查询词典 carboxyl group

The space oriented blocks of modifiers favor the formation of small-sized rutile TiO2 nano-rods, at the same time, the coordination between carboxyl or hydroxyl group of modifiers and TiO2 nanoparticles also inhibit the TiO2 crystal growth, resulting in small-sized rutile nanoparticles.

结果表明：含羧基或羟基的有机化合物在修饰剂条件下都制得了纳米金红石型二氧化钛，且修饰剂的加入抑制了棒状纳米二氧化钛的颗粒大小，其中修饰剂的空间位阻效应在控制合成小尺寸二氧化钛纳米棒中起主要作用，且修饰剂的羟基和羧基的络合作用对颗粒的生长也起到抑制作用。

PartⅡ: N-phosphoryl amino acids have many biomimic reactions and the co-participation of the three functional group of phosphoryl, carboxyl and theamino acids side chain are essential for these reactions to occur. To study themechanism and the intrinsic relationship of these three groups will enlight thestudy on the mechanism of enzymatic reaction, the origin of life and otherproblems in the life science.

第二部分：N-磷酰氨基酸的多种仿生化反应是磷酰基、羧基、和侧链基团协同作用的结果，对其反应机理的研究，将对生化反应和生命起源中磷的作用有着重要的意义。

The copper atom is in a planar coordination site of [N_2O_2] and it devites from the mean plane by only 0.80 pm. Byπ-πstacking interactions, a alabastrine structure was obtained.(2)Schiff-base complex [Cu(H_2O)]·H_2O, where H3GS is the 3-carboxyl -salicylidene glycine, was synthesized and characterized by elemental analysis, IR spectra and single-crystal analysis. The crystal belongs to monoclinic system, space group P2(1)/c, a=848.46(3)pm, b=681.54(3)pm, c=1967.16(8)pm,β=95.8210(10)°, Z=4, R_1=0.0279, wR_2=0.0724. The copper atom is in a square-pyramidal field with the base

结果表明该晶系属单斜晶系，空间群P2(1)/c，晶胞参数：a=848.46(3)pm，b=681.54(3)pm，c=1967.16(8)pm，α=90°，β=95.8210(10)°，γ=90°，Z=4，R_1=0.0279，wR_2=0.0724，Cu原子位于轻微变形的四方锥场底心，底面被氮原子、酚氧原子、甘氨酸羧基的一个氧原子和一个水分子氧原子占据，而甘氨酸羧基的另一个氧原子占据相邻分子的锥顶，因而形成一维链状结构；合成了单核双聚配合物Na_2[Cu_2_2]·2H_2O ，铜三核配合物Cu_3_2·5H_2O和铜锌异三核配合物ZnCu_2_2·5H_2O，并用元素分析，IR光谱，电子光谱和磁化率测定对配合物的组

As expected from the reaction mechanism, the carboxyl groups of aspartic and glutamic acid residues were not modified, while the amino group s that could react with the activated peptides were concomitantly protected by formylation.

如反应机理所预测的那样，天门冬氨酸和谷氨酸残基未被修饰，而能与活性肽反应的氨基则同时被甲酰化保护起来。

In complexes 8～16 synthesized by hydrothermal method, most of the ligands adopt multidentate coordination modes joining several lanthanide ions into high-dimensional coordination polymers. And changing of 5-substituting group on isophthalic acid has a little effect on the coordinated abilities of the meta-carboxyl groups.

水热法制备的配合物8～16中，配体多采取多齿配位模式桥连多个稀土离子，形成高维配位聚合物，同时由于羧基氧原子和稀土离子的强的键合力，间苯二甲酸的5位取代基的变化对间位羧基的配位能力的影响不大。

Furthermore, the one-dimensional complexes 26 and 28 with strongπ-πpacking interactions are prepared from DMF solvent, which indicates that the traditional solvent volatilizing method could bring low-dimensional complex.4. By measuring the enthalpy changes of the liquid phase formation reaction for complexes a~e, and calculating the electronic densities of five 5-substituted derivation of isophthalic acid, we can make a conclusion that 5-substituted group changing of the ligand has a little influence on oxygen atoms of carboxyl groups.5. Fluorescence experiments of these complexes indicated that they could be used for luminescence materials in future.6. Using packing saturation rule we calculated and analyzed these series of complexes, and the results showed that the changes of complexes with changes of ligands could be explained from the rule.

在DMF溶剂中得到了具有强π-π堆积作用力的一维配位聚合物[Ln(5-NO_2-bdc)(NO_3)]Ln=Pr(26和Ho(28)，表明传统的溶剂挥发合成条件可以得到低维的配合物。4、通过配合物a～e的液相生成反应焓的测定，以及配体阳离子的电子密度计算，进一步佐证了间苯二甲酸的5位取代基变化对配体的羧基氧原子配位能力影响不大的结论。5、荧光特性表明此类配合物可以用于发光材料。6、利用堆积饱和规律对所得系列的配合物的进行计算和分析，发现随着配体的变化，配合物的变化可以从堆积饱和规律出发进行解释。

The results of analysis showed that the DBD was more suitable for oxidizing carbon black than RF. Because carbon black oxidized by DBD had a lot of single oxygenous functional group,carboxyl,which could be used to graft antitumour medicine and could be well dispersed in water.

通过对氧化后炭黑性能的分析测试得出以下结论：DBD 工艺优于RF 工艺，经DBD 氧化改性的纳米炭黑含氧官能团多，官能团单一，在水中的分散稳定性良好，为高选择性地进行药物接枝反应创造了条件。

A convenient method to synthesize three kinds of novel 2-(2-hydroxyphenyl) benzimidazole in order to improve the solubilities of the fluorophores with substituent of carboxyl, ester and double-bond which are aimed for determining the sulphydryl group was reported.

合成了N-{3-(2-苯并咪唑基)-4-羟基苯基}马来酰亚胺酸， N-{3-(2-苯并咪唑基)-4-乙酸酯基苯基}和马来酰亚胺N-{3-(2-苯并咪唑基)-4-羟基苯基}马来酰亚胺，在基本荧光发射团上分别引入了羧酸基；酯基；双键活性基团。

As CAAX-mimetics, 1, 3-dihydro-5-phenyl-2-H-1, 4-benzodiazepin-2-one was modified by linking carboxyl groups with various carbon through N-1 and C-3, 3-(imidazol-4-yl) propion amido group with different substituents was connected at C-7; In the synthesis of bisubstrate analogues, thiocarbamido compounds was alkylated by alkyl iodide and then hydrolyzed to give alkylthiol benzoate compounds.

1，4-苯并二氮杂草-2-酮类化合物的合成过程中分别对其1、3、4和7位进行了基团变化，在1和3位连接不同长度含羧基或酯基的侧链，在7位连接不同取代的咪唑丙酰氨基。在苯甲酸硫醇酯化合物合成过程中，建立了一种硫原子连有不同长度碳链的苯甲酸硫醇酯的合成方法。

Organic our country high polymer flocculant already has commercialized at present having several breeds such as PAM , polypropylene acidamides and carboxyl methyl cellulose only , studies innocuous high-effect organic synthesis high polymer flocculant (the ammonium equality gathers the sum copolymer kind if alkyl alkene propyl group halogenates waiting), optimizes it's the cost reduction composing handicraft.

目前我国有机高分子絮凝剂已商品化的仅有PAM、聚丙烯酰胺和羧甲基纤维素等几个品种，研究高效无毒的有机合成高分子絮凝剂(如烷基烯丙基卤化铵的均聚和共聚物类等)，优化其合成工艺降低成本。

The big eared hedgehog, the little owl, the sand gecko, the three-toed jerboa, and every show needs a villain - saw-scale - the viper!

大耳刺猬，小猫头鹰，沙壁虎，三趾跳鼠，每场戏都需要反派角色：蝰蛇。

Plasmodiophora brassicae ; resting spores ; density gradient centrifugation of sucrose ; ultrasonic disruption

根肿；休眠孢子；蔗糖密度梯度离心；超声波破碎