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The aim of this study was to develop a novel amphiphilic functional block poly(ε-caprolactone) bearing ketone groups MPEG-b-P(OPD-co-CL. 2-oxepane-1, 5-dione was copolymerized with ε-caprolatone in which methoxy poly (MPEG, Mn=5 000) and stannous octoate were used as initiator and catalyst, respectively. The syntheses were conducted by bulk and solution polymerization. 1H NMR results showed that peak position and splitting of the polymers synthesized through solution polymerization were consistent with theoretical data, demonstrating the products were designed block copolymers. While in the bulk polymerization, polymer peak position was changed due to their high reaction temperature, suggesting their structural variation.

将带有羰基官能团的4-羰基己内酯和ε-己内酯分别在甲氧基聚乙二醇(MPEG,Mn=5 000)为引发剂,异辛酸亚锡为催化剂溶液和本体体系中开环聚合,合成了两亲性侧基带有羰基官能团的聚己内酯嵌段共聚物MPEG-b-P(OPD-co-CL.1H NMR结果表明采用溶液聚合法合成的聚合物各峰的峰位置和分裂情况与理论一致,证明了产物是实验所设计的嵌段共聚物,而采用本体聚合法合成的聚合物由于温度的影响,聚合物各峰的峰位置发生了变化,说明其结构发生了变化;差示扫描量热法分析结果表明随着OPD单体含量的增加,聚合物的熔点,玻璃化转变温度和熔融焓增加;热失重测试结果表明OPD单体的引入增加了聚合物的热敏感性。

In this paper,the forming mechanism and affecting favtor of bulk metallic glasses is systematically discussed from the aspects of thermodynamic, kinetic and microstructure . Thermodynamic factors which favor the amorphization of alloys analyzed, the glass forming range of ternary alloys system was proposed by using Miedema theory, Toop model and considering the influence of free energy of pure metals at different temperature. The approach was applied to predict the composition range of amorphous Mg-Cu-La alloys. Several methods(such as three empirical criterions ,binary alloys phase diagram , Miedema theory and Toop mode) were used to design a series of Mg65Cu25La10 、Mg68Cu17La15 and Mg57Cu23La20 alloys, These bulk amorphous alloys with maximum diameter thickness reaching to 1mm were prepared by means of graphite-molding casting though the raw materials are of a low purity by conventional casting processes at a low cooling rate.

本文从合金的热力学、动力学及结构形成条件方面系统的讨论了Mg 基大块非晶的形成机制及影响因素,并从非晶形成的热力学观点出发,综合应用Miedema理论和Toop 模型,并考虑纯金属在不同温度下的自由能,在此基础上提出了一种定量预测三元非晶合金形成范围的方法,用该方法计算Mg-Cu-La 三元合金系的非晶形成范围,应用多项技术(三经验原则、二元合金相图及Miedema 理论和Toop模型)设计了Mg65Cu25La10 、Mg68Cu17La15 和Mg57Cu23La20非晶合金。

As exposed to optics microscope and inverted microscope,compared to control,SW480 cells with Giemsa staining that treated with the H2RA(cimetidine、nizatidine) took on malignance declining as crimpled firstly,cellular bulk and heteromorphism dimimished,the amount of rounded cell manifolded,nucleolus bulk lessened,dyeing thin,the amount of nucleolus decreased,partial cell organs manifest side-gathering phenomenon on chromatin,and the link between SW480 cell is loosened , subsequently partial rounded cell is floated.When the H2RA(cimetidine 40μM、nizatidine 20μM) against SW480 cells after 3 day,SW480 cells change roundly,nucleolus smashed,shrinking nucleolus came into being,and part of those not adhibited cell wall.

在光镜和倒置相差显微镜下,与对照组相比,经姬姆萨染色观察,西咪替丁、尼扎替丁处理的SW480细胞,先发生皱缩,体积变小,异形性减少,细胞变圆数目增多,细胞核变小,染色变淡,核仁数量减少,部分可见染色质边集现象;细胞间连接疏松,随后部分变圆细胞浮起。40μM西咪替丁及20μM尼扎替丁连续处理3天后,SW480细胞全部变圆,细胞核碎裂,固缩微核形成,部分不再贴壁。

These productions boosted the development of plastic theory in engineering and settled a platform of applying plastic theories in engineering. And especially the intergraded mechanical models of metal bulk forming process provided a new approach of describing the metal bulk forming process in quantitative and parameter methods and make possible the realization of intelligent function of the computer simulation of metal plastic forming process.

所取得的主要研究成果是对工程塑性理论的深化及其在应用方向上的提升,构成了推广应用工程塑性理论的简易平台,特别是基于模型单元的力学模型而建立的金属体积成形过程的整体力学模型,是定量参数化描述体积成形过程的新的有力工具与方法,是赋予金属塑性成形过程模拟以智能化功能的关键。

The results showed that the greatest bulk density values appeared in the 49th day after silking, and harvest later had influence on the grain bulk density.

从试验结果分析,容重最高值出现在吐丝后49天,晚收影响籽粒的容重。

Likes slivering the bulk bulk to boil the food.

大。小凉山及大部分彝族禁食狗肉。

The meat mainly has the beef, the pork, the mutton, the chicken and so on, likes slivering the bulk bulk to boil the food, the Han Nationality calls it "the steelyard weight steelyard weight meat".

肉食主要有牛肉、猪肉、羊肉、鸡肉等,喜欢切成大块大块煮食,汉族称之为&砣砣肉&。

"The pre-feasibility research of 100,000 tons general bulk cargo berth in Yangkou Port area, Nantong" has been finished by China Communication First Design Institute of Navigation Engineering,"the Project Proposal of the bulk cargo logistics park in Yangkou Port" has been finished by Hohai University, and "The pre-feasibility research of local railway from Hai'an to Yangkou" has been finished by The Fourth Survey and Design Institute of China Railways.

已委托中交一航院编制完成了《南通洋口港10万吨级通用散货码头工程预可行性研究报告》,委托河海大学编制完成了《洋口港散货物流园区项目建议书》,委托铁道第四勘察设计院编制完成了《地方铁路海安至洋口预可行性研究报告》,以上项目均已获省发改委批准开展前期工作。

"The pre-feasibility research of 100,000 tons general bulk cargo berth in Yangkou Port area, Nantong" has been finished by China Communication First Design Institute of Navigation Engineering,"the Project Proposal of the bulk cargo logistics park in Yangkou Port" has been finished by Hohai University, and "The pre-feasibility research of local railway from Hai'an to Yangkou" has been finished by The Fourth Survey and Design Institute of China Railways.

已委托中交一航院编制完成了《南通洋口港10万吨级通用散货码头工程预可行性研究报告》,委托河海大学编制了《洋口港散货物流园区项目建议书》,委托铁道第四勘察设计院编制完成了《地方铁路海安至洋口预可行性研究报告》,以上项目均已获省发改委批准开展前期工作。

JVC headphones in bulk is cost-effective has always been synonymous with New JVC brand new original authentic an iron headphones FXC50, bulk-free parts, no use of history, not foreign waste, extremely comfortable to wear.

JVC的散装耳机一向就是性价比的代名词,新到JVC全新原装正品动铁耳机FXC50,散装无配件,绝无使用史,绝非洋垃圾,佩带非常舒适。

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Smoking cigarettes adds to the Computer Desk Computer manufacturer computer mouse Computer Computerized collar knitter machine Conduit Bodies construction board Container Bag Control Arm Cooking Thermometer general levels of air pollution as well as damaging our health.

吸烟不仅对健康有害,而且增加空气污染程度。香烟雾含有多种有害物质:不仅有致癌化学物质、有某种能阻止氧气进入血液的气体,还有引起血压增高、心速加快的被称为尼古丁的物质。

He is one of my favorite actors.

他是我最喜欢的男演员之一。

Today they need to market their skills, talents, and competencies.

今天他们需要推销他们的技能、才干和能力。