonic acid］和DPPH(α，α-diphenyl-β-picrylhydrazyl)自由基为最高，其次为热水萃取物和冷水萃取物，而新鲜苎麻根乙醇萃取物总酚类含量为200.24 ±0.93 mg/g，约高於新鲜苎麻叶乙醇萃取物的4.5倍，其清除ABTS自由基能力是新鲜苎麻叶乙醇萃取物的7.4倍，约为维生素衍生物的1/3倍。

For the DPPH free radical scavenging, their EC50 values are 19.05 mg/ml and 15.61 mg/ml respectively, but their anti-oxidant capacities are 40 to 60 % higher than fresh ones. Hot water extracts of Boehmeria nivea root experienced sun dry treatment have a better ability to scavenging ABTS free radical (EC50=34.16 μg/ml)when compared to that of fresh root, which only have one tenth anti-oxidant ability left.

经冷冻乾燥和日晒乾燥的苎麻叶热水萃取物其抗氧化成分较新鲜者低约55至67 %，而对DPPH自由基清除能力其EC50分别为19.05 mg/ml和15.61 mg/ml，相对其抗氧化能力却较新鲜者为高约40至60%；经日晒乾燥苎麻根热水萃取物其清除ABTS自由基能力(EC50=34.16 μg/ml)明显较新鲜者为高，显示其清除自由基能力只剩1/10。

The first part of this research was to investigate anti-oxidant abilities of Boehmeria nivea leaf and root. Different extraction methods, drying conditions as well as far infrared were applied to measure their effects on anti-oxidant abilities of Boehmeria nivea leaf and root. Results showed that 95% ethanol extracts of fresh leaves and roots demonstrate the highest anti-oxidant components(total contents of phenol compounds and flavonoids)and scavenging abilities free radical scavengingABTS(2,2'-azinobis［3-ethylbenzothiazoline-6- sulfonic acid］and DPPH (α,α-diphenyl-β-picrylhydrazyl) free radical , followed by hot water and cold water extraction.

本研究第一部份拟针对苎麻叶与根探讨其抗氧化能力，并以不同萃取方法、不同乾燥处理方式及经远红外线照射对其抗氧化能力之影响，研究结果显示，在不同萃取方法中，新鲜苎麻叶与根皆以95%乙醇萃取物的抗氧化成分及抗氧化能力清除ABTS(2，2'-azinobis［3-ethylben-zothiazo-line-6

A new method was developed for detection of the hydroxyl radical in Fenton reaction by bromocresol green oxidative assay. After oxidized by hydroxyl radical, the absorbance of bromocresol green is decreased apparently.

利用Fenton反应产生的羟基自由基与染料试剂溴甲酚绿(Bromocresol green， BG)发生氧化反应后使其吸光度值降低，建立了一种可间接测定羟基自由基的新方法。

The experiments for determining the mechanism and kinetics of catalytic pyrolysis reaction for a simple petroleum feedstock, were carried out in a batch micro-reactor using Daqing light gas oil. The results showed that carbonium and free radical reactions were the key reactions in catalytic pyrolysis. The carbonium ions were induced by catalytic reaction, whereas free radical reaction was predominantly due to thermal cracking.

首先在重油微反装置上考察大庆减压馏分油催化裂解反应产品分布，并将反应结果与相同温度范围内的热裂解反应相比较，二者的产品分布随温度等操作参数的变化规律明显不同，进而推断催化裂解反应过程为正碳离子反应机理和自由基反应机理并存；并建立了大庆减压馏分油催化裂解消失动力学模型，求得了化学反应速率常数。

VDF and TFE seemed to copolymerize in a random way. The growing polymer chain radical -CF2. or-CH2 . is strongly favored over the CH2 end of CH2 = CF2, and the growth of the chain radical-CH2. trended towards CF2=CF2 in the copolymerization of VDF and TFE.

偏氟乙烯和四氟乙烯以无规共聚进行反应，在共聚反应中的链自由基CF2·或CH2·容易增长于CH2=CF2的CH2端，而链自由基CH2·在偏氟乙烯和四氟乙烯共聚反应中的增长倾向于四氟乙烯。

CPDA dissociates into a cumyl radical and a phenyl dithioester radical.

cpda游离成基自由基和苯硫酯自由基。

The studies on the developing of new media are very important to the increasing of the area density of HDD and to the implementation of hybrid recoding technology.

光磁混合记录方法，是一种可以突破超顺磁极限的限制，并进一步提高硬盘记录密度和读写速率的一种新型超高密度信息存储方式。

In io, mTOR inhibition promotes T cell anergy under conditions that would normally induce priming.

体内研究中，在正常可激发免疫反应的条件下，抑制mTOR可促使T细胞无能。