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In order to explore the latent toxicity of ionic liquid, multi-spectrum methods were used to study the interaction between imidazole ionic liquids and BSA.

为探讨离子液体的潜在毒性,采用多种光谱手段研究了咪唑型离子液体与BSA的相互作用。

Though recently ionic materials composed of DNA and polyether-derivatized transition metal complexes were reported, dissolution of proteins and carbohydrates in ionic liquids is generally hindered by their insolubility.

虽然最近离子材料组成DNA和聚醚衍生物过渡金属配合物的报告,溶解蛋白质和碳水化合物的离子液体通常是阻碍其insolubility 。

The ionic exchange process is the key part of the abstraction shop in VC production line, Intermittent static ionic exchange bed was used now, But some problem need to be resolved that the entity resin utilization ratio is low, The operator make more error and materiel were expended more.

在VC生产过程中,离子交换工序是提取车间的关键工序,目前使用的是间歇式固定床离子交换设备,存在树脂利用率不高、人为失误多、物耗高等问题。

Studies show that the ECMI method produces most accurate potentials for these ionic states, and that the ECMI not only obtain accurate potentials near equilibrium internuclear distance, but also generate correct potential data in the ionic asymptotic and dissociation region where other methods may fail or may give less accurate results.

将获得的ECMI势能曲线与用其他理论方法得到的势能曲线进行的比较表明,ECMI得到了这些态的最好势能,而且ECMI势不仅能获得平衡核间距附近的精确势能,还能得到其他方法往往难以得到的双原子分子离子渐进区和离解区的正确势能。

The results show that the calculated cell parameters are in agreement with the experimental ones. The interactions between Li—N and Al—N are strong ionic bonds in Li3AlN2. The interaction between N and H is strong covalent bond and the interaction between Li and N is strong ionic bond in LiNH2. The calculated reaction enthalpies are 23.7 and 55.3 kJ/mol, respectively, which are in agreement with the experimental ones.

结果表明:Li3AlN2的Li—N、Al—N键主要为离子键,LiNH2的N—H键主要为共价键,Li—N键主要为离子键;298 K时贮氢反应的反应焓计算值分别为23.7和55.3 kJ/mol,与实验值均符合得较好;反应中各固态、气态物质的晶胞的结构优化后的晶格常数、键长与键角等与相应的实验值均符合较好。

Based on the experimental results reported in literature, the dissolution and separation performance of ionic liquids for lignin, cellulose and hemicellulose are summarized. The relationship between structure of ionic liquids and their dissolution performance is analyzed, and the possible dissolution mechanism is discussed.

根据目前所报道的研究结果,总结了不同离子液体对木质素、纤维素、半纤维素的溶解作用以及对木质纤维素的分离性能,分析了离子液体的结构与其溶解性能的关系,讨论了可能的溶解机理。

The influences of alkali concentration, temperature, polymer and additive on ionic conductivity and electrochemical stability were studied with orthogonal experiments and single factor experiments design, the relation of structure and ionic conductibility is researched by FIRT, XRD,DSC and SEM analysis ways.

结合正交设计实验和单因素实验研究了碱浓度、温度、聚合物以及增塑剂对固体电解质离子电导率、电化学稳定性的影响,用红外光谱、X衍射分析和差热分析等手段研究其结构与离子导电性能的关系,摸索出了本实验条件下的最优方案。

A novel ionic liquid Caprolactam-trifluoromethanesulfonic acid was prepared with trifluoromethanesulfonic acid and Caprolactam as raw material. The structure of the ionic liquid was characterized by 1HNMR and FTIR.

以三氟甲磺酸和己内酰胺为原料制备了一种新型离子液体己内酰胺三氟甲磺酸,用1HNMR、FTIR对其结构进行了表征。

The effects of aggregation structure and porous structure on ionic conductivity and electrolyte uptake were investigated.The experimental results showed that compared with PVDF system,PVDF-HFP system has higher ionic conductivity(2.93×10-3S/cm,20℃) and better electrolyte maintenance,logσand 1/T followed VTF equation.

计算表明,无定形区对体系的吸液率的贡献为50~60%,对电导率的贡献为30~40%,这说明载流子在被电解液溶胀的无定形区中的迁移不能忽略。

The main content of this paper as follows: The acidic strength, reaction temperature, reaction time of Chlorine-aluminate Ionic Liquids with different structure of cation on the activity of transalkylation of MN with TeMB and the selectivity of 2,6-DMN were studied. The optimum reaction condition was obtained: the molar fraction of AlCl_3 is 0.71, molar ratio of 2-MN and TeMB is 1, the amount of ionic liquid is 32wt%, reaction temperature is 20℃and reaction time is 8h using X-xAlCl_3 and X-xAlCl_3 as catalysts; the optimum reaction time is shortened 6h using Et_3NHCl-xAlCl_3 as catalyst.

本文主要研究了以下内容:分别考察了不同阳离子结构的氯铝酸盐类离子液体的酸强度、反应温度、反应时间等因素对MN和TeMB转移烷基化的催化反应活性和2,6-DMN选择性的影响,优化得到适宜的反应条件为:以X-xAlCl_3和X-xAlCl_3为催化剂时,AlCl_3的摩尔分数x=0.71,2-MN和TeMB摩尔比为1∶1,离子液体用量为32wt%,反应温度为20℃,反应时间为8h;以Et_3NHCl-xAlCl_3为催化剂时,反应时间缩短到6h。

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