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The other Cu were six coordinated H2O to form the octahedral geometry coordinated cation.

阴阳离子之间除了通过静电力相互作用外,还存在氢键作用。

The analysis results of crystal structure shows that the stoichiometric mononuclear Ni complex molecule C(subscript 37.5H45Cl2N10O12Ni was composed of two mononuclear Ni complex units {Ni[C35H33N10O](ClO4)2(CH3OH)2.5(H2O)0.5, Ni coordinated to the ligand to form hexacoordinated distorted octahedral configuration, and the orbital contribution and atomic net charge results has provided a good testimony for the coordinated condition in the crystal structure.

晶体结构分析表明,Ni单核配合物的化学经验式C37.5H45Cl2N10O12Ni的单胞中含有两个配合物分子{Ni[C35H33N10O](ClO4)2(CH3OH)2.5(H2O)0.5},Ni与配位原子形成六配位的扭曲八面体结构。ab从头算所得原子轨道贡献和原子净电荷布居分析结果与晶体结构中的配位情况相符。

In most of cobalt coordination polymers, Co ions are six-coordinated in an octahedral symmetry, whereas five-coordinated ones are seldom.

在大多数的钴配位聚合物中,Co离子是六配位八面体对称性,然而五配位的很少。

In this character analysis part, another important relationship of coordinated control parameter and coordinated control structure is depicted in detail followed by an entire control problem describe. And the analysis results show that the nature of control subsystem partition problem is to find the oversaturation related signal groups in the network.

在过饱和交通特性分析的最后部分详细阐述了协调层控制中的控制参数与控制结构的关系,以此为基点,揭示了过饱和状态下控制小区的划分本质是寻找路网中与过饱和路段相关的信号灯组的关系问题,并对过饱和控制问题进行了完整的描述。

The unit the crime question mainly lies in two aspects: First, the theory explained how the question namely will produce in the UK-US legal system criminal law practice question and the mainland legal system criminal law theory is coordinated, specifically speaking, how is the unit in the crime question and the mainland legal system criminal law by the natural person crime the question which is coordinated for the premise penology theory.

单位犯罪的问题主要在于两个方面:其一,理论解释问题即如何将产生于英美法系刑法实践的问题与大陆法系的刑法理论相协调,具体而言,就是如何将单位犯罪问题与大陆法系刑法中以自然人犯罪为前提的刑法理论相协调的问题。

In complex 1,Cucan be described as a four-coordinated square planar geometry.Compound 8 is the sodium salt of plumbagin and exists as ionic compound.Compounds 9-16 are the rare earth complexes of plumbagin with La,Y,Dy,Sm,Gd,Nd,Erand Eu.Compound 17 is binuclear Y complex.18 is mononuclear Ycomplex with plumbagin and another ligand from Plumbago Zeylanica.Compounds 19-21 are the ternary complexes with plumbagin and 2,2\'-bpy and phen as assistant ligand.In 19, the geometry of Cucan be described as five-coordinated distorted square pyramid that exists in a dimer through the weak bonding,and 1-D chain structure is formed by intermolecular hydrogen bonds.

化合物1的单晶结构分析表明1具有四配位平面四边形结构,化合物8是白花丹素的Na盐,以离子化合物形式存在;化合物9~16为白花丹素的La,Y,Dy,Sm,Gd,Nd,Er,Eu的稀土金属配合物;化合物17是白花丹素的双核钇结构;化合物18为白花丹素的单核钇结构,该配合物除了含白花丹素外,还有来自白花丹植物中的另一个单体化合物也参与配位;化合物19~21是以2,2\'-联吡啶和邻菲咯啉等含N配体为辅助配体,具有白花丹素—含N配体—金属离子的三元配合物,化合物19是白花丹素和2,2\'-联吡啶与Cu的配合物,具有五配位的四方锥构型,通过Cu…O弱的成键作用形成二聚体,再通过分子间的氢键作用进一步形成一维链状结构,化合物20和化合物21是白花丹素分别与2,2\'-联吡啶和邻菲咯啉的Zn配合物,都具有六配位八面体构型的双核锌配合物,呈一维链状结构,化合物20中链与链之间的大量氢键将一维链扩展成二维层,分子间的π-π堆积作用进一步形成三维结构。

Such derivatives are prepared by reacting a kaolin group mineral with a reagent, such as, an alkali metal halide or an ammonium halide which converts the majority of the octahedrally coordinated aluminum in the kaolin group mineral to tetrahedrally coordinated aluminum.

这种衍生物是通过将高岭族矿物与一种试剂,例如一种碱金属卤化物或一种卤化铵进行反应,从而将高岭族矿物中的大部分六配位铝转化为四配位铝而制备的。

The results of the dissertation were concluded as follows:(1) It is essential to deposit a basic additive on the Mo-based catalysts for the synthesis of CH_3SH. The potassium-doped Mo-based catalysts exhibit the highest activity than that of the catalysts doped with the otherⅠA andⅡA group basic promoters. H_2-TPR and LRS characterizations suggest that the addition of a base leads to the transformation of octahedrally coordinated Mo to tetrahedrally coordinated Mo, thus leads to the split of low temperature reduction peaks. The interaction between the basic components and Mo lead to the formation of B-Mo interface phase, which are closely correlated with the formation of CH_3SH.(2) It has been found that Fe, Co, Ni and Te have evident promoting effects for the K-Mo/SiO_2 catalysts.

主要结果归纳如下:(1)在Mo基催化剂中,必须添加碱才具有可观的合成甲硫醇活性,在IA和IIA族元素中,K是最佳的碱促进剂,当K/Mo摩尔比为2,前驱体为K_2CO_3,采用共浸法制备的K-Mo催化剂活性最高。H_2-TPR和LRS表征显示,碱的加入导致表面八面体钼氧物种向四面体转化,催化剂的低温还原峰发生分裂,碱助剂与钼之间存在强相互作用形成了B-Mo"界面相",该物种与合成甲硫醇密切相关。

In fact, CA ecology and political environments arecoordinated in emerge and motivation. Traditional accusatorial action and originaldemocracy are coordinated; traditional inquisitorial action and dictator-type system arecoordinated; modern CA and modern politic systems are coordinated.

实际上,刑事诉讼生态与政治环境保持着共生、互动与协调的生态平衡关系:传统弹劾式诉讼与原始民主政体是协调的;传统纠问式诉讼与专制集权政体是匹配的;而现代刑事诉讼生态与民主宪政体制则极为和谐一致。

For the first tin atom, it appears to be seven-coordinated with a distorted pentagonal bipyramid geometry, and the other is five-coordinated with a distorted trigonal bipyramidal geometry.

其中一类锡原子呈七配位畸变五角双锥构型,另一类呈七配位畸变三角双锥构型。

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