查询词典 elemental algorithm

Based on the problem of various types of catalyst and according to the features of carbonylation catalysts reactions, our team has been designed a series of new metal complexes of benimidazoles, which can be used for carbonylation catalyst of industry. Seven new benzimidazole derivatives were prepared by the o-phenylenediamine、oxalic acid、glycolic acid、monomethyl monopotassium malonate、ethyl cyanoacetate、succinic anhydride. The structures of them were confirmed by IR、Elemental analsis. The crystal structures of d and e were determined by X-ray single crystal diffraction of Germanic Bruker Smart APEX II CCD. The catalysis of them was tested by carbonylation reactions.

本文设计以邻苯二胺和草酸、羟基乙酸、丙二酸单甲酯、氰基乙酸乙酯、丁二酸单甲酯为原料采用PPA催化和无机酸催化法，合成了4种苯并咪唑-2-羧酸衍生物并进行了表征；培养了2个化合物d、e的晶体并测定和讨论了晶体结构；制备了3种未见报道的苯并咪唑金属配合物，对配合物在羰基化法制醋酐-醋酸反应的催化作用进行了初步试验。

Chapter four. Two glucosamide-based trisiloxane Gemini surfactants which were connected with the short carbon chain dialcohol diglycidyl ether spacer were synthesized and their properties were determined. These compounds were structurally characterized by their 1H and 13C NMR spectra and elemental analysis.

界面性能通过K12表面张力仪测定，在临界聚集浓度CAC为1一3、10一5时可以显著地降低水的表面张力值至约21 mN/m，比连接基为低碳链二缩水甘油醚的略低，其CAC值随着乙氧基数的增加而增加，其CAC值比相应的单体低1~2个数量级，而且有两个CAC值。

Two oleanane type triterpenes were isolated from the crude drug Lu Lu Tong , the fruits of Liquidambar formosana and their structures were elucidated as 2α,3β dihydroxy 23 norolean 4(24), 12(13) dien 28 oic acid(1), 2α,3β,23 trihydroxyolean 12(13) en 28 oic acid(2), based on 13 C NMR, DEPT, 1H NMR, 1H 1H COSY, 13 C 1H COSY, IR, MS and elemental analysis.

从生药路路通分离得到2个齐墩果烷骨架的五环三萜类化合物。通过13CNMR，DEPT，1HNMR，2D1H－13CCOSY，2D1H－1HCOSY，IR，MS和元素分析阐明了它们的结构。（1）为2α，3β－二羟基－23－去甲－齐墩果－4（24），12（13）－二烯－28－羧酸，（2）为2α，3β，23－三羟基齐墩果－12（13）－烯－28－羧酸，（1）未见文献报道，（2）是首次从这一植物中分离得

These data were used to infer the molecular formula and the elemental compositions of all the fragmental ions through software interpretation and, by further applying fragmentation regularities of mass spectrometry, the majority of ions were fully assigned. A base peak at m/z 402 in the mass spectrum was found as the molecular ion. The fragments were created mainly from the fragmentations of the tetrahydrofuran rings and the hydroxyl group. The most fragment products contain the dimethoxy phenyl group.

利用这些数据通过软件导出了分子式和所有碎片离子的元素组成，由此进一步根据质谱裂解规律对石梓醇分子的电子轰击质谱的主要裂解碎片给出了完全的归属，质谱中发现基峰为分子离子峰(m/z402)，裂解碎片主要来自双骈四氢呋喃环的裂解和羟基引起的裂解，绝大部分裂解产物包含二甲氧基苯基基团。

Three new chromophores and 4 nitro benzoic acid 2 {4 [2 (4 dimethylamino phenyl vinyl] phenyl} ethylamino ethyl ester have been synthesized and the structures have been characterized by 1H NMR, IR and elemental analyses.

作者中文名：延云兴；陶绪堂；杨家祥；王东；于晓强；赵显；蒋民华摘要：合成了反式-4-[N-(乙氧基羰基-4-硝基苯基)-N'-乙基氨基]-4'-二苯乙烯和三个新有机化合物。

B. Three novel dimeric dissymmetric chiral ligands and six chain binuclear Salen complexes were synthesized and characterized by FT-IR,〓HNMR, Elemental analyses, UV-vis, furthermore the CD spectra properties of the ligands and complexes were discussed in detail for the first time.

合成了三个未见报道的链式双Salen配体和六个链式双核Salen金属配合物，通过核磁共振波谱、元素分析、红外光谱、紫外-可见光谱进行了表征，并首次详讨论了手性配体及配合物的圆二色光谱性质。

And the guiding principle, elemental thought, corresponding measures, suggestion for carrying out the resources saving, comprehensive utilization and building the industrial system of durably developing were given.

作者提出了今后山东工业开展资源节约和综合利用，建立可持续发展工业体系的总体指导思想、基本思路和相应的对策建议。

Firstly,two novel rare earth complexes(CH_2=CHO)Ln~Ⅲ[2,6-_2PhNSiMe _3]_2Li_3Ln=Y(2,Yb(3)containing arylamido and enolate mixed ligands have been synthesized by treatment of 2 equiv of of 2,6-~iPr_2PhNHSiMe_3 with exces n-BuLi at -78℃in THF for 12h,followed by reaction with 1 equiv of LnCl_3at 80℃for 24h in one-pot.All the two compounds were characterized by spectroscopic methods,elemental analyses,and a single-crystal X-ray diffraction study.

首先，-78℃下，在两当量的2，6-~iPr_2PhNHSiMe_3(1)THF溶液中加入过量的n-BuLi，反应12小时，再加入一当量的LnCl_380℃下，反应24小时，一锅法合成了含胺基、乙烯醇基混合配体的新型稀土金属配合物(CH_2=CHO)Ln~Ⅲ[2，6-_2PhNSiMe_3]_2Li_3Ln=Y(2、Yb(3)，上述化合物结构经单晶X-ray衍射、光谱和元素分析表征，表明我们得到的是一类新型的三价稀土配合物。

Three novel rigid compounds 3, 6-bis[2-(4-pyridylethenyl]-9-ethylcarbazole (L~1), 3,6-bis[2-(2-pyridyl)ethenyl]-9-ethylcarbazole (L~2), 3,6-bis[2-(4-pyridyl)ethenyl]-9 -ethylpyridylcarbazole (L~3) were successfully synthesized by Heck reaction, which were fully characterized by elemental analyses, NMR, MS, IR spectra and single X-ray diffraction analysis.

利用Heck偶联反应，成功地合成了三种新型刚性的吡啶基咔唑类化合物：3，6-二[2-(4-吡啶基)乙烯基]-9-乙基咔唑(L~1)，3，6-二[2-(2-吡啶基)乙烯基]-9-乙基咔唑(L~2)和3，6-二[2-(4-吡啶基)吡啶基]-9-乙基吡啶基咔唑(L~3)，通过元素分析、核磁共振谱、质谱、红外光谱和单晶X-射线衍射等分析手段确证了它们的结构。

The influence of the structure and property of Jinzhou coker heavy gatch on formation of needle coke was investigated by using elemental analysis, liquid chromatogram, FT-IR spectroscopy and molecular weight determination.

本文利用元素分析、液相色谱、傅立叶变换红外光谱、分子量测定等分析手段，研究了锦州焦化重蜡油的组成结构和性质对生产针状焦的影响，并通过与典型针状焦生产原料——锦州催化裂化油浆的比较，指出了锦州焦化重蜡油用作针状焦原料的不足。

Pachomius manual labour was organized as an essential part of the monastic life; and since it is a principle of the monks as distinguished from the mendicants, that the body shall be self-supporting, external work of one sort or another has been an inevitable part of the life ever since.

根据圣pachomius体力劳动组织作为一个重要组成部分寺院生活；以来，这是一个原则的和尚，作为有别于乞丐，该机构应自支撑，对外工作的这种或那种已一个必然的一部分，生活至今。

In order to study the effects of parametrical rolling on the ship movement and tilts, in allusion to ship's navigating in regular following waves, the equation of ship rolling motion is transformed into normal Mathieu equation by proper variable replacement when strong parametrical excitation in restoring moment varied according to sine or cosine wave.

为研究参数横摇对船舶运动和倾覆的影响，通过对船在规则波上随浪航行时，恢复力矩中出现的1个以正余弦规律变化的强参数激励项进行适当的变量置换，将船舶的横摇运动方程转换成标准形式的Mathieu方程。